Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts: Difference between revisions
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{{#doiinfobox: 10.1021/jacs.8b10619}} | {{#doiinfobox: 10.1021/jacs.8b10619}} | ||
[[Category:Photocatalytic CO2 conversion to HCOOH]] | [[Category:Photocatalytic CO2 conversion to HCOOH]] | ||
{{BaseTemplate}} | {{BaseTemplate}}<!-- Investigation unfinished, CuPS not saved --> | ||
==== Investigation ==== | |||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | |||
==== Catalyst ==== | |||
<chemform smiles="C([*])1C=C2C3N([Mn+](C#O)(C#O)(C#O)([Br-])N2=CC=1)=CC=C([*])C=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,OMe"> | <chemform smiles="C([*])1C=C2C3N([Mn+](C#O)(C#O)(C#O)([Br-])N2=CC=1)=CC=C([*])C=3" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,OMe"> | ||
-INDIGO-02132315572D | -INDIGO-02132315572D | ||
Line 58: | Line 62: | ||
M V30 23 1 1 21 | M V30 23 1 1 21 | ||
M V30 24 1 11 22 | M V30 24 1 11 22 | ||
M V30 END BOND | |||
M V30 END CTAB | |||
M END | |||
</chemform><chemform smiles="C1C=C2C3C=CC=C(C4C(C)=CC(C)=CC=4C)N=3[Mn](C#O)(C#O)(~Br)N2=C(C2C(C)=CC(C)=CC=2C)C=1" inchi="1S/C28H28N2.2CHO.BrH.Mn/c1-17-13-19(3)27(20(4)14-17)25-11-7-9-23(29-25)24-10-8-12-26(30-24)28-21(5)15-18(2)16-22(28)6;2*1-2;;/h7-16H,1-6H3;2*1H;1H;/q;;;;+1/p-1" inchikey="LAJRVYLSNAAJQU-UHFFFAOYSA-M" height="200px" width="300px" float="none"> | |||
-INDIGO-03102311002D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 36 40 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C 4.73485 -2.97507 0.0 0 | |||
M V30 2 C 6.46515 -2.97459 0.0 0 | |||
M V30 3 C 5.60164 -2.47497 0.0 0 | |||
M V30 4 N 6.46515 -3.97553 0.0 0 | |||
M V30 5 C 4.73485 -3.98002 0.0 0 | |||
M V30 6 C 5.60382 -4.47503 0.0 0 | |||
M V30 7 C 5.60768 -5.47503 0.0 0 | |||
M V30 8 C 6.47425 -6.97269 0.0 0 | |||
M V30 9 N 6.47451 -5.97505 0.0 0 | |||
M V30 10 C 5.60775 -7.47374 0.0 0 | |||
M V30 11 C 4.73771 -5.97808 0.0 0 | |||
M V30 12 C 4.74417 -6.97814 0.0 0 | |||
M V30 13 C 7.33141 -2.47499 0.0 0 | |||
M V30 14 C 7.34038 -7.47251 0.0 0 | |||
M V30 15 C 9.07068 -7.47086 0.0 0 | |||
M V30 16 C 8.20683 -6.97182 0.0 0 | |||
M V30 17 C 9.07135 -8.47181 0.0 0 | |||
M V30 18 C 7.34106 -8.47746 0.0 0 | |||
M V30 19 C 8.21036 -8.97189 0.0 0 | |||
M V30 20 C 8.19513 -0.975685 0.0 0 | |||
M V30 21 C 7.33103 -1.47428 0.0 0 | |||
M V30 22 C 9.06231 -1.47558 0.0 0 | |||
M V30 23 C 8.20205 -2.97688 0.0 0 | |||
M V30 24 C 9.06489 -2.47126 0.0 0 | |||
M V30 25 C 6.46497 -0.974331 0.0 0 | |||
M V30 26 C 9.92752 -0.974162 0.0 0 | |||
M V30 27 C 8.20562 -3.97688 0.0 0 | |||
M V30 28 C 8.20677 -5.97182 0.0 0 | |||
M V30 29 C 6.47682 -8.98054 0.0 0 | |||
M V30 30 C 9.93819 -8.97039 0.0 0 | |||
M V30 31 Mn 7.7 -4.95 0.0 0 | |||
M V30 32 Br 7.7 -3.95 0.0 0 | |||
M V30 33 C 8.56603 -4.45 0.0 0 | |||
M V30 34 C 8.56603 -5.45 0.0 0 | |||
M V30 35 O 9.43205 -3.95 0.0 0 | |||
M V30 36 O 9.43205 -5.95 0.0 0 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 2 3 1 | |||
M V30 2 2 4 2 | |||
M V30 3 1 1 5 | |||
M V30 4 1 2 3 | |||
M V30 5 2 5 6 | |||
M V30 6 1 6 4 | |||
M V30 7 1 6 7 | |||
M V30 8 2 9 7 | |||
M V30 9 2 10 8 | |||
M V30 10 1 7 11 | |||
M V30 11 1 8 9 | |||
M V30 12 2 11 12 | |||
M V30 13 1 12 10 | |||
M V30 14 1 2 13 | |||
M V30 15 1 8 14 | |||
M V30 16 2 16 14 | |||
M V30 17 2 17 15 | |||
M V30 18 1 14 18 | |||
M V30 19 1 15 16 | |||
M V30 20 2 18 19 | |||
M V30 21 1 19 17 | |||
M V30 22 2 21 13 | |||
M V30 23 2 22 20 | |||
M V30 24 1 13 23 | |||
M V30 25 1 20 21 | |||
M V30 26 2 23 24 | |||
M V30 27 1 24 22 | |||
M V30 28 1 21 25 | |||
M V30 29 1 22 26 | |||
M V30 30 1 23 27 | |||
M V30 31 1 16 28 | |||
M V30 32 1 18 29 | |||
M V30 33 1 17 30 | |||
M V30 34 10 4 31 | |||
M V30 35 10 9 31 | |||
M V30 36 8 31 32 | |||
M V30 37 10 31 33 | |||
M V30 38 10 31 34 | |||
M V30 39 3 33 35 | |||
M V30 40 3 34 36 | |||
M V30 END BOND | M V30 END BOND | ||
M V30 END CTAB | M V30 END CTAB | ||
M END | M END | ||
</chemform> | </chemform> | ||
==== Photosensitizer ==== | |||
<chemform smiles="" inchi="" inchikey="" height="200px" width="300px" float="none"></chemform> |
Revision as of 11:31, 10 March 2023
Investigations
- Durability test (Molecular process, Photocatalytic CO2 conversion experiments)
- Results for photocatalytic reduction of CO2 (Molecular process, Photocatalytic CO2 conversion experiments)