Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst

Abstract

A photochemical reduction of CO2 to CO and CH4 was shown using the iron porphyrin catalyst Fe(pTMAPP)Cl5 (100826) in combination with the phenoxazine photosensitizers 5,10-Di(2-naphthyl)-5,10-dihydrophenazine (100498) and 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine (100493). Turnover numbers (TONs) up to 149 for CO and 29 for CH4 were reached. The experiments were conducted under visible-light irradiation (λ > 435 nm) with a tertiary amine (see section SEDs below) as sacrificial electron donor.

Advances and special progress

The first demonstration for the reduction of CO2 to CH4 (complete 8e–/8H+ reduction) by a combination of an earth-abundant metal catalyst and an organic dye. So far, similar systems were shown to induce 2e–/2H+ reduction of CO2 to CO or formic acid.

Additional remarks

Methane was produced continuously (even after irradiation up to 4 days). The 8e–/8H+ reduction efficiency strongly depends on the redox properties of the organic photosensitizer and acidity of the proton source.

In additional experiments, CO was used as the gas resource. The system consisting of iron porphyrin catalyst Fe(pTMAPP)Cl5 (100826) in combination with the phenoxazine photosensitizer 5,10-Di(2-naphthyl)-5,10-dihydrophenazine (100498) and 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine (100493) was able to produce CH4 with a TON of 80 (85% selectivity, quantum yield: 0.47%).

Catalysts

Fe(pTMAPP)Cl5 (100826)

Photosensitizers

5,10-Di(2-naphthyl)-5,10-dihydrophenazine (100498) 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine (100493)

Investigations

   REDIRECT Photocatalytic reduction of CO2Investigation-Name: Table 1

Sacrificial Electron Donor

In this study, the experiments were done with the sacrificial electron donors DIPEA (DIPEA (100615)), TEOA (TEOA (100507)), BIH (BIH (100508)), and TEA (TEA (100505)).

Additives

In this study, different additives were used. As depicted in the investigation table, water (H2O (100616),) phenol (PhOH (100617)), and trifluoroethanol (TFE (100618)) were used.