Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH: Difference between revisions

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M  V30 END CTAB
M  V30 END CTAB
M  END
M  END
</chemform><chemform smiles="C12N3[Mn+]([C-]#[O+])([C-]#[O+])([C-]#[O+])(N#CC)N4=CC=CC(C(=O)C(=O)C=1C=CC=3)=C24" inchikey="OYUJSMZZRTUSDV-UHFFFAOYSA-N" inchi="1S/C12H6N2O2.C2H3N.3CO.Mn/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;1-2-3;3*1-2;/h1-6H;1H3;;;;/q;;;;;+1" float="none" width="200" height="200">
</chemform><chemform smiles="C12N3[Mn+]([C-]#[O+])([C-]#[O+])([C-]#[O+])(N#CC)N4=CC=CC(C(=O)C(=O)C=1C=CC=3)=C24.F[P-](F)(F)(F)(F)F" inchikey="JWEFEWAAUDGGIH-UHFFFAOYSA-N" inchi="1S/C12H6N2O2.C2H3N.3CO.F6P.Mn/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;1-2-3;3*1-2;1-7(2,3,4,5)6;/h1-6H;1H3;;;;;/q;;;;;-1;+1" float="none" width="200" height="200">
   -INDIGO-01102415462D
   -INDIGO-01102415522D


   0  0  0  0  0  0  0  0  0  0  0 V3000
   0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 BEGIN CTAB
M  V30 COUNTS 26 29 0 0 0
M  V30 COUNTS 33 35 0 0 0
M  V30 BEGIN ATOM
M  V30 BEGIN ATOM
M  V30 1 C 8.22511 -3.34193 0.0 0
M  V30 1 C 8.22511 -3.34193 0.0 0
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M  V30 25 C 11.5909 -4.96618 0.0 0
M  V30 25 C 11.5909 -4.96618 0.0 0
M  V30 26 C 12.3319 -4.95736 0.0 0
M  V30 26 C 12.3319 -4.95736 0.0 0
M  V30 27 F 12.617 -2.25 0.0 0
M  V30 28 P 13.483 -1.75 0.0 0 CHG=-1
M  V30 29 F 14.349 -2.25 0.0 0
M  V30 30 F 13.483 -0.75 0.0 0
M  V30 31 F 14.349 -1.25 0.0 0
M  V30 32 F 12.617 -1.25 0.0 0
M  V30 33 F 13.483 -2.75 0.0 0
M  V30 END ATOM
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 BEGIN BOND
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M  V30 28 3 18 25
M  V30 28 3 18 25
M  V30 29 1 25 26
M  V30 29 1 25 26
M  V30 30 1 27 28
M  V30 31 1 28 29
M  V30 32 1 28 30
M  V30 33 1 28 31
M  V30 34 1 28 32
M  V30 35 1 28 33
M  V30 END BOND
M  V30 END BOND
M  V30 END CTAB
M  V30 END CTAB

Revision as of 15:53, 10 January 2024


Catalyst

Mn(phdk)(CO)3(MeCN) Mn(phen)(CO)3Br Mn(bpy)(CO)3Br

Photosensitizer

Ru(bpy)3Cl2

Investigation

  1. REDIRECT Photocatalytic CO2 reduction with the Mn complexes under various conditions.
Investigation-Name: Table 1

Sacrificial electron donor

BNAHTEOA

Investigations

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