Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH: Difference between revisions
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</chemform><chemform smiles="C12N3[Mn+]([C-]#[O+])([C-]#[O+])([C-]#[O+])(N#CC)N4=CC=CC(C(=O)C(=O)C=1C=CC=3)=C24" inchikey=" | </chemform><chemform smiles="C12N3[Mn+]([C-]#[O+])([C-]#[O+])([C-]#[O+])(N#CC)N4=CC=CC(C(=O)C(=O)C=1C=CC=3)=C24.F[P-](F)(F)(F)(F)F" inchikey="JWEFEWAAUDGGIH-UHFFFAOYSA-N" inchi="1S/C12H6N2O2.C2H3N.3CO.F6P.Mn/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;1-2-3;3*1-2;1-7(2,3,4,5)6;/h1-6H;1H3;;;;;/q;;;;;-1;+1" float="none" width="200" height="200"> | ||
-INDIGO- | -INDIGO-01102415522D | ||
0 0 0 0 0 0 0 0 0 0 0 V3000 | 0 0 0 0 0 0 0 0 0 0 0 V3000 | ||
M V30 BEGIN CTAB | M V30 BEGIN CTAB | ||
M V30 COUNTS | M V30 COUNTS 33 35 0 0 0 | ||
M V30 BEGIN ATOM | M V30 BEGIN ATOM | ||
M V30 1 C 8.22511 -3.34193 0.0 0 | M V30 1 C 8.22511 -3.34193 0.0 0 | ||
| Line 100: | Line 100: | ||
M V30 25 C 11.5909 -4.96618 0.0 0 | M V30 25 C 11.5909 -4.96618 0.0 0 | ||
M V30 26 C 12.3319 -4.95736 0.0 0 | M V30 26 C 12.3319 -4.95736 0.0 0 | ||
M V30 27 F 12.617 -2.25 0.0 0 | |||
M V30 28 P 13.483 -1.75 0.0 0 CHG=-1 | |||
M V30 29 F 14.349 -2.25 0.0 0 | |||
M V30 30 F 13.483 -0.75 0.0 0 | |||
M V30 31 F 14.349 -1.25 0.0 0 | |||
M V30 32 F 12.617 -1.25 0.0 0 | |||
M V30 33 F 13.483 -2.75 0.0 0 | |||
M V30 END ATOM | M V30 END ATOM | ||
M V30 BEGIN BOND | M V30 BEGIN BOND | ||
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M V30 28 3 18 25 | M V30 28 3 18 25 | ||
M V30 29 1 25 26 | M V30 29 1 25 26 | ||
M V30 30 1 27 28 | |||
M V30 31 1 28 29 | |||
M V30 32 1 28 30 | |||
M V30 33 1 28 31 | |||
M V30 34 1 28 32 | |||
M V30 35 1 28 33 | |||
M V30 END BOND | M V30 END BOND | ||
M V30 END CTAB | M V30 END CTAB | ||
Revision as of 15:53, 10 January 2024
Catalyst
Mn(phdk)(CO)3(MeCN)
Mn(phen)(CO)3Br
Mn(bpy)(CO)3Br
Photosensitizer
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | additives | λexc [nm] | . | TON CO | TON HCOOH | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 100 | 0.1 | 480 | 8 | 52 | |||||||||||
| 2. | 100 | 0.1 | 480 | 15 | 58 | |||||||||||
| 3. | 100 | 0.1 | 480 | 9 | 48 | |||||||||||
| 4. | 100 | 0.1 | 480 | 47 | 15 | |||||||||||
| 5. | 100 | 0.1 | 500 | 7 | 40 | |||||||||||
| 6. | 100 | 0.1 | 457 | 7 | 34 | |||||||||||
| 7. | 2 | 100 | 0.1 | 480 | 5 | 18 | ||||||||||
| 8. | 200 | 0.1 | 480 | 8 | 52 | |||||||||||
| 9. | 100 | 0.1 | 480 | |||||||||||||
| 10. | 100 | 0.1 | 500 | |||||||||||||
| 11. | 100 | 480 | 3 | |||||||||||||
| 12. | 0.1 | 500 | ||||||||||||||
| 13. | 100 | 0.1 | Argon gas | 480 | ||||||||||||
| 14. | 100 | 0.1 | 480 | |||||||||||||
| 15. | 100 | 0.1 | 480 | |||||||||||||
| 16. | 100 | 0.1 | 480 | 21 | 22 | |||||||||||
| 17. | 100 | 0.1 | 480 | 2 | ||||||||||||
| 18. | 100 | 480 | 9 | 13 | ||||||||||||
| 19. | 100 | 0.1 | 480 | 17 | 4 | |||||||||||
| 20. | 100 | 0.1 | 480 | 6 | 39 | |||||||||||
| 21. | 100 | ascorbic acid/NaA | 480 | |||||||||||||
| 22. | 100 | ascorbic acid/NaA | 500 |
Investigation-Name: Table 1
Sacrificial electron donor
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
