Editing Highly efficient and selective visible-light driven CO2-to-CO conversion by a Co-based cryptate in H2O-CH3CN solution

[[Category:Photocatalytic CO2 conversion to CO]][[Category:Publication]]
{{BaseTemplate}}
===Abstract===
====Summary====
A photochemical reduction of CO<sub>2</sub> to CO was shown using the copper cryptate  as catalyst in combination with the ruthenium photosensitizer . Turnover numbers (TONs) up to 51392 and a selectivity of 98% for CO were reached in MeCN/H<sub>2</sub>O. The experiments were conducted under visible-light irradiation (λ = 450 nm) using TEOA as sacrificial electron donor (see section SEDs below).
====Advances and special progress====
====Additional remarks====
===Content of the published article in detail===
The article contains results for the reduction of CO<sub>2</sub> to CO under visible-light catalysis using a copper complex as a catalyst. The catalytic system performs best (referring to the TON of CO production) in MeCN/H<sub>2</sub>O with complex xx.
====Catalyst====
<chemform smiles="" inchi="" inchikey="" height="200px" width="300px" float="none"></chemform>

====Photosensitizer====
====Investigation====

====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donor {{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=false|width=300|height=200}}. 
====Additives====
In this study, no additives were tested.