Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate: Difference between revisions

From ChemWiki
publication
About
DOI 10.1021/jacs.0c08145
Authors Sung Eun Lee, Azam Nasirian, Ye Eun Kim, Pegah Tavakoli Fard, Youngmee Kim, Byeongmoon Jeong, Sung-Jin Kim, Jin-Ook Baeg, Jinheung Kim,
Submitted 19.10.2020
Published online 19.10.2020
Licenses https://doi.org/10.15223/policy-029, https://doi.org/10.15223/policy-037, https://doi.org/10.15223/policy-045,
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
Go to literature page
(Added molecules)
(Swap to Molecule link)
Line 2: Line 2:
{{#doiinfobox: 10.1021/jacs.0c08145}}
{{#doiinfobox: 10.1021/jacs.0c08145}}


==== Investigation ====
==== Catalyst====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
 
==== Catalyst ====
<chemform smiles="C1C=CC=N2[Ni]3(~SC4=CC=CC=N43)(N3=C(NC4C=CC=CC=43)C=12)1~SC2N1=CC=CC=2" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" height="200px" width="300px" float="none">
<chemform smiles="C1C=CC=N2[Ni]3(~SC4=CC=CC=N43)(N3=C(NC4C=CC=CC=43)C=12)1~SC2N1=CC=CC=2" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" height="200px" width="300px" float="none">
   -INDIGO-01252311222D
   -INDIGO-01252311222D
Line 166: Line 163:
</chemform>
</chemform>


==== Photosensitizer ====
====Photosensitizer====
<chemform smiles="" inchi="" inchikey="SEACYXSIPDVVMV-UHFFFAOYSA-L " height="200px" width="300px" float="none"></chemform>
{{#moleculelink:|link=SEACYXSIPDVVMV-UHFFFAOYSA-L|image=true}}
 
====Investigation====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}


==== Sacrificial electron donor ====
==== Sacrificial electron donor====
<chemform smiles="" inchi="" inchikey="GSEJCLTVZPLZKY-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}}
[[Category:Photocatalytic CO2 conversion to HCOOH]]
[[Category:Photocatalytic CO2 conversion to HCOOH]]

Revision as of 10:34, 7 July 2023


Catalyst

Ni(pbi)(pyS)2 Ni(pbt)(pyS)2

Photosensitizer

Eosin Y

Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A....TON HCOOH...
1.

Ni(pbi)(pyS)2

0.004

Eosin Y

2

TEOA

0.4

H2O

14000
2.

Ni(pbt)(pyS)2

0.004

Eosin Y

2

TEOA

0.4

H2O

13100
Investigation-Name: Table 1

Sacrificial electron donor

TEOA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)