Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst: Difference between revisions

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About
DOI 10.1021/jacs.8b09740
Authors Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert,
Submitted 07.12.2018
Published online 07.12.2018
Licenses -
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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(Added molecule)
Line 160: Line 160:
M  V30 END CTAB
M  V30 END CTAB
M  END
M  END
</chemform><chemform smiles="N12~[Fe](~Cl)34N5=C6C(C7C=CC([N+](C)(C)C)=CC=7)=C7N~3C(=C(C3C=CC([N+](C)(C)C)=CC=3)C3=N4C(=C(C4C=CC([N+](C)(C)C)=CC=4)C1=CC=C2C(C1C=CC([N+](C)(C)C)=CC=1)=C5C=C6)C=C3)C=C7.[Cl-].[Cl-].[Cl-].[Cl-]" inchi="1S/C56H60N8.5ClH.Fe/c1-61(2,3)41-21-13-37(14-22-41)53-45-29-31-47(57-45)54(38-15-23-42(24-16-38)62(4,5)6)49-33-35-51(59-49)56(40-19-27-44(28-20-40)64(10,11)12)52-36-34-50(60-52)55(48-32-30-46(53)58-48)39-17-25-43(26-18-39)63(7,8)9;;;;;;/h13-36H,1-12H3;5*1H;/q+2;;;;;;+3/p-5/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-;;;;;;" inchikey="NRVILUOLTIKJEU-NGWNFTKISA-I" height="200px" width="300px" float="none">
</chemform><chemform smiles="C1C=C2C(C3C=CC([N+](C)(C)C)=CC=3)=C3C=CC4C(C5C=CC([N+](C)(C)C)=CC=5)=C5N6~[Fe](~Cl)7(~N2C=1C(C1C=CC([N+](C)(C)C)=CC=1)=C1N7=C(C(C2C=CC([N+](C)(C)C)=CC=2)=C6C=C5)C=C1)N3=4.[Cl-].[Cl-].[Cl-].[Cl-]" inchi="1S/C56H60N8.5ClH.Fe/c1-61(2,3)41-21-13-37(14-22-41)53-45-29-31-47(57-45)54(38-15-23-42(24-16-38)62(4,5)6)49-33-35-51(59-49)56(40-19-27-44(28-20-40)64(10,11)12)52-36-34-50(60-52)55(48-32-30-46(53)58-48)39-17-25-43(26-18-39)63(7,8)9;;;;;;/h13-36H,1-12H3;5*1H;/q+2;;;;;;+3/p-5/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-;;;;;;" inchikey="NRVILUOLTIKJEU-NGWNFTKISA-I" height="200px" width="300px" float="none">
   -INDIGO-01262315002D
   -INDIGO-01262316122D


