Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON H2	TON HCOOH
1.	Ru(py)-(MeNdpp)2(CO)2Cl	25	[Ru(bpy)3][PF6]	0.025	TEOA	DMF	405		380
2.	Ru(py)-(MeNdpp)2(CO)2Cl	50	[Ru(bpy)3][PF6]	0.05	TEOA	DMF	405		210
3.	Ru(py)-(MeNdpp)2(CO)2Cl	100	[Ru(bpy)3][PF6]	0.1	TEOA	DMF	405	57.5	363
4.	Ru(py)-(MeNdpp)2(CO)2Cl	500	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	14	162
5.	Ru(py)-(MeNdpp)2(CO)2Cl	1000	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	13.3	90.5
6.	Ru(py)-(HNdpp)2(CO)2Cl	500	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	14	70.5
7.	Ru(py)-(HNdpp)2(CO)2Cl	1000	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	12	44.5
8.	Ru(py)-(HNdpp)2(CO)2Cl	2000	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	9.3	41.5

Investigation-Name: Table 1

Investigations

DOI	10.1002/cssc.201901326
Authors	Yasmeen Hameed, Gyandshwar Kumar Rao, Jeffrey S. Ovens, Bulat Gabidullin, Darrin Richeson,
Submitted	11.06.2019
Published online	03.07.2019
Licenses	http://onlinelibrary.wiley.com/termsAndConditions#vor, http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects	General Energy, General Materials Science, General Chemical Engineering, Environmental Chemistry
Go to literature page