Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate: Difference between revisions
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{{#doiinfobox: 10.1021/jacs.0c08145}} | {{#doiinfobox: 10.1021/jacs.0c08145}} | ||
==== Catalyst==== | |||
==== Catalyst ==== | |||
<chemform smiles="C1C=CC=N2[Ni]3(~SC4=CC=CC=N43)(N3=C(NC4C=CC=CC=43)C=12)1~SC2N1=CC=CC=2" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" height="200px" width="300px" float="none"> | <chemform smiles="C1C=CC=N2[Ni]3(~SC4=CC=CC=N43)(N3=C(NC4C=CC=CC=43)C=12)1~SC2N1=CC=CC=2" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" height="200px" width="300px" float="none"> | ||
-INDIGO-01252311222D | -INDIGO-01252311222D | ||
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</chemform> | </chemform> | ||
==== Photosensitizer ==== | ====Photosensitizer==== | ||
{{#moleculelink:|link=SEACYXSIPDVVMV-UHFFFAOYSA-L|image=true}} | |||
====Investigation==== | |||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | |||
==== Sacrificial electron donor ==== | ==== Sacrificial electron donor==== | ||
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}} | |||
[[Category:Photocatalytic CO2 conversion to HCOOH]] | [[Category:Photocatalytic CO2 conversion to HCOOH]] |
Revision as of 10:34, 7 July 2023
Catalyst
Photosensitizer
Investigation
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | . | TON HCOOH | . | . | . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1. | 0.004 | 2 | 0.4 | 14000 | |||||||||||
2. | 0.004 | 2 | 0.4 | 13100 |
Investigation-Name: Table 1
Sacrificial electron donor
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)