CO2+ results from SI

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< Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction
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investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100969

2

Ru(bpy)3

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90 2.8333333333333 7.73 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90 2.0333333333333 8.53 n/a


in 5 mL solvent

Molecule:100969

2

Ir(ppy)3

0.2

BIH

0.05

PhOH

1

MeCN



CO2 90 4.2666666666667 10.92 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

BIH

0.05

PhOH

1

MeCN



CO2 90 10.783333333333 2.2 n/a


in 5 mL solvent

Molecule:100969

2

Ru(bpy)3

0.2

BIH

0.05

PhOH

1

MeCN



CO2 90 6.2666666666667 3.15 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

PhOH

1

MeCN



CO2 90 2 0.133 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

PhOH

0.5

MeCN



CO2 90 0.21666666666667 0.97 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

Molecule:100972

0.1

MeCN



CO2 90 0.23333333333333 1.2 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

TFE

0.1

MeCN



CO2 90 0.3 0.483 n/a


in 5 mL solvent