Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate: Difference between revisions

Revision as of 10:07, 12 January 2024

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	.	.	.	.	TON HCOOH	.	.	.
1.	Ni(pbi)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O					14000
2.	Ni(pbt)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O					13100

Investigation-Name: Table 1

DOI	10.1021/jacs.0c08145
Authors	Sung Eun Lee, Azam Nasirian, Ye Eun Kim, Pegah Tavakoli Fard, Youngmee Kim, Byeongmoon Jeong, Sung-Jin Kim, Jin-Ook Baeg, Jinheung Kim,
Submitted	19.10.2020
Published online	19.10.2020
Licenses	https://doi.org/10.15223/policy-029, https://doi.org/10.15223/policy-037, https://doi.org/10.15223/policy-045,
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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 ==== Catalyst====
-<chemform smiles="C1C=CC=N2[Ni+2]3([S-]C4N3=CC=CC=4)3([S-]C4=CC=CC=N43)N3=C(NC4C=CC=CC=43)C=12" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" float="none" width="200" height="200">
+<chemform smiles="C1C=CC=N2[Ni+2]3([S-]C4N3=CC=CC=4)3([S-]C4=CC=CC=N43)N3=C(NC4C=CC=CC=43)C=12" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" float="none" width="300" height="200">
    -INDIGO-11302312462D
@@ Line 164: / Line 164: @@
 ====Photosensitizer====
-{{#moleculelink:|link=SEACYXSIPDVVMV-UHFFFAOYSA-L|image=true|width=500|height=300}}
+{{#moleculelink:|link=SEACYXSIPDVVMV-UHFFFAOYSA-L|image=true|width=300|height=200}}
 ====Investigation====