Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands: Difference between revisions

Revision as of 16:29, 27 November 2023

Catalyst

Photosensitizer

Investigation

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON H2	TON HCOOH
1.	Ru(py)-(MeNdpp)2(CO)2Cl	0.025	[Ru(bpy)3][PF6]	0.025	TEOA	DMF	405		380
2.	Ru(py)-(MeNdpp)2(CO)2Cl	0.05	[Ru(bpy)3][PF6]	0.05	TEOA	DMF	405		210
3.	Ru(py)-(MeNdpp)2(CO)2Cl	0.1	[Ru(bpy)3][PF6]	0.1	TEOA	DMF	405	57.5	363
4.	Ru(py)-(MeNdpp)2(CO)2Cl	0.5	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	14	162
5.	Ru(py)-(MeNdpp)2(CO)2Cl	1	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	13.3	90.5
6.	Ru(py)-(HNdpp)2(CO)2Cl	0.5	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	14	70.5
7.	Ru(py)-(HNdpp)2(CO)2Cl	1	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	12	44.5
8.	Ru(py)-(HNdpp)2(CO)2Cl	2	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	9.3	41.5

Investigation-Name: Table 1

Sacrificial electron donor

TEOA

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1002/cssc.201901326
Authors	Yasmeen Hameed, Gyandshwar Kumar Rao, Jeffrey S. Ovens, Bulat Gabidullin, Darrin Richeson,
Submitted	11.06.2019
Published online	03.07.2019
Licenses	http://onlinelibrary.wiley.com/termsAndConditions#vor, http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects	General Energy, General Materials Science, General Chemical Engineering, Environmental Chemistry
Go to literature page

