A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity: Difference between revisions
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=== Photosensitizer === | === Photosensitizer === | ||
<chemform smiles="C1C2C=CC3C=CC=N4[Ru+2]5(N6C7C8N5=CC=CC=8C=CC=7C=CC=6)5(N6=CC=CC7C=CC8C=CC=N5C=8C=76)N(C=2C=34)=CC=1.P(F)(F)(F)([F-])(F)(F)F.P(F)(F)(F)([F-])(F)(F)F" inchi="1S/3C12H8N2.2F7P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-8(2,3,4,5,6)7;/h3*1-8H;;;/q;;;2*-1;+2" inchikey="YYWPACUPCNICHF-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | |||
-INDIGO-12072422152D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 59 68 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C -4.49166 0.079824 0.0 0 | |||
M V30 2 C -4.06787 -0.62801 0.0 0 | |||
M V30 3 C -3.24298 -0.614915 0.0 0 | |||
M V30 4 N -2.84187 0.106013 0.0 0 | |||
M V30 5 C -3.26566 0.813846 0.0 0 | |||
M V30 6 C -4.09055 0.800752 0.0 0 | |||
M V30 7 C -2.86455 1.53478 0.0 0 | |||
M V30 8 C -3.28834 2.24261 0.0 0 | |||
M V30 9 C -4.11323 2.22951 0.0 0 | |||
M V30 10 C -4.51434 1.50859 0.0 0 | |||
M V30 11 N -2.03965 1.54787 0.0 0 | |||
M V30 12 C -1.63855 2.2688 0.0 0 | |||
M V30 13 C -2.06233 2.97663 0.0 0 | |||
M V30 14 C -2.88723 2.96354 0.0 0 | |||
M V30 15 C 0.250331 2.98281 0.0 0 | |||
M V30 16 C -0.574639 2.98991 0.0 0 | |||
M V30 17 C -0.99328 2.27903 0.0 0 | |||
M V30 18 N -0.586952 1.56103 0.0 0 | |||
M V30 19 C 0.238017 1.55392 0.0 0 | |||
M V30 20 C 0.656658 2.26481 0.0 0 | |||
M V30 21 C 0.644346 0.835919 0.0 0 | |||
M V30 22 C 1.46932 0.828809 0.0 0 | |||
M V30 23 C 1.88796 1.5397 0.0 0 | |||
M V30 24 C 1.48163 2.2577 0.0 0 | |||
M V30 25 N 0.225704 0.125028 0.0 0 | |||
M V30 26 C 0.632033 -0.59297 0.0 0 | |||
M V30 27 C 1.457 -0.600079 0.0 0 | |||
M V30 28 C 1.87564 0.110811 0.0 0 | |||
M V30 29 Ru -1.28362 0.415314 0.0 0 CHG=2 | |||
M V30 30 C 0.325773 -2.28096 0.0 0 | |||
M V30 31 C 0.741449 -1.56833 0.0 0 | |||
M V30 32 C 0.332132 -0.852031 0.0 0 | |||
M V30 33 N -0.49286 -0.848359 0.0 0 | |||
M V30 34 C -0.908535 -1.56099 0.0 0 | |||
M V30 35 C -0.499218 -2.27729 0.0 0 | |||
M V30 36 C -1.73353 -1.55732 0.0 0 | |||
M V30 37 C -2.1492 -2.26994 0.0 0 | |||
M V30 38 C -1.73989 -2.98624 0.0 0 | |||
M V30 39 C -0.914894 -2.98991 0.0 0 | |||
M V30 40 N -2.14284 -0.841017 0.0 0 | |||
M V30 41 C -2.96783 -0.837345 0.0 0 | |||
M V30 42 C -3.38351 -1.54997 0.0 0 | |||
M V30 43 C -2.97419 -2.26627 0.0 0 | |||
M V30 44 P 3.56559 0.765939 0.0 0 | |||
M V30 45 F 3.35207 -0.030949 0.0 0 | |||
M V30 46 F 2.85112 1.17844 0.0 0 | |||
M V30 47 F 4.14895 1.3493 0.0 0 | |||
