Control experiments

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investigation
Molecular process, Photocatalytic CO2 conversion experiments
"Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property."Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property."Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

[MoO(2Hqpdt)2][NBu4]

0.0001

[Cu(PP)2][TBA]2

0.1

BIH

0.1


DMF



Molecule:100865 25 white LED 23 8600 144 98.4%; 0%; 1.6%; 0%; 0%


No


[Cu(PP)2][TBA]2

0.1

BIH

0.1


DMF



Molecule:100865 25 white LED 23 0 0 n/a


No

[MoO(2Hqpdt)2][NBu4]

0.0001


BIH

0.1


DMF



Molecule:100865 25 white LED 23 0 0 n/a


No

[MoO(2Hqpdt)2][NBu4]

0.0001

[Cu(PP)2][TBA]2

0.1

BIH

0.1


DMF



25 white LED 23 8600 144 98.4%; 0%; 1.6%; 0%; 0%


No