Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction: Difference between revisions

Revision as of 10:30, 7 July 2023

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	[MoO(qpdt)2][NBu4]2	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	400	73	670	80
2.	[K]2[MoO(Hqpdt)2]	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	400	13	51	31
3.	[MoO(2Hqpdt)2][NBu4]	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	400	40	89	83

Investigation-Name: Table 1

DOI	10.1002/anie.201809084
Authors	Thibault Fogeron, Pascal Retailleau, Lise‐Marie Chamoreau, Yun Li, Marc Fontecave,
Submitted	13.11.2018
Published online	28.11.2018
Licenses	http://onlinelibrary.wiley.com/termsAndConditions#vor, http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects	General Chemistry, Catalysis
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@@ Line 2: / Line 2: @@
 {{#doiinfobox: 10.1002/anie.201809084}}
-==== Investigation ====
+==== Catalyst====
-{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
-==== Catalyst ====
 <chemform smiles="[Mo-2](=O)1(~SC2C3=NC4C=CC=CC=4N(C)C3OC(C)(C)C=2S~1)1~SC2C(C)(C)OC3N(C)C4C=CC=CC=4N=C3C=2S~1.[K+].[K+]" inchi="1S/2C14H16N2OS2.2K.Mo.O/c2*1-14(2)12(19)11(18)10-13(17-14)16(3)9-7-5-4-6-8(9)15-10;;;;/h2*4-7,13,18-19H,1-3H3;;;;/q;;2*+1;+2;/p-4" inchikey="ZANCFLAGIYSVGM-UHFFFAOYSA-J" height="200px" width="300px" float="none">
    -INDIGO-01242316062D
@@ Line 474: / Line 471: @@
 </chemform>
-==== Photosensitizer ====
+====Photosensitizer====
-<chemform smiles="" inchi="" inchikey="BZSVVCFHMVMYCR-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform>
+{{#moleculelink:|link=BZSVVCFHMVMYCR-UHFFFAOYSA-N|image=true}}
+====Investigation====
+{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
-==== Sacrificial electron donor ====
+==== Sacrificial electron donor====
-<chemform smiles="" inchi="" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform><chemform smiles="" inchi="" inchikey="GSEJCLTVZPLZKY-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
+{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}}
 [[Category:Photocatalytic CO2 conversion to HCOOH]]