Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 12:45, 3 May 2023

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	1	2	13
2.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	2	4	21
3.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	13	8	62
4.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	8	8	34
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	7	9	40
6.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	4	27

Investigation-Name: Table 1

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ru(bpy)2Cl2	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	9	26
2.	Ru(bpy)2CO3	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	11	39
3.	[Ru(bpy)2ClCO][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	19	19	117
4.	[Ru(bpy)2HCO][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	21	16	107
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	21	14	75
6.	[Ru(bpy)(AcMe)2][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	4	12	64
7.	[Ru(bpy)2ClCO][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	36	33	296
8.	[Ru(bpy)2HCO][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	16	29	145
9.	[Ru(bpy)(H2O)(CO)][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	34	28	211
10.	[Ru(bpy)2ClCO][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	40	67	419
11.	[Ru(bpy)2HCO][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	25	62	225
12.	[Ru(bpy)(H2O)(CO)][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	45	65	335
13.	[Ru(bpy)(AcMe)2][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	4	44	75

Investigation-Name: Table 2

CO2 reduction experiments (Molecular process, Photocatalytic CO2 conversion experiments)
Optimization of concentrations (Molecular process, Photocatalytic CO2 conversion experiments)
Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 2 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 3 - CV (Assay, Cyclic Voltammetry experiments)

DOI	10.1002/cctc.201500494
Authors	Alonso Rosas-Hernández, Henrik Junge, Matthias Beller,
Submitted	26.08.2015
Published online	26.08.2015
Licenses	http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects	Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Catalysis
Go to literature page

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 [[Category:Photocatalytic CO2 conversion to HCOOH]]
 {{#doiinfobox: 10.1002/cctc.201500494 }}
-{{#literature:|doi=http://dx.doi.org/10.1002/cctc.201500494}}
 === Catalysts ===
 <chemform smiles="C1C=CN2~[Ru](~[*])(~[*])3(~N4C=CC=CC=4C4N~3=CC=CC=4)~N3C=CC=CC=3C=2C=1" inchi="" inchikey="" height="200px" width="300px" float="none" r1="Cl,Cl,H" r2="Cl,CO,CO">