@@ Line 127: / Line 127: @@
 ====Photosensitizer====
-{{#moleculelink:|link=HNVRWFFXWFXICS-UHFFFAOYSA-N|image=true}}
+<chemform smiles="C1C=CN2[Ru+2]3(N4=CC=CC=C4C4=CC=CC=N43)(N3=CC=CC=C3C=2C=1)1N2C(C3N1=CC=CC=3)=CC=CC=2.[P-](F)(F)(F)(F)(F)F.[P-](F)(F)(F)(F)(F)F" inchi="1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2" inchikey="KLDYQWXVZLHTKT-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-11272316292D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 51 57 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 8.40037 -1.10079 0.0 0
+M  V30 2 C 9.26594 -2.59904 0.0 0
+M  V30 3 C 9.26687 -1.6014 0.0 0
+M  V30 4 N 8.3991 -3.09951 0.0 0
+M  V30 5 C 7.53006 -1.60327 0.0 0
+M  V30 6 C 7.53586 -2.60333 0.0 0
+M  V30 7 C 10.132 -3.09904 0.0 0
+M  V30 8 C 11.8623 -3.09739 0.0 0
+M  V30 9 C 10.9984 -2.59835 0.0 0
+M  V30 10 C 11.8629 -4.09833 0.0 0
+M  V30 11 N 10.1326 -4.10398 0.0 0
+M  V30 12 C 11.0019 -4.59841 0.0 0
+M  V30 13 N 10.1848 -6.15007 0.0 0
+M  V30 14 C 11.9152 -6.14959 0.0 0
+M  V30 15 C 11.0516 -5.64997 0.0 0
+M  V30 16 C 11.9152 -7.15053 0.0 0
+M  V30 17 C 10.1848 -7.15502 0.0 0
+M  V30 18 C 11.0538 -7.65003 0.0 0
+M  V30 19 C 9.31882 -7.65502 0.0 0
+M  V30 20 C 8.4551 -9.15433 0.0 0
+M  V30 21 C 9.31921 -8.65573 0.0 0
+M  V30 22 C 7.58792 -8.65444 0.0 0
+M  V30 23 N 8.44818 -7.15313 0.0 0
+M  V30 24 C 7.58534 -7.65875 0.0 0
+M  V30 25 C 4.83485 -6.20007 0.0 0
+M  V30 26 N 6.56515 -6.19959 0.0 0
+M  V30 27 C 5.70164 -5.69997 0.0 0
+M  V30 28 C 6.56515 -7.20053 0.0 0
+M  V30 29 C 4.83485 -7.20502 0.0 0
+M  V30 30 C 5.70382 -7.70003 0.0 0
+M  V30 31 C 5.70164 -4.69997 0.0 0
+M  V30 32 C 4.83506 -3.20231 0.0 0
+M  V30 33 C 4.8348 -4.19994 0.0 0
+M  V30 34 C 5.70157 -2.70125 0.0 0
+M  V30 35 N 6.57161 -4.19691 0.0 0
+M  V30 36 C 6.56515 -3.19686 0.0 0
+M  V30 37 Ru 8.44661 -5.11294 0.0 0 CHG=2
+M  V30 38 P 14.442 -2.725 0.0 0 CHG=-1
+M  V30 39 F 15.308 -2.225 0.0 0
+M  V30 40 F 13.576 -2.225 0.0 0
+M  V30 41 F 14.442 -3.725 0.0 0
+M  V30 42 F 15.308 -3.225 0.0 0
+M  V30 43 F 14.442 -1.725 0.0 0
+M  V30 44 F 13.576 -3.225 0.0 0
+M  V30 45 P 14.5 -5.675 0.0 0 CHG=-1
+M  V30 46 F 15.366 -5.175 0.0 0
+M  V30 47 F 13.634 -5.175 0.0 0
+M  V30 48 F 14.5 -6.675 0.0 0
+M  V30 49 F 15.366 -6.175 0.0 0
+M  V30 50 F 14.5 -4.675 0.0 0
+M  V30 51 F 13.634 -6.175 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 2 7
+M  V30 8 2 9 7
+M  V30 9 2 10 8
+M  V30 10 1 7 11
+M  V30 11 1 8 9
+M  V30 12 2 11 12
+M  V30 13 1 12 10
+M  V30 14 2 15 13
+M  V30 15 2 16 14
+M  V30 16 1 13 17
+M  V30 17 1 14 15
+M  V30 18 2 17 18
+M  V30 19 1 18 16
+M  V30 20 1 17 19
+M  V30 21 2 21 19
+M  V30 22 2 22 20
+M  V30 23 1 19 23
+M  V30 24 1 20 21
+M  V30 25 2 23 24
+M  V30 26 1 24 22
+M  V30 27 2 27 25
+M  V30 28 2 28 26
+M  V30 29 1 25 29
+M  V30 30 1 26 27
+M  V30 31 2 29 30
+M  V30 32 1 30 28
+M  V30 33 1 27 31
+M  V30 34 2 33 31
+M  V30 35 2 34 32
+M  V30 36 1 31 35
+M  V30 37 1 32 33
+M  V30 38 2 35 36
+M  V30 39 1 36 34
+M  V30 40 10 35 37
+M  V30 41 10 37 26
+M  V30 42 10 37 4
+M  V30 43 10 11 37
+M  V30 44 10 37 13
+M  V30 45 10 23 37
+M  V30 46 1 38 39
+M  V30 47 1 38 40
+M  V30 48 1 38 41
+M  V30 49 1 38 42
+M  V30 50 1 38 43
+M  V30 51 1 38 44
+M  V30 52 1 45 46
+M  V30 53 1 45 47
+M  V30 54 1 45 48
+M  V30 55 1 45 49
+M  V30 56 1 45 50
+M  V30 57 1 45 51
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
 ====Investigation====

Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands: Difference between revisions

Revision as of 16:29, 27 November 2023

Contents

Catalyst

Photosensitizer

Investigation

Sacrificial electron donor

Investigations

Topics

Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands: Difference between revisions

Revision as of 16:29, 27 November 2023

Catalyst

Photosensitizer

Investigation

Sacrificial electron donor

Investigations

Current site

Topics