Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate: Difference between revisions

Revision as of 12:47, 30 November 2023

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	.	.	.	.	TON HCOOH	.	.	.
1.	Ni(pbi)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O					14000
2.	Ni(pbt)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O					13100

Investigation-Name: Table 1

DOI	10.1021/jacs.0c08145
Authors	Sung Eun Lee, Azam Nasirian, Ye Eun Kim, Pegah Tavakoli Fard, Youngmee Kim, Byeongmoon Jeong, Sung-Jin Kim, Jin-Ook Baeg, Jinheung Kim,
Submitted	19.10.2020
Published online	19.10.2020
Licenses	https://doi.org/10.15223/policy-029, https://doi.org/10.15223/policy-037, https://doi.org/10.15223/policy-045,
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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@@ Line 3: / Line 3: @@
 ==== Catalyst====
-<chemform smiles="C1C=CC=N2[Ni+]3([S-]C4N3=CC=CC=4)3([S-]C4=CC=CC=N43)N3=C(NC4C=CC=CC=43)C=12" inchikey="VEKXLADSICNUAQ-UHFFFAOYSA-L" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+1/p-2" float="none" width="200" height="200">
+<chemform smiles="C1C=CC=N2[Ni+2]3([S-]C4N3=CC=CC=4)3([S-]C4=CC=CC=N43)N3=C(NC4C=CC=CC=43)C=12" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" float="none" width="200" height="200">
-   -INDIGO-11302312452D
+   -INDIGO-11302312462D
   0  0  0  0  0  0  0  0  0  0 V3000
@@ Line 38: / Line 38: @@
 M  V30 27 C 8.93402 -8.69908 0.0 0
 M  V30 28 S 7.12277 -8.08302 0.0 0 CHG=-1
-M  V30 29 Ni 7.04952 -6.51544 0.0 0 CHG=1
+M  V30 29 Ni 7.04952 -6.51544 0.0 0 CHG=2
 M  V30 30 S 6.97788 -5.00244 0.0 0 CHG=-1
 M  V30 END ATOM