Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction: Difference between revisions
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{{#doiinfobox: 10.1039/c6sc01913g}}{{MissingInvestigation}} | {{#doiinfobox: 10.1039/c6sc01913g}}{{MissingInvestigation}} | ||
==== Catalyst==== | |||
==== Catalyst ==== | |||
<chemform smiles="C1C=C2C3C=CC=CN=3[Re+](C#O)(N#CC)(C#O)(C#O)N2=CC=1.[*]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="PF6-"> | <chemform smiles="C1C=C2C3C=CC=CN=3[Re+](C#O)(N#CC)(C#O)(C#O)N2=CC=1.[*]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="PF6-"> | ||
-INDIGO-05042311362D | -INDIGO-05042311362D | ||
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</chemform> | </chemform> | ||
==== Photosensitizer ==== | ====Photosensitizer ==== | ||
<chemform smiles="C1C=C2P(C3C=CC=CC=3)(C3C=CC=CC=3)~[Re+]3(N4=C(C5N3=CC([*])=C([*])C=5)C=C([*])C([*])=C4)(C#O)(C#O)~P(C3C=CC=CC=3)(C3C=CC=CC=3)C3C=CC(P(C4C=CC=CC=4)(C4C=CC=CC=4)~[Re+]4(N5=C(C6N4=CC([*])=C([*])C=6)C=C([*])C([*])=C5)(C#O)(C#O)~P(C4C=CC=CC=4)(C4C=CC=CC=4)C4C=CC(P(C5C=CC=CC=5)(C5C=CC=CC=5)~[Re+]5(N6=CC([*])=C([*])C=C6C6C=C([*])C([*])=CN=65)(C#O)(C#O)~P(C5C=CC=CC=5)(C5C=CC=CC=5)C=1C=C2)=CC=4)=CC=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="CH3,H,CH3,H" r2="H,CH3,CH3,OMe"> | <chemform smiles="C1C=C2P(C3C=CC=CC=3)(C3C=CC=CC=3)~[Re+]3(N4=C(C5N3=CC([*])=C([*])C=5)C=C([*])C([*])=C4)(C#O)(C#O)~P(C3C=CC=CC=3)(C3C=CC=CC=3)C3C=CC(P(C4C=CC=CC=4)(C4C=CC=CC=4)~[Re+]4(N5=C(C6N4=CC([*])=C([*])C=6)C=C([*])C([*])=C5)(C#O)(C#O)~P(C4C=CC=CC=4)(C4C=CC=CC=4)C4C=CC(P(C5C=CC=CC=5)(C5C=CC=CC=5)~[Re+]5(N6=CC([*])=C([*])C=C6C6C=C([*])C([*])=CN=65)(C#O)(C#O)~P(C5C=CC=CC=5)(C5C=CC=CC=5)C=1C=C2)=CC=4)=CC=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="CH3,H,CH3,H" r2="H,CH3,CH3,OMe"> | ||
-INDIGO-04202312202D | -INDIGO-04202312202D | ||
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M END | M END | ||
</chemform> | </chemform> | ||
====Investigation==== | |||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=}}{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 2}} | |||
==== Sacrificial electron donor ==== | ==== Sacrificial electron donor ==== | ||
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}} | |||
[[Category:Photocatalytic CO2 conversion to HCOOH]] | [[Category:Photocatalytic CO2 conversion to HCOOH]] | ||
Revision as of 10:32, 7 July 2023
 Missing investigation
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This page about a publication or dataset does not currently include an investigation. Please add any experiments detailed in the publication or performed to obtain this dataset.
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Catalyst
Photosensitizer
Investigation
Experiment 'Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction/' does not exist.
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | λexc [nm] | . | TON CO | TON H2 | TON HCOOH | . | . | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.05 | 0.05 | 436 | 20 | 72 | 290 | |||||||||||
| 2. | 0.05 | 0.05 | 0.03 | 436 | 16 | 49 | 280 | ||||||||||
| 3. | 0.05 | 0.05 | 436 | 32 | 85 | ||||||||||||
| 4. | 0.05 | 0.05 | 0.03 | 436 | 80 | 60 |
Investigation-Name: Table 2
