Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction: Difference between revisions

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Revision as of 10:30, 3 February 2023


Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A...λexc [nm].TON COTON H2TON HCOOH.
1.

[MoO(qpdt)2][NBu4]2

0.05

Ru(bpy)3Cl2

0.5

BIH

0.1

MeCN

4007367080
2.

[K]2[MoO(Hqpdt)2]

0.05

Ru(bpy)3Cl2

0.5

BIH

0.1

MeCN

400135131
3.

[MoO(2Hqpdt)2][NBu4]

0.05

Ru(bpy)3Cl2

0.5

BIH

0.1

MeCN

400408983
Investigation-Name: Table 1

Catalyst

[K]2[MoO(Hqpdt)2] [MoO(2Hqpdt)2][NBu4]

Photosensitizer

Ru(bpy)3Cl2

Sacrificial electron donor

BIH

TEOA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)