M V30 48 F 3.56559 1.59094 0.0 0 CHG=-1 | |||
M V30 49 F 4.39059 0.765939 0.0 0 | |||
M V30 50 F 2.7687 0.552413 0.0 0 | |||
M V30 51 F 4.14895 0.182576 0.0 0 | |||
M V30 52 P 3.68934 -1.58531 0.0 0 | |||
M V30 53 F 3.47582 -2.3822 0.0 0 | |||
M V30 54 F 2.97487 -1.17281 0.0 0 | |||
M V30 55 F 4.27271 -1.00195 0.0 0 | |||
M V30 56 F 3.68934 -0.760311 0.0 0 CHG=-1 | |||
M V30 57 F 4.51434 -1.58531 0.0 0 | |||
M V30 58 F 2.89245 -1.79884 0.0 0 | |||
M V30 59 F 4.27271 -2.16867 0.0 0 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 2 1 2 | |||
M V30 2 1 2 3 | |||
M V30 3 2 3 4 | |||
M V30 4 1 4 5 | |||
M V30 5 2 5 6 | |||
M V30 6 1 6 1 | |||
M V30 7 1 5 7 | |||
M V30 8 2 7 8 | |||
M V30 9 1 8 9 | |||
M V30 10 2 9 10 | |||
M V30 11 1 10 6 | |||
M V30 12 1 7 11 | |||
M V30 13 2 11 12 | |||
M V30 14 1 12 13 | |||
M V30 15 2 13 14 | |||
M V30 16 1 14 8 | |||
M V30 17 2 15 16 | |||
M V30 18 1 16 17 | |||
M V30 19 2 17 18 | |||
M V30 20 1 18 19 | |||
M V30 21 2 19 20 | |||
M V30 22 1 20 15 | |||
M V30 23 1 19 21 | |||
M V30 24 2 21 22 | |||
M V30 25 1 22 23 | |||
M V30 26 2 23 24 | |||
M V30 27 1 24 20 | |||
M V30 28 1 21 25 | |||
M V30 29 2 25 26 | |||
M V30 30 1 26 27 | |||
M V30 31 2 27 28 | |||
M V30 32 1 28 22 | |||
M V30 33 10 11 29 | |||
M V30 34 10 18 29 | |||
M V30 35 10 4 29 | |||
M V30 36 10 25 29 | |||
M V30 37 2 30 31 | |||
M V30 38 1 31 32 | |||
M V30 39 2 32 33 | |||
M V30 40 1 33 34 | |||
M V30 41 2 34 35 | |||
M V30 42 1 35 30 | |||
M V30 43 1 34 36 | |||
M V30 44 2 36 37 | |||
M V30 45 1 37 38 | |||
M V30 46 2 38 39 | |||
M V30 47 1 39 35 | |||
M V30 48 1 36 40 | |||
M V30 49 2 40 41 | |||
M V30 50 1 41 42 | |||
M V30 51 2 42 43 | |||
M V30 52 1 43 37 | |||
M V30 53 10 40 29 | |||
M V30 54 10 33 29 | |||
M V30 55 1 44 45 | |||
M V30 56 1 44 46 | |||
M V30 57 1 44 47 | |||
M V30 58 1 44 48 | |||
M V30 59 1 44 49 | |||
M V30 60 1 44 50 | |||
M V30 61 1 44 51 | |||
M V30 62 1 52 53 | |||
M V30 63 1 52 54 | |||
M V30 64 1 52 55 | |||
M V30 65 1 52 56 | |||
M V30 66 1 52 57 | |||
M V30 67 1 52 58 | |||
M V30 68 1 52 59 | |||
M V30 END BOND | |||
M V30 END CTAB | |||
M END | |||
</chemform> | |||
=== Investigation === | === Investigation === |
Revision as of 22:15, 7 December 2024
A bs tract
Summary
Additional remarks
Content of the published article in detail
Catalysts tested in this study
Photosensitizer
Investigation
Further Information
Sacrificial electron donor
In this study, the experiments were done with the sacrificial electron donor .
Additives
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)