   0  0  0  0  0  0  0  0  0  0  0 V3000
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Line 167: Line 167:
M  V30 COUNTS 70 77 0 0 0
M  V30 COUNTS 70 77 0 0 0
M  V30 BEGIN ATOM
M  V30 BEGIN ATOM
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M  V30 1 C 8.82458 -2.03516 0.0 0
M  V30 2 C 5.92365 -3.24351 0.0 0
M  V30 2 C 9.15193 -2.99472 0.0 0
M  V30 3 C 6.32233 -2.47336 0.0 0
M  V30 3 N 8.37913 -3.6265 0.0 0
M  V30 4 C 7.25241 -2.55717 0.0 0
M  V30 4 C 7.56594 -3.043 0.0 0
M  V30 5 C 7.53129 -3.34266 0.0 0
M  V30 5 C 7.83141 -2.06548 0.0 0
M  V30 6 N 6.77064 -6.60996 0.0 0
M  V30 6 N 8.44637 -6.44835 0.0 0
M  V30 7 C 7.51764 -7.23741 0.0 0
M  V30 7 C 9.23777 -7.06875 0.0 0
M  V30 8 C 7.22484 -8.11381 0.0 0
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M  V30 9 C 7.93405 -7.99327 0.0 0
M  V30 10 C 5.90583 -7.11973 0.0 0
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M  V30 24 C 4.61671 -3.2836 0.0 0
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M  V30 25 C 8.56553 -3.48888 0.0 0
M  V30 25 C 5.89126 -2.65749 0.0 0
M  V30 26 C 3.57532 -7.0683 0.0 0
M  V30 26 C 10.8257 -2.52634 0.0 0
M  V30 27 C 3.87613 -2.4949 0.0 0
M  V30 27 C 5.96126 -7.51231 0.0 0
M  V30 28 C 9.12273 -2.57763 0.0 0
M  V30 28 C 5.51501 -9.18408 0.0 0
M  V30 29 C 2.21692 -2.02347 0.0 0
M  V30 29 C 6.22063 -8.47882 0.0 0
M  V30 30 C 2.90971 -2.73235 0.0 0
M  V30 30 C 4.548 -8.92566 0.0 0
M  V30 31 C 2.47403 -1.09269 0.0 0
M  V30 31 C 4.99038 -7.25286 0.0 0
M  V30 32 C 4.11222 -1.5244 0.0 0
M  V30 32 C 4.2878 -7.96457 0.0 0
M  V30 33 C 3.41217 -0.838092 0.0 0
M  V30 33 C 4.2195 -2.21125 0.0 0
M  V30 34 C 9.08185 -0.869924 0.0 0
M  V30 34 C 4.92475 -2.91686 0.0 0
M  V30 35 C 8.61087 -1.7278 0.0 0
M  V30 35 C 4.47791 -1.24424 0.0 0
M  V30 36 C 10.0612 -0.847614 0.0 0
M  V30 36 C 6.15071 -1.68661 0.0 0
M  V30 37 C 10.1139 -2.5376 0.0 0
M  V30 37 C 5.439 -0.984039 0.0 0
M  V30 38 C 10.5738 -1.67014 0.0 0
M  V30 38 C 11.272 -0.854574 0.0 0
M  V30 39 C 11.0862 -8.2807 0.0 0
M  V30 39 C 10.5664 -1.55983 0.0 0
M  V30 40 C 10.3489 -7.56272 0.0 0
M  V30 40 C 12.239 -1.11299 0.0 0
M  V30 41 C 10.8484 -9.29113 0.0 0
M  V30 41 C 11.7966 -2.78579 0.0 0
M  V30 42 C 9.10412 -8.84112 0.0 0
M  V30 42 C 12.4992 -2.07408 0.0 0
M  V30 43 C 9.85272 -9.56306 0.0 0
M  V30 43 N 3.76965 -0.538284 0.0 0 CHG=1
M  V30 44 C 2.65696 -8.51859 0.0 0
M  V30 44 N 12.9449 -0.404729 0.0 0 CHG=1
M  V30 45 C 3.52644 -8.05826 0.0 0
M  V30 45 C 10.9325 -7.49452 0.0 0
M  V30 46 C 1.83006 -8.00589 0.0 0
M  V30 46 C 12.6043 -7.94076 0.0 0
M  V30 47 C 2.71616 -6.56549 0.0 0
M  V30 47 C 11.899 -7.23514 0.0 0
M  V30 48 C 1.85203 -7.04176 0.0 0
M  V30 48 C 12.3458 -8.90777 0.0 0
M  V30 49 N 1.90013 -0.294853 0.0 0 CHG=1
M  V30 49 C 10.673 -8.46539 0.0 0
M  V30 50 N 10.4033 0.0777473 0.0 0 CHG=1
M  V30 50 C 11.3848 -9.16797 0.0 0
M  V30 51 N 11.5999 -10.0067 0.0 0 CHG=1
M  V30 51 N 3.84205 -9.63392 0.0 0 CHG=1
M  V30 52 N 1.04201 -8.58609 0.0 0 CHG=1
M  V30 52 N 13.0541 -9.61372 0.0 0 CHG=1
M  V30 53 C 11.3865 -0.111833 0.0 0
M  V30 53 C 4.26965 0.327741 0.0 0
M  V30 54 C 10.5058 1.03629 0.0 0
M  V30 54 C 2.90363 -1.03828 0.0 0
M  V30 55 C 9.46698 0.24328 0.0 0
M  V30 55 C 3.06254 0.168823 0.0 0
M  V30 56 C 1.48083 0.566873 0.0 0
M  V30 56 C 12.4449 0.461297 0.0 0
M  V30 57 C 0.980577 -0.800839 0.0 0
M  V30 57 C 13.811 -0.904729 0.0 0
M  V30 58 C 2.69878 0.129588 0.0 0
M  V30 58 C 13.652 0.302378 0.0 0
M  V30 59 C 0.301268 -7.80818 0.0 0
M  V30 59 C 12.5541 -10.4797 0.0 0
M  V30 60 C 0.390704 -9.25952 0.0 0
M  V30 60 C 13.9201 -9.11372 0.0 0
M  V30 61 C 1.65639 -9.21554 0.0 0
M  V30 61 C 13.7612 -10.3208 0.0 0
M  V30 62 C 10.9685 -10.7568 0.0 0
M  V30 62 C 2.97602 -9.13392 0.0 0
M  V30 63 C 12.3428 -9.38366 0.0 0
M  V30 63 C 4.34205 -10.4999 0.0 0
M  V30 64 C 12.324 -10.7505 0.0 0
M  V30 64 C 3.13494 -10.341 0.0 0
M  V30 65 Fe 6.675 -5.15 0.0 0
M  V30 65 Fe 8.425 -5.075 0.0 0
M  V30 66 Cl 7.38211 -4.44289 0.0 0
M  V30 66 Cl 9.13211 -4.36789 0.0 0
M  V30 67 Cl 12.775 -10.05 0.0 0 CHG=-1
M  V30 67 Cl 13.05 -8.875 0.0 0 CHG=-1
M  V30 68 Cl 11.675 0.65 0.0 0 CHG=-1
M  V30 68 Cl 3.9 -8.8 0.0 0 CHG=-1
M  V30 69 Cl 0.35 0.025 0.0 0 CHG=-1
M  V30 69 Cl 3.8 -1.35 0.0 0 CHG=-1
M  V30 70 Cl -0.45 -8.575 0.0 0 CHG=-1
M  V30 70 Cl 12.975 -1.225 0.0 0 CHG=-1
M  V30 END ATOM
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 BEGIN BOND
M  V30 1 1 1 2
M  V30 1 2 1 2
M  V30 2 2 2 3
M  V30 2 1 2 3
M  V30 3 1 3 4
M  V30 3 1 3 4
M  V30 4 2 4 5
M  V30 4 2 4 5
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Line 311: Line 311:
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M  V30 END BOND
M  V30 END BOND

Revision as of 16:15, 26 January 2023


[VLD18]

Investigation

  1. REDIRECT Photocatalytic reduction of CO2
Investigation-Name: Table 1

Catalyst

Photosensitizer

5,10-Di(2-naphthyl)-5,10-dihydrophenazine 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine

Other molecules

DIPEA H2O PhOH TFE

Literature

[VLD18] Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst. Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert, Journal of the American Chemical Society 2018, Vol. 140, Pages 17830-17834. DOI2: 10.1021/jacs.8b09740
Publication: Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst

Investigations

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