Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts: Difference between revisions

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DOI 10.1021/jacs.8b10619
Authors Hiroyuki Takeda, Hiroko Kamiyama, Kouhei Okamoto, Mina Irimajiri, Toshihide Mizutani, Kazuhide Koike, Akiko Sekine, Osamu Ishitani,
Submitted 27.11.2018
Published online 27.11.2018
Licenses http://pubs.acs.org/page/policy/authorchoice_termsofuse.html,
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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M  V30 END CTAB
M  V30 END CTAB
M  END
M  END
</chemform><chemform smiles="C1C=C2C3C=CC=C(C4C(C)=CC(C)=CC=4C)N=3[Mn](C#O)(C#O)(~Br)N2=C(C2C(C)=CC(C)=CC=2C)C=1" inchi="1S/C28H28N2.2CHO.BrH.Mn/c1-17-13-19(3)27(20(4)14-17)25-11-7-9-23(29-25)24-10-8-12-26(30-24)28-21(5)15-18(2)16-22(28)6;2*1-2;;/h7-16H,1-6H3;2*1H;1H;/q;;;;+1/p-1" inchikey="LAJRVYLSNAAJQU-UHFFFAOYSA-M" height="200px" width="300px" float="none">
</chemform><chemform smiles="C1C=C2C3C=CC=C(C4C(C)=CC(C)=CC=4C)N=3[Mn+]([C-]#[O+])([C-]#[O+])([Br-])N2=C(C2C(C)=CC(C)=CC=2C)C=1" inchikey="MMWVUSACGPQHBP-UHFFFAOYSA-M" inchi="1S/C28H28N2.2CO.BrH.Mn/c1-17-13-19(3)27(20(4)14-17)25-11-7-9-23(29-25)24-10-8-12-26(30-24)28-21(5)15-18(2)16-22(28)6;2*1-2;;/h7-16H,1-6H3;;;1H;/q;;;;+1/p-1" float="none" width="200" height="200">
   -INDIGO-03102311002D
   -INDIGO-01102416202D


   0  0  0  0  0  0  0  0  0  0  0 V3000
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M  V30 29 C 6.47682 -8.98054 0.0 0
M  V30 29 C 6.47682 -8.98054 0.0 0
M  V30 30 C 9.93819 -8.97039 0.0 0
M  V30 30 C 9.93819 -8.97039 0.0 0
M  V30 31 Mn 7.7 -4.95 0.0 0
M  V30 31 Mn 9.55 -5.025 0.0 0 CHG=1
M  V30 32 Br 7.7 -3.95 0.0 0
M  V30 32 Br 9.55 -3.675 0.0 0 CHG=-1
M  V30 33 C 8.56603 -4.45 0.0 0
M  V30 33 C 10.741 -4.3 0.0 0 CHG=-1
M  V30 34 C 8.56603 -5.45 0.0 0
M  V30 34 C 10.741 -5.75 0.0 0 CHG=-1
M  V30 35 O 9.43205 -3.95 0.0 0
M  V30 35 O 11.607 -3.8 0.0 0 CHG=1
M  V30 36 O 9.43205 -5.95 0.0 0
M  V30 36 O 11.607 -6.25 0.0 0 CHG=1
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M  V30 BEGIN BOND
M  V30 BEGIN BOND
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M  V30 34 10 4 31
M  V30 34 10 4 31
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M  V30 35 10 9 31
M  V30 36 8 31 32
M  V30 36 10 31 32
M  V30 37 10 31 33
M  V30 37 10 31 33
M  V30 38 10 31 34
M  V30 38 10 31 34

Revision as of 16:21, 10 January 2024


Catalyst

100751 [Show R-Groups] Mn(oMesbpy)(CO)2Br

Photosensitizer

[Cu(phen)-(dPPh-Bu)2]2[PF6]2

Investigation

  1. REDIRECT Results for photocatalytic reduction of CO2
Investigation-Name: Table 1

Sacrificial electron donor

BIHTEOA

Investigations

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