Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction

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Catalyst

[Re(bpy)(CO)3(MeCN)][PF6]

Photosensitizer

Investigation

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	.	.	λexc [nm]	.	TON CO	TON H2	TON HCOOH	.	.	.
1.	Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05			DMF			436		20	72	290
2.	Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05	BI(OH)H	0.03	DMF			436		16	49	280
3.	[Mn(dtBubpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05			DMF			436		32		85
4.	[Mn(dtBubpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05	BI(OH)H	0.03	DMF			436		80		60

Investigation-Name: Table 2Export

Sacrificial electron donor

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