Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction: Difference between revisions

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DOI 10.1039/c6sc01913g
Authors Jana Rohacova, Osamu Ishitani,
Submitted 05.07.2016
Published online 2016
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{{#doiinfobox: 10.1039/c6sc01913g}}{{MissingMolecule}}{{MissingInvestigation}}
{{#doiinfobox: 10.1039/c6sc01913g}}
{{#moleculelink:|link=YGWAVCYEYZMOLM-UHFFFAOYSA-N}} Revise


==== Investigation ====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=}}
==== Catalyst ====
<chemform smiles="" inchi="" inchikey="" height="200px" width="300px" float="none"></chemform>Re(bpy)(CO)3(MeCN)
==== Photosensitizer ====
<chemform smiles="C1C=C2P(C3C=CC=CC=3)(C3C=CC=CC=3)~[Re+]3(N4=C(C5N3=CC([*])=C([*])C=5)C=C([*])C([*])=C4)(C#O)(C#O)~P(C3C=CC=CC=3)(C3C=CC=CC=3)C3C=CC(P(C4C=CC=CC=4)(C4C=CC=CC=4)~[Re+]4(N5=C(C6N4=CC([*])=C([*])C=6)C=C([*])C([*])=C5)(C#O)(C#O)~P(C4C=CC=CC=4)(C4C=CC=CC=4)C4C=CC(P(C5C=CC=CC=5)(C5C=CC=CC=5)~[Re+]5(N6=CC([*])=C([*])C=C6C6C=C([*])C([*])=CN=65)(C#O)(C#O)~P(C5C=CC=CC=5)(C5C=CC=CC=5)C=1C=C2)=CC=4)=CC=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="CH3,H,CH3,H" r2="H,CH3,CH3,OMe">
<chemform smiles="C1C=C2P(C3C=CC=CC=3)(C3C=CC=CC=3)~[Re+]3(N4=C(C5N3=CC([*])=C([*])C=5)C=C([*])C([*])=C4)(C#O)(C#O)~P(C3C=CC=CC=3)(C3C=CC=CC=3)C3C=CC(P(C4C=CC=CC=4)(C4C=CC=CC=4)~[Re+]4(N5=C(C6N4=CC([*])=C([*])C=6)C=C([*])C([*])=C5)(C#O)(C#O)~P(C4C=CC=CC=4)(C4C=CC=CC=4)C4C=CC(P(C5C=CC=CC=5)(C5C=CC=CC=5)~[Re+]5(N6=CC([*])=C([*])C=C6C6C=C([*])C([*])=CN=65)(C#O)(C#O)~P(C5C=CC=CC=5)(C5C=CC=CC=5)C=1C=C2)=CC=4)=CC=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="CH3,H,CH3,H" r2="H,CH3,CH3,OMe">
   -INDIGO-04202312202D
   -INDIGO-04202312202D
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M  END
M  END
</chemform>
</chemform>
==== Sacrificial electron donor ====
<chemform smiles="" inchi="" inchikey="GSEJCLTVZPLZKY-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
[[Category:Photocatalytic CO2 conversion to HCOOH]]
[[Category:Photocatalytic CO2 conversion to HCOOH]]

Revision as of 13:31, 3 May 2023


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Investigation

Experiment 'Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction/' does not exist.

Catalyst

Re(bpy)(CO)3(MeCN)

Photosensitizer

Sacrificial electron donor

TEOA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
  • Table 2 (Molecular process, Photocatalytic CO2 conversion experiments)