Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 16:15, 1 August 2023

Missing investigation

This page about a publication or dataset does not currently include an investigation. Please add any experiments detailed in the publication or performed to obtain this dataset.

Faulty molecule

A molecule on this page has a mistake in its structure or is missing a part. Please edit the structure or redraw a new molecule using the replace molecule workflow.

Investigations

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	1	2	13
2.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	2	4	21
3.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	13	8	62
4.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	8	8	34
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	7	9	40
6.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	4	27

Experiment-Name: Table 1

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ru(bpy)2Cl2	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	9	26
2.	Ru(bpy)2CO3	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	11	39
3.	[Ru(bpy)2ClCO][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	19	19	117
4.	[Ru(bpy)2HCO][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	21	16	107
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	21	14	75
6.	[Ru(bpy)(AcMe)2][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	4	12	64
7.	[Ru(bpy)2ClCO][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	36	33	296
8.	[Ru(bpy)2HCO][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	16	29	145
9.	[Ru(bpy)(H2O)(CO)][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	34	28	211
10.	[Ru(bpy)2ClCO][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	40	67	419
11.	[Ru(bpy)2HCO][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	25	62	225
12.	[Ru(bpy)(H2O)(CO)][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	45	65	335
13.	[Ru(bpy)(AcMe)2][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	4	44	75

Experiment-Name: Table 2

	analyte	reduction potential	solvent	electrolyte	WE	RE
1.	Ru(bpy)2Cl2	0,-2.11	MeCN	TBABF4	glassy carbon	Ag/AgNO3 in MeCN
2.	Ru(bpy)2CO3	0.45,-1.97	MeCN	TBABF4	glassy carbon	Ag/AgNO3 in MeCN
3.	[Ru(bpy)2ClCO][PF6]	1.22,-1.75	MeCN	TBABF4	glassy carbon	Ag/AgNO3 in MeCN
4.	[Ru(bpy)2HCO][PF6]	1.20,-1.61	MeCN	TBABF4	glassy carbon	Ag/AgNO3 in MeCN

Experiment-Name: Table 3 - CV

Investigations

CO2 reduction experiments (Molecular process, Photocatalytic CO2 conversion experiments)
Optimization of concentrations (Molecular process, Photocatalytic CO2 conversion experiments)
Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 2 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 3 - CV (Assay, Cyclic Voltammetry experiments)

DOI	10.1002/cctc.201500494
Authors	Alonso Rosas-Hernández, Henrik Junge, Matthias Beller,
Submitted	26.08.2015
Published online	26.08.2015
Licenses	http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects	Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Catalysis
Go to literature page

