Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis: Difference between revisions
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{{#doiinfobox: 10.1021/acs.jpcc.8b00950}} | {{#doiinfobox: 10.1021/acs.jpcc.8b00950}} | ||
==== | ==== Catalyst==== | ||
{{# | {{#moleculelink:|link=NRVILUOLTIKJEU-NGWNFTKISA-I|image=true}} | ||
==== Photosensitizer ==== | ====Photosensitizer==== | ||
<chemform smiles="C1C=C2C3C([Ir+]4(N5C(C6N4=CC=CC=6)=CC=CC=5)4(N5C(C6C4=CC=CC=6)=CC=CC=5)N2=CC=1)=CC=CC=3" inchi="1S/2C11H9N.C10H8N2.Ir/c2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h2*1-9H;1-8H;/q;;;+1" inchikey="WEEPMIZXGXTKSO-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | <chemform smiles="C1C=C2C3C([Ir+]4(N5C(C6N4=CC=CC=6)=CC=CC=5)4(N5C(C6C4=CC=CC=6)=CC=CC=5)N2=CC=1)=CC=CC=3" inchi="1S/2C11H9N.C10H8N2.Ir/c2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h2*1-9H;1-8H;/q;;;+1" inchikey="WEEPMIZXGXTKSO-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | ||
-INDIGO-01262315082D | -INDIGO-01262315082D | ||
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M V30 END CTAB | M V30 END CTAB | ||
M END | M END | ||
</chemform> | </chemform>{{#moleculelink:|link=UEEXRMUCXBPYOV-UHFFFAOYSA-N|image=true}} | ||
====Investigation==== | |||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | |||
==== Sacrificial electron donor ==== | ====Sacrificial electron donor==== | ||
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=JGFZNNIVVJXRND-UHFFFAOYSA-N|image=true}} | |||
==== Additives ==== | ====Additives==== | ||
{{#moleculelink:|link=RHQDFWAXVIIEBN-UHFFFAOYSA-N|image=true}} | |||
[[Category:Photocatalytic CO2 conversion to CH4]] | [[Category:Photocatalytic CO2 conversion to CH4]] | ||
Revision as of 09:02, 7 July 2023
Catalyst
Molecule with key NRVILUOLTIKJEU-NGWNFTKISA-I does not exist.
Photosensitizer
Molecule with key UEEXRMUCXBPYOV-UHFFFAOYSA-N does not exist.
Investigation
Investigation-Name: Table 1
Sacrificial electron donor
Additives
Investigations
- Cyclic voltammetry in various conditions (Assay, Cyclic Voltammetry experiments)
- Photocatalytic reduction of CO2: conditions optimization (Molecular process, Photocatalytic CO2 conversion experiments)
