Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate

Catalyst

Ni(pbi)(pyS)2 Ni(pbt)(pyS)2

Photosensitizer

Eosin Y

Investigation

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	.	.	.	.	TON HCOOH	.	.	.
1.	Ni(pbi)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O					14000
2.	Ni(pbt)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O					13100

Investigation-Name: Table 1Export

Sacrificial electron donor

TEOA