Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts: Difference between revisions

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DOI 10.1021/jacs.8b10619
Authors Hiroyuki Takeda, Hiroko Kamiyama, Kouhei Okamoto, Mina Irimajiri, Toshihide Mizutani, Kazuhide Koike, Akiko Sekine, Osamu Ishitani,
Submitted 27.11.2018
Published online 27.11.2018
Licenses http://pubs.acs.org/page/policy/authorchoice_termsofuse.html,
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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==== Catalyst ====
==== Catalyst ====
<chemform smiles="C([*])1C=C2C3N([Mn+](C#O)(C#O)(C#O)([Br-])N2=CC=1)=CC=C([*])C=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,OMe">
<chemform smiles="C([*])1C=C2C3N([Mn+]([Br-])([C-]#[O+])([C-]#[O+])([C-]#[O+])N2=CC=1)=CC=C([*])C=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,OMe">
   -INDIGO-02132315572D
   -INDIGO-05052316132D


   0  0  0  0  0  0  0  0  0  0  0 V3000
   0  0  0  0  0  0  0  0  0  0  0 V3000
Line 27: Line 27:
M  V30 12 C 5.62882 -7.92503 0.0 0
M  V30 12 C 5.62882 -7.92503 0.0 0
M  V30 13 Mn 7.55 -5.475 0.0 0 CHG=1
M  V30 13 Mn 7.55 -5.475 0.0 0 CHG=1
M  V30 14 Br 7.55 -4.475 0.0 0 CHG=-1
M  V30 14 C 8.41603 -4.975 0.0 0 CHG=-1
M  V30 15 C 8.41603 -4.975 0.0 0
M  V30 15 C 8.41603 -5.975 0.0 0 CHG=-1
M  V30 16 C 8.41603 -5.975 0.0 0
M  V30 16 C 7.55 -6.475 0.0 0 CHG=-1
M  V30 17 C 7.55 -6.475 0.0 0
M  V30 17 O 7.55 -7.475 0.0 0 CHG=1
M  V30 18 O 7.55 -7.475 0.0 0
M  V30 18 O 9.28205 -6.475 0.0 0 CHG=1
M  V30 19 O 9.28205 -6.475 0.0 0
M  V30 19 O 9.28205 -4.475 0.0 0 CHG=1
M  V30 20 O 9.28205 -4.475 0.0 0
M  V30 20 R# 3.89382 -2.97507 0.0 0 RGROUPS=(1 1)
M  V30 21 R# 3.89382 -2.97507 0.0 0 RGROUPS=(1 1)
M  V30 21 R# 3.89382 -7.93002 0.0 0 RGROUPS=(1 1)
M  V30 22 R# 3.89382 -7.93002 0.0 0 RGROUPS=(1 1)
M  V30 22 Br 7.525 -3.3 0.0 0 CHG=-1
M  V30 END ATOM
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 BEGIN BOND
Line 56: Line 56:
M  V30 17 10 13 15
M  V30 17 10 13 15
M  V30 18 10 13 16
M  V30 18 10 13 16
M  V30 19 10 13 17
M  V30 19 3 16 17
M  V30 20 3 17 18
M  V30 20 3 15 18
M  V30 21 3 16 19
M  V30 21 3 14 19
M  V30 22 3 15 20
M  V30 22 1 1 20
M  V30 23 1 1 21
M  V30 23 1 11 21
M  V30 24 1 11 22
M  V30 24 10 13 22
M  V30 END BOND
M  V30 END BOND
M  V30 END CTAB
M  V30 END CTAB

Revision as of 15:16, 5 May 2023


Investigation

  1. REDIRECT Results for photocatalytic reduction of CO2
Investigation-Name: Table 1

Catalyst

100751 [Show R-Groups]

Photosensitizer

Sacrificial electron donor

BIH TEOA

Investigations

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