Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate: Difference between revisions
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==== Catalyst==== | ==== Catalyst==== | ||
<chemform smiles="C1C=CC=N2[Ni+2]3([S-]C4=CC=CC=N43)(N3=C(NC4C=CC=CC=43)C=12)1[S-]C2N1=CC=CC=2" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" height="200px" width="300px" float="none"> | <chemform smiles="C1C=CC=N2[Ni+2]3([S-]C4=CC=CC=N43)(N3=C(NC4C=CC=CC=43)C=12)1[S-]C2N1=CC=CC=2" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" height="200px" width="300px" float="none"> | ||
-INDIGO- | -INDIGO-11282314192D | ||
0 0 0 0 0 0 0 0 0 0 0 V3000 | 0 0 0 0 0 0 0 0 0 0 0 V3000 | ||
| Line 10: | Line 10: | ||
M V30 COUNTS 30 37 0 0 0 | M V30 COUNTS 30 37 0 0 0 | ||
M V30 BEGIN ATOM | M V30 BEGIN ATOM | ||
M V30 1 C | M V30 1 C 4.22629 -7.80601 0.0 0 | ||
M V30 2 N 5. | M V30 2 N 5.90948 -7.56855 0.0 0 | ||
M V30 3 C 4. | M V30 3 C 4.96703 -7.24549 0.0 0 | ||
M V30 4 C | M V30 4 C 6.08213 -8.50205 0.0 0 | ||
M V30 5 C | M V30 5 C 4.36141 -8.74382 0.0 0 | ||
M V30 6 C | M V30 6 C 5.29809 -9.11534 0.0 0 | ||
M V30 7 C 4. | M V30 7 C 4.92207 -6.38756 0.0 0 | ||
M V30 8 N 4. | M V30 8 N 4.11814 -5.81174 0.0 0 | ||
M V30 9 C 4. | M V30 9 C 4.47217 -4.9117 0.0 0 | ||
M V30 10 C 5. | M V30 10 C 5.45493 -4.93524 0.0 0 | ||
M V30 11 N 5. | M V30 11 N 5.71267 -5.91607 0.0 0 | ||
M V30 12 C 3. | M V30 12 C 3.95563 -4.10265 0.0 0 | ||
M V30 13 C 4. | M V30 13 C 4.43773 -3.2562 0.0 0 | ||
M V30 14 C 5. | M V30 14 C 5.97573 -4.1409 0.0 0 | ||
M V30 15 C 5. | M V30 15 C 5.46132 -3.25564 0.0 0 | ||
M V30 16 C | M V30 16 C 8.19043 -5.02095 0.0 0 | ||
M V30 17 C 9. | M V30 17 C 9.64906 -4.15013 0.0 0 | ||
M V30 18 C 8. | M V30 18 C 8.6395 -4.13871 0.0 0 | ||
M V30 19 C | M V30 19 C 10.0934 -5.02704 0.0 0 | ||
M V30 20 N 8. | M V30 20 N 8.55109 -5.74026 0.0 0 | ||
M V30 21 C 9. | M V30 21 C 9.5156 -5.85055 0.0 0 | ||
M V30 22 N 8. | M V30 22 N 8.5589 -7.14296 0.0 0 | ||
M V30 23 C | M V30 23 C 10.2084 -7.55589 0.0 0 | ||
M V30 24 C 9. | M V30 24 C 9.5038 -6.86005 0.0 0 | ||
M V30 25 C 9. | M V30 25 C 9.92498 -8.50582 0.0 0 | ||
M V30 26 C 8. | M V30 26 C 8.33576 -7.91156 0.0 0 | ||
M V30 27 C 8. | M V30 27 C 8.93402 -8.69908 0.0 0 | ||
M V30 28 S | M V30 28 S 6.97788 -5.00244 0.0 0 CHG=-1 | ||
M V30 29 S 7. | M V30 29 S 7.12277 -8.08302 0.0 0 CHG=-1 | ||
M V30 30 Ni 7. | M V30 30 Ni 7.04952 -6.51544 0.0 0 CHG=2 | ||
M V30 END ATOM | M V30 END ATOM | ||
M V30 BEGIN BOND | M V30 BEGIN BOND | ||
Revision as of 14:19, 28 November 2023
Catalyst
Photosensitizer
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | . | TON HCOOH | . | . | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.004 | 2 | 0.4 | 14000 | |||||||||||
| 2. | 0.004 | 2 | 0.4 | 13100 |
Investigation-Name: Table 1
Sacrificial electron donor
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
