Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst: Difference between revisions

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DOI 10.1021/jacs.8b09740
Authors Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert,
Submitted 07.12.2018
Published online 07.12.2018
Licenses -
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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(Added molecule)
Line 157: Line 157:
M  V30 75 8 15 65
M  V30 75 8 15 65
M  V30 76 8 19 65
M  V30 76 8 19 65
M  V30 END BOND
M  V30 END CTAB
M  END
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M  V30 BEGIN ATOM
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M  V30 2 C 5.92365 -3.24351 0.0 0
M  V30 3 C 6.32233 -2.47336 0.0 0
M  V30 4 C 7.25241 -2.55717 0.0 0
M  V30 5 C 7.53129 -3.34266 0.0 0
M  V30 6 N 6.77064 -6.60996 0.0 0
M  V30 7 C 7.51764 -7.23741 0.0 0
M  V30 8 C 7.22484 -8.11381 0.0 0
M  V30 9 C 6.21343 -8.11468 0.0 0
M  V30 10 C 5.90583 -7.11973 0.0 0
M  V30 11 C 8.95377 -4.34675 0.0 0
M  V30 12 C 9.9173 -4.57529 0.0 0
M  V30 13 C 9.92859 -5.54629 0.0 0
M  V30 14 C 8.97594 -5.81495 0.0 0
M  V30 15 N 8.45454 -5.05032 0.0 0
M  V30 16 C 4.27019 -4.09676 0.0 0
M  V30 17 N 4.77512 -4.81791 0.0 0
M  V30 18 C 4.22036 -5.53905 0.0 0
M  V30 19 C 3.37468 -5.24187 0.0 0
M  V30 20 C 3.39827 -4.31154 0.0 0
M  V30 21 C 8.55065 -6.96713 0.0 0
M  V30 22 C 9.33759 -7.82585 0.0 0
M  V30 23 C 4.50637 -6.58252 0.0 0
M  V30 24 C 4.61671 -3.2836 0.0 0
M  V30 25 C 8.56553 -3.48888 0.0 0
M  V30 26 C 3.57532 -7.0683 0.0 0
M  V30 27 C 3.87613 -2.4949 0.0 0
M  V30 28 C 9.12273 -2.57763 0.0 0
M  V30 29 C 2.21692 -2.02347 0.0 0
M  V30 30 C 2.90971 -2.73235 0.0 0
M  V30 31 C 2.47403 -1.09269 0.0 0
M  V30 32 C 4.11222 -1.5244 0.0 0
M  V30 33 C 3.41217 -0.838092 0.0 0
M  V30 34 C 9.08185 -0.869924 0.0 0
M  V30 35 C 8.61087 -1.7278 0.0 0
M  V30 36 C 10.0612 -0.847614 0.0 0
M  V30 37 C 10.1139 -2.5376 0.0 0
M  V30 38 C 10.5738 -1.67014 0.0 0
M  V30 39 C 11.0862 -8.2807 0.0 0
M  V30 40 C 10.3489 -7.56272 0.0 0
M  V30 41 C 10.8484 -9.29113 0.0 0
M  V30 42 C 9.10412 -8.84112 0.0 0
M  V30 43 C 9.85272 -9.56306 0.0 0
M  V30 44 C 2.65696 -8.51859 0.0 0
M  V30 45 C 3.52644 -8.05826 0.0 0
M  V30 46 C 1.83006 -8.00589 0.0 0
M  V30 47 C 2.71616 -6.56549 0.0 0
M  V30 48 C 1.85203 -7.04176 0.0 0
M  V30 49 N 1.90013 -0.294853 0.0 0 CHG=1
M  V30 50 N 10.4033 0.0777473 0.0 0 CHG=1
M  V30 51 N 11.5999 -10.0067 0.0 0 CHG=1
M  V30 52 N 1.04201 -8.58609 0.0 0 CHG=1
M  V30 53 C 11.3865 -0.111833 0.0 0
M  V30 54 C 10.5058 1.03629 0.0 0
M  V30 55 C 9.46698 0.24328 0.0 0
M  V30 56 C 1.48083 0.566873 0.0 0
M  V30 57 C 0.980577 -0.800839 0.0 0
M  V30 58 C 2.69878 0.129588 0.0 0
M  V30 59 C 0.301268 -7.80818 0.0 0
M  V30 60 C 0.390704 -9.25952 0.0 0
M  V30 61 C 1.65639 -9.21554 0.0 0
M  V30 62 C 10.9685 -10.7568 0.0 0
M  V30 63 C 12.3428 -9.38366 0.0 0
M  V30 64 C 12.324 -10.7505 0.0 0
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M  V30 66 Cl 7.38211 -4.44289 0.0 0
M  V30 67 Cl 12.775 -10.05 0.0 0 CHG=-1
M  V30 68 Cl 11.675 0.65 0.0 0 CHG=-1
M  V30 69 Cl 0.35 0.025 0.0 0 CHG=-1
M  V30 70 Cl -0.45 -8.575 0.0 0 CHG=-1
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 1 1 2
M  V30 2 2 2 3
M  V30 3 1 3 4
M  V30 4 2 4 5
M  V30 5 1 5 1
M  V30 6 1 6 7
M  V30 7 1 7 8
M  V30 8 2 8 9
M  V30 9 1 9 10
M  V30 10 1 10 6
M  V30 11 1 11 12
M  V30 12 2 12 13
M  V30 13 1 13 14
M  V30 14 2 14 15
M  V30 15 1 15 11
M  V30 16 1 16 17
M  V30 17 2 17 18
M  V30 18 1 18 19
M  V30 19 2 19 20
M  V30 20 1 20 16
M  V30 21 2 7 21
M  V30 22 1 14 21
M  V30 23 1 21 22
M  V30 24 1 18 23
M  V30 25 2 23 10
M  V30 26 2 16 24
M  V30 27 1 24 2
M  V30 28 1 5 25
M  V30 29 2 25 11
M  V30 30 1 23 26
M  V30 31 1 24 27
M  V30 32 1 25 28
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M  V30 34 2 31 29
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M  V30 36 1 29 30
M  V30 37 2 32 33
M  V30 38 1 33 31
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M  V30 40 2 36 34
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M  V30 42 1 34 35
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M  V30 46 2 41 39
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M  V30 50 1 43 41
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M  V30 52 2 46 44
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M  V30 54 1 44 45
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M  V30 58 1 36 50
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M  V30 60 1 46 52
M  V30 61 1 50 53
M  V30 62 1 50 54
M  V30 63 1 50 55
M  V30 64 1 49 56
M  V30 65 1 49 57
M  V30 66 1 49 58
M  V30 67 1 52 59
M  V30 68 1 52 60
M  V30 69 1 52 61
M  V30 70 1 51 62
M  V30 71 1 51 63
M  V30 72 1 51 64
M  V30 73 8 1 65
M  V30 74 10 15 65
M  V30 75 8 6 65
M  V30 76 10 17 65
M  V30 77 8 65 66
M  V30 END BOND
M  V30 END BOND
M  V30 END CTAB
M  V30 END CTAB

Revision as of 15:00, 26 January 2023


[VLD18]

Investigation

  1. REDIRECT Photocatalytic reduction of CO2
Investigation-Name: Table 1

Catalyst

Photosensitizer

5,10-Di(2-naphthyl)-5,10-dihydrophenazine 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine

Other molecules

DIPEA H2O PhOH TFE

Literature

[VLD18] Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst. Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert, Journal of the American Chemical Society 2018, Vol. 140, Pages 17830-17834. DOI2: 10.1021/jacs.8b09740
Publication: Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst

Investigations

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