Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst: Difference between revisions
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{{BaseTemplate}} | {{BaseTemplate}} | ||
{{#doiinfobox: 10.1021/jacs.8b09740}} | {{#doiinfobox: 10.1021/jacs.8b09740}} | ||
=== Catalyst === | ===Catalyst=== | ||
<chemform smiles="C12C(C3C=CC([N+](C)(C)C)=CC=3)=C3N4~[Fe]56~N7C(=C(C8C=CC([N+](C)(C)C)=CC=8)C8N~5C(C(C5C=CC([N+](C)(C)C)=CC=5)=C(N=1~6)C=C2)=CC=8)C=CC=7C(C1C=CC([N+](C)(C)C)=CC=1)=C4C=C3" inchi="1S/C56H62N8.Fe/c1-61(2,3)41-21-13-37(14-22-41)53-45-29-31-47(57-45)54(38-15-23-42(24-16-38)62(4,5)6)49-33-35-51(59-49)56(40-19-27-44(28-20-40)64(10,11)12)52-36-34-50(60-52)55(48-32-30-46(53)58-48)39-17-25-43(26-18-39)63(7,8)9;/h13-36,57,60H,1-12H3;/q+4;/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-;" inchikey="MXOBCRHAQPLEER-YUTFXDKVSA-N" height="200px" width="300px" float="none"> | <chemform smiles="C12C(C3C=CC([N+](C)(C)C)=CC=3)=C3N4~[Fe]56~N7C(=C(C8C=CC([N+](C)(C)C)=CC=8)C8N~5C(C(C5C=CC([N+](C)(C)C)=CC=5)=C(N=1~6)C=C2)=CC=8)C=CC=7C(C1C=CC([N+](C)(C)C)=CC=1)=C4C=C3" inchi="1S/C56H62N8.Fe/c1-61(2,3)41-21-13-37(14-22-41)53-45-29-31-47(57-45)54(38-15-23-42(24-16-38)62(4,5)6)49-33-35-51(59-49)56(40-19-27-44(28-20-40)64(10,11)12)52-36-34-50(60-52)55(48-32-30-46(53)58-48)39-17-25-43(26-18-39)63(7,8)9;/h13-36,57,60H,1-12H3;/q+4;/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-;" inchikey="MXOBCRHAQPLEER-YUTFXDKVSA-N" height="200px" width="300px" float="none"> | ||
-INDIGO-12132211272D | -INDIGO-12132211272D | ||
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</chemform> | </chemform> | ||
=== Photosensitizer === | === Photosensitizer=== | ||
<chemform smiles="C1C=CC2N(C3C=C4C=CC=CC4=CC=3)C3C=CC=CC=3N(C3C=C4C=CC=CC4=CC=3)C=2C=1" inchi="1S/C32H22N2/c1-3-11-25-21-27(19-17-23(25)9-1)33-29-13-5-7-15-31(29)34(32-16-8-6-14-30(32)33)28-20-18-24-10-2-4-12-26(24)22-28/h1-22H" inchikey="HPIOBCHPZVAATK-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | <chemform smiles="C1C=CC2N(C3C=C4C=CC=CC4=CC=3)C3C=CC=CC=3N(C3C=C4C=CC=CC4=CC=3)C=2C=1" inchi="1S/C32H22N2/c1-3-11-25-21-27(19-17-23(25)9-1)33-29-13-5-7-15-31(29)34(32-16-8-6-14-30(32)33)28-20-18-24-10-2-4-12-26(24)22-28/h1-22H" inchikey="HPIOBCHPZVAATK-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | ||
-INDIGO-12132211302D | -INDIGO-12132211302D | ||
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</chemform> | </chemform> | ||
=== Sacrificial Electron Donor === | === Investigation === | ||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | |||
===Sacrificial Electron Donor === | |||
<chemform smiles="N(C(C)C)(C(C)C)CC" inchi="1S/C8H19N/c1-6-9(7(2)3)8(4)5/h7-8H,6H2,1-5H3" inchikey="JGFZNNIVVJXRND-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | <chemform smiles="N(C(C)C)(C(C)C)CC" inchi="1S/C8H19N/c1-6-9(7(2)3)8(4)5/h7-8H,6H2,1-5H3" inchikey="JGFZNNIVVJXRND-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | ||
-INDIGO-12132211432D | -INDIGO-12132211432D | ||
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M V30 END CTAB | M V30 END CTAB | ||
M END | M END | ||
</chemform> | </chemform> | ||
{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}} | |||
=== Additives === | {{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}} | ||
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}} | |||
===Additives=== | |||
<chemform smiles="O([H])[H]" inchi="1S/H2O/h1H2" inchikey="XLYOFNOQVPJJNP-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | <chemform smiles="O([H])[H]" inchi="1S/H2O/h1H2" inchikey="XLYOFNOQVPJJNP-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | ||
-INDIGO-12132211442D | -INDIGO-12132211442D | ||
Revision as of 09:07, 7 July 2023
Catalyst
Photosensitizer
5,10-Di(2-naphthyl)-5,10-dihydrophenazine
3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine
Investigation
- REDIRECT Photocatalytic reduction of CO2
Investigation-Name: Table 1
Sacrificial Electron Donor
Additives
Investigations
- Photocatalytic reduction of CO (Molecular process, Photocatalytic CO2 conversion experiments)
- Photocatalytic reduction of CO2 (Molecular process, Photocatalytic CO2 conversion experiments)
