Effect of proton donor

From ChemWiki
< An integrated Re(I) photocatalyst and sensitizer that activates the formation of formic acid from reduction of CO2
Revision as of 16:43, 23 January 2024 by Victor.larignon (talk | contribs) (Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100760 |PS=Molecule:100808 |e-D=Molecule:100507 |solvent A=Molecule:100529 |solvent B=Molecule:100507 |solvent-ratio=4:1 |include=No }} }}")
(diff) ← Older revision | Latest revision (diff) | Newer revision → (diff)

investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

[Re(bpy)2(CO)2][OTf]

[Ru(bpy)3][PF6]

TEOA


DMF

TEOA


4:1 n/a


No