Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis: Difference between revisions
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====Photosensitizer==== | ====Photosensitizer==== | ||
<chemform smiles="" inchi="" inchikey="" height="200px" width="300px" float="none"> -INDIGO-08012317142D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 44 51 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C 4.03485 -3.90007 0.0 0 | |||
M V30 2 C 5.76515 -3.89959 0.0 0 | |||
M V30 3 C 4.90164 -3.39997 0.0 0 | |||
M V30 4 C 5.76515 -4.90053 0.0 0 CHG=-1 | |||
M V30 5 C 4.03485 -4.90502 0.0 0 | |||
M V30 6 C 4.90382 -5.40003 0.0 0 | |||
M V30 7 C 6.63141 -3.39999 0.0 0 | |||
M V30 8 C 7.49583 -1.90109 0.0 0 | |||
M V30 9 C 6.63149 -2.39928 0.0 0 | |||
M V30 10 C 8.36278 -2.40138 0.0 0 | |||
M V30 11 N 7.50182 -3.90229 0.0 0 | |||
M V30 12 C 8.3649 -3.39706 0.0 0 | |||
M V30 13 C 4.08485 -6.82507 0.0 0 | |||
M V30 14 C 5.81515 -6.82459 0.0 0 CHG=-1 | |||
M V30 15 C 4.95164 -6.32497 0.0 0 | |||
M V30 16 C 5.81515 -7.82553 0.0 0 | |||
M V30 17 C 4.08485 -7.83002 0.0 0 | |||
M V30 18 C 4.95382 -8.32503 0.0 0 | |||
M V30 19 C 6.68166 -8.3247 0.0 0 | |||
M V30 20 C 8.41196 -8.32139 0.0 0 | |||
M V30 21 N 7.54763 -7.82318 0.0 0 | |||
M V30 22 C 8.41359 -9.32233 0.0 0 | |||
M V30 23 C 6.6833 -9.32964 0.0 0 | |||
M V30 24 C 7.55308 -9.82324 0.0 0 | |||
M V30 25 C 9.35985 -3.77507 0.0 0 | |||
M V30 26 C 11.0902 -3.77459 0.0 0 | |||
M V30 27 C 10.2266 -3.27497 0.0 0 | |||
M V30 28 C 11.0902 -4.77553 0.0 0 | |||
M V30 29 N 9.35985 -4.78002 0.0 0 | |||
M V30 30 C 10.2288 -5.27503 0.0 0 | |||
M V30 31 C 10.2327 -6.27503 0.0 0 | |||
M V30 32 C 11.105 -7.76933 0.0 0 | |||
M V30 33 C 11.1014 -6.7717 0.0 0 | |||
M V30 34 C 10.2405 -8.27372 0.0 0 | |||
M V30 35 N 9.36465 -6.78143 0.0 0 | |||
M V30 36 C 9.37498 -7.78146 0.0 0 | |||
M V30 37 Ir 7.55 -5.775 0.0 0 CHG=3 | |||
M V30 38 P 13.517 -3.7 0.0 0 CHG=-1 | |||
M V30 39 F 14.383 -3.2 0.0 0 | |||
M V30 40 F 12.651 -3.2 0.0 0 | |||
M V30 41 F 13.517 -4.7 0.0 0 | |||
M V30 42 F 14.383 -4.2 0.0 0 | |||
M V30 43 F 13.517 -2.7 0.0 0 | |||
M V30 44 F 12.651 -4.2 0.0 0 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 2 3 1 | |||
M V30 2 2 4 2 | |||
M V30 3 1 1 5 | |||
M V30 4 1 2 3 | |||
M V30 5 2 5 6 | |||
M V30 6 1 6 4 | |||
M V30 7 1 2 7 | |||
M V30 8 2 9 7 | |||
M V30 9 2 10 8 | |||
M V30 10 1 7 11 | |||
M V30 11 1 8 9 | |||
M V30 12 2 11 12 | |||
M V30 13 1 12 10 | |||
M V30 14 2 15 13 | |||
M V30 15 2 16 14 | |||
M V30 16 1 13 17 | |||
M V30 17 1 14 15 | |||
M V30 18 2 17 18 | |||
M V30 19 1 18 16 | |||
M V30 20 1 16 19 | |||
M V30 21 2 21 19 | |||
M V30 22 2 22 20 | |||
M V30 23 1 19 23 | |||
M V30 24 1 20 21 | |||
M V30 25 2 23 24 | |||
M V30 26 1 24 22 | |||
M V30 27 2 27 25 | |||
M V30 28 2 28 26 | |||
M V30 29 1 25 29 | |||
M V30 30 1 26 27 | |||
M V30 31 2 29 30 | |||
M V30 32 1 30 28 | |||
M V30 33 1 30 31 | |||
M V30 34 2 33 31 | |||
M V30 35 2 34 32 | |||
M V30 36 1 31 35 | |||
M V30 37 1 32 33 | |||
M V30 38 2 35 36 | |||
M V30 39 1 36 34 | |||
M V30 40 10 11 37 | |||
M V30 41 10 37 29 | |||
M V30 42 10 35 37 | |||
M V30 43 10 37 21 | |||
M V30 44 10 14 37 | |||
M V30 45 10 37 4 | |||
M V30 46 1 38 39 | |||
M V30 47 1 38 40 | |||
M V30 48 1 38 41 | |||
M V30 49 1 38 42 | |||
M V30 50 1 38 43 | |||
M V30 51 1 38 44 | |||
M V30 END BOND | |||
M V30 END CTAB | |||
M END</chemform>{{#moleculelink:|link=UEEXRMUCXBPYOV-UHFFFAOYSA-N|image=true}} | |||
====Investigation==== | ====Investigation==== |
Revision as of 16:33, 1 August 2023
Missing SI data |
This page or an investigation on this page is missing important data. It might be included in the Supporting Information of the publication.
|
Catalyst
Molecule with key NRVILUOLTIKJEU-NGWNFTKISA-I does not exist.
Photosensitizer
Molecule with key UEEXRMUCXBPYOV-UHFFFAOYSA-N does not exist.
Investigation
Investigation-Name: Table 1
Investigation-Name: Table 2 - CV
Sacrificial electron donor
Additives
Investigations
- Cyclic voltammetry in various conditions (Assay, Cyclic Voltammetry experiments)
- Photocatalytic reduction of CO2: conditions optimization (Molecular process, Photocatalytic CO2 conversion experiments)