@@ Line 463: / Line 463: @@
 M  V30 44 1 35 13
 M  V30 45 8 33 31
+M  V30 46 1 38 39
+M  V30 47 1 38 40
+M  V30 48 1 38 41
+M  V30 49 1 38 42
+M  V30 50 1 38 43
+M  V30 51 1 38 44
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform><chemform smiles="C1C=C[C-]2[Ir+3]3([C-]4C=CC=CC=4C4C=CC=CN=43)3(N4=CC=CC=C4C4C=CC=CN=43)N3=CC=CC=C3C=2C=1.[P-](F)(F)(F)(F)(F)F" inchi="1S/2C11H8N.C10H8N2.F6P.Ir/c2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-7(2,3,4,5)6;/h2*1-6,8-9H;1-8H;;/q2*-1;;-1;+3" inchikey="RJJGJTKSOSSNNL-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-08012317142D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 44 51 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 4.03485 -3.90007 0.0 0
+M  V30 2 C 5.76515 -3.89959 0.0 0
+M  V30 3 C 4.90164 -3.39997 0.0 0
+M  V30 4 C 5.76515 -4.90053 0.0 0 CHG=-1
+M  V30 5 C 4.03485 -4.90502 0.0 0
+M  V30 6 C 4.90382 -5.40003 0.0 0
+M  V30 7 C 6.63141 -3.39999 0.0 0
+M  V30 8 C 7.49583 -1.90109 0.0 0
+M  V30 9 C 6.63149 -2.39928 0.0 0
+M  V30 10 C 8.36278 -2.40138 0.0 0
+M  V30 11 N 7.50182 -3.90229 0.0 0
+M  V30 12 C 8.3649 -3.39706 0.0 0
+M  V30 13 C 4.08485 -6.82507 0.0 0
+M  V30 14 C 5.81515 -6.82459 0.0 0 CHG=-1
+M  V30 15 C 4.95164 -6.32497 0.0 0
+M  V30 16 C 5.81515 -7.82553 0.0 0
+M  V30 17 C 4.08485 -7.83002 0.0 0
+M  V30 18 C 4.95382 -8.32503 0.0 0
+M  V30 19 C 6.68166 -8.3247 0.0 0
+M  V30 20 C 8.41196 -8.32139 0.0 0
+M  V30 21 N 7.54763 -7.82318 0.0 0
+M  V30 22 C 8.41359 -9.32233 0.0 0
+M  V30 23 C 6.6833 -9.32964 0.0 0
+M  V30 24 C 7.55308 -9.82324 0.0 0
+M  V30 25 C 9.35985 -3.77507 0.0 0
+M  V30 26 C 11.0902 -3.77459 0.0 0
+M  V30 27 C 10.2266 -3.27497 0.0 0
+M  V30 28 C 11.0902 -4.77553 0.0 0
+M  V30 29 N 9.35985 -4.78002 0.0 0
+M  V30 30 C 10.2288 -5.27503 0.0 0
+M  V30 31 C 10.2327 -6.27503 0.0 0
+M  V30 32 C 11.105 -7.76933 0.0 0
+M  V30 33 C 11.1014 -6.7717 0.0 0
+M  V30 34 C 10.2405 -8.27372 0.0 0
+M  V30 35 N 9.36465 -6.78143 0.0 0
+M  V30 36 C 9.37498 -7.78146 0.0 0
+M  V30 37 Ir 7.55 -5.775 0.0 0 CHG=3
+M  V30 38 P 13.517 -3.7 0.0 0 CHG=-1
+M  V30 39 F 14.383 -3.2 0.0 0
+M  V30 40 F 12.651 -3.2 0.0 0
+M  V30 41 F 13.517 -4.7 0.0 0
+M  V30 42 F 14.383 -4.2 0.0 0
+M  V30 43 F 13.517 -2.7 0.0 0
+M  V30 44 F 12.651 -4.2 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 2 7
+M  V30 8 2 9 7
+M  V30 9 2 10 8
+M  V30 10 1 7 11
+M  V30 11 1 8 9
+M  V30 12 2 11 12
+M  V30 13 1 12 10
+M  V30 14 2 15 13
+M  V30 15 2 16 14
+M  V30 16 1 13 17
+M  V30 17 1 14 15
+M  V30 18 2 17 18
+M  V30 19 1 18 16
+M  V30 20 1 16 19
+M  V30 21 2 21 19
+M  V30 22 2 22 20
+M  V30 23 1 19 23
+M  V30 24 1 20 21
+M  V30 25 2 23 24
+M  V30 26 1 24 22
+M  V30 27 2 27 25
+M  V30 28 2 28 26
+M  V30 29 1 25 29
+M  V30 30 1 26 27
+M  V30 31 2 29 30
+M  V30 32 1 30 28
+M  V30 33 1 30 31
+M  V30 34 2 33 31
+M  V30 35 2 34 32
+M  V30 36 1 31 35
+M  V30 37 1 32 33
+M  V30 38 2 35 36
+M  V30 39 1 36 34
+M  V30 40 10 11 37
+M  V30 41 10 37 29
+M  V30 42 10 35 37
+M  V30 43 10 37 21
+M  V30 44 10 14 37
+M  V30 45 10 37 4
 M  V30 46 1 38 39
 M  V30 47 1 38 40

Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 16:15, 1 August 2023

Contents

Catalysts

Photosensitizer

Sacrificial electron donor

Investigations

Investigations

Topics

Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 16:15, 1 August 2023

Catalysts

Photosensitizer

Sacrificial electron donor

Investigations

Investigations

Current site

Topics