Editing Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production

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{{#doiinfobox: 10.1021/jacs.7b01956}}

==== Catalyst====
{{#moleculelink:|link=YWLPEVCCGUVAOP-UHFFFAOYSA-N|image=true}}

====Photosensitizer====
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  -INDIGO-02012310412D

  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 37 45 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 10.5435 -4.92762 0.0 0
M  V30 2 C 11.7491 -4.99092 0.0 0
M  V30 3 C 11.2288 -4.73543 0.0 0
M  V30 4 C 11.8152 -5.59773 0.0 0
M  V30 5 N 10.1065 -5.76474 0.0 0
M  V30 6 C 11.152 -6.14351 0.0 0
M  V30 7 N 9.25866 -4.63911 0.0 0
M  V30 8 C 9.63235 -3.30328 0.0 0
M  V30 9 C 9.14128 -3.93512 0.0 0
M  V30 10 C 10.2777 -3.25752 0.0 0
M  V30 11 C 10.2001 -4.55637 0.0 0
M  V30 12 C 10.6339 -3.773 0.0 0
M  V30 13 C 5.94213 -3.03516 0.0 0
M  V30 14 C 7.24168 -3.49305 0.0 0
M  V30 15 C 6.59328 -2.8886 0.0 0
M  V30 16 N 7.04427 -4.43995 0.0 0
M  V30 17 C 5.69026 -3.59788 0.0 0
M  V30 18 C 6.01761 -4.2224 0.0 0
M  V30 19 C 4.16032 -4.25649 0.0 0
M  V30 20 C 5.64012 -4.58942 0.0 0
M  V30 21 C 4.8164 -4.06601 0.0 0
M  V30 22 N 5.79253 -5.37659 0.0 0
M  V30 23 C 3.99774 -4.91039 0.0 0
M  V30 24 C 4.6602 -5.58382 0.0 0
M  V30 25 C 5.61199 -8.17009 0.0 0
M  V30 26 C 7.22575 -8.54472 0.0 0
M  V30 27 N 6.81042 -7.59487 0.0 0
M  V30 28 C 7.08099 -9.28642 0.0 0
M  V30 29 C 5.63354 -9.26837 0.0 0
M  V30 30 C 6.38037 -9.63065 0.0 0
M  V30 31 C 8.04784 -8.35665 0.0 0
M  V30 32 C 9.63143 -8.08568 0.0 0
M  V30 33 N 8.65644 -7.66877 0.0 0
M  V30 34 C 9.74901 -9.15397 0.0 0
M  V30 35 C 8.28703 -9.41911 0.0 0
M  V30 36 C 9.08273 -9.6819 0.0 0
M  V30 37 Ru 7.90443 -6.04653 0.0 0 CHG=2
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 2 9 7
M  V30 8 2 10 8
M  V30 9 1 7 11
M  V30 10 1 8 9
M  V30 11 2 11 12
M  V30 12 1 12 10
M  V30 13 2 15 13
M  V30 14 2 16 14
M  V30 15 1 13 17
M  V30 16 1 14 15
M  V30 17 2 17 18
M  V30 18 1 18 16
M  V30 19 2 21 19
M  V30 20 2 22 20
M  V30 21 1 19 23
M  V30 22 1 20 21
M  V30 23 2 23 24
M  V30 24 1 24 22
M  V30 25 2 27 25
M  V30 26 2 28 26
M  V30 27 1 25 29
M  V30 28 1 26 27
M  V30 29 2 29 30
M  V30 30 1 30 28
M  V30 31 2 33 31
M  V30 32 2 34 32
M  V30 33 1 31 35
M  V30 34 1 32 33
M  V30 35 2 35 36
M  V30 36 1 36 34
M  V30 37 1 26 31
M  V30 38 1 20 18
M  V30 39 1 11 1
M  V30 40 10 16 37
M  V30 41 10 22 37
M  V30 42 10 27 37
M  V30 43 10 33 37
M  V30 44 10 5 37
M  V30 45 10 7 37
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>

====Investigation====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}

====Sacrificial electron donor====
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}}
[[Category:Photocatalytic CO2 conversion to CO]]