Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst: Difference between revisions
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[[Category:Photocatalytic conversion of CO2 to CH4]] | [[Category:Photocatalytic conversion of CO2 to CH4]] | ||
{{#literature:|doi=10.1021/jacs.8b09740}} | {{#literature:|doi=10.1021/jacs.8b09740}} | ||
=== Catalyst === | |||
<chemform smiles="C12C(C3C=CC([N+](C)(C)C)=CC=3)=C3N4~[Fe]56~N7C(=C(C8C=CC([N+](C)(C)C)=CC=8)C8N~5C(C(C5C=CC([N+](C)(C)C)=CC=5)=C(N=1~6)C=C2)=CC=8)C=CC=7C(C1C=CC([N+](C)(C)C)=CC=1)=C4C=C3" inchi="1S/C56H62N8.Fe/c1-61(2,3)41-21-13-37(14-22-41)53-45-29-31-47(57-45)54(38-15-23-42(24-16-38)62(4,5)6)49-33-35-51(59-49)56(40-19-27-44(28-20-40)64(10,11)12)52-36-34-50(60-52)55(48-32-30-46(53)58-48)39-17-25-43(26-18-39)63(7,8)9;/h13-36,57,60H,1-12H3;/q+4;/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-;" inchikey="MXOBCRHAQPLEER-YUTFXDKVSA-N" height="200px" width="300px" float="none"> | |||
-INDIGO-12132211272D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 65 76 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C 6.04424 -2.5609 0.0 0 | |||
M V30 2 C 7.33133 -1.66667 0.0 0 | |||
M V30 3 C 6.36602 -1.6242 0.0 0 | |||
M V30 4 C 7.56769 -2.60624 0.0 0 | |||
M V30 5 N 6.78397 -3.14046 0.0 0 | |||
M V30 6 C 4.63287 -3.92379 0.0 0 | |||
M V30 7 C 4.532 -5.51407 0.0 0 | |||
M V30 8 N 5.16816 -4.74793 0.0 0 | |||
M V30 9 C 3.63825 -5.15661 0.0 0 | |||
M V30 10 C 3.69714 -4.16923 0.0 0 | |||
M V30 11 C 8.75201 -4.00987 0.0 0 | |||
M V30 12 C 9.58697 -5.32603 0.0 0 | |||
M V30 13 C 9.63842 -4.3551 0.0 0 | |||
M V30 14 C 8.65581 -5.58713 0.0 0 | |||
M V30 15 N 8.10856 -4.76374 0.0 0 | |||
M V30 16 C 7.01046 -7.93253 0.0 0 | |||
M V30 17 C 5.78378 -6.99601 0.0 0 | |||
M V30 18 C 6.03403 -7.92348 0.0 0 | |||
M V30 19 N 6.54571 -6.43131 0.0 0 | |||
M V30 20 C 7.28367 -7.01054 0.0 0 | |||
M V30 21 C 5.0119 -2.87292 0.0 0 | |||
M V30 22 C 8.51405 -2.9837 0.0 0 | |||
M V30 23 C 8.29876 -6.63698 0.0 0 | |||
M V30 24 C 4.79605 -6.58792 0.0 0 | |||
M V30 25 C 4.32364 -2.14745 0.0 0 | |||
M V30 26 C 9.27269 -2.33219 0.0 0 | |||
M V30 27 C 9.01458 -7.33526 0.0 0 | |||
M V30 28 C 4.03772 -7.2398 0.0 0 | |||
M V30 29 C 3.59147 -8.91156 0.0 0 | |||
M V30 30 C 4.29709 -8.20631 0.0 0 | |||
M V30 31 C 2.62446 -8.65315 0.0 0 | |||
M V30 32 C 3.06684 -6.98035 0.0 0 | |||
M V30 33 C 2.36426 -7.69206 0.0 0 | |||
M V30 34 C 10.6863 -7.78151 0.0 0 | |||
M V30 35 C 9.9811 -7.07589 0.0 0 | |||
M V30 36 C 10.4279 -8.74852 0.0 0 | |||
M V30 37 C 8.75513 -8.30614 0.0 0 | |||
M V30 38 C 9.46685 -9.00872 0.0 0 | |||
M V30 39 C 9.71894 -0.660424 0.0 0 | |||
M V30 40 C 9.01332 -1.36567 0.0 0 | |||
M V30 41 C 10.6859 -0.918838 0.0 0 | |||
M V30 42 C 10.2436 -2.59164 0.0 0 | |||
M V30 43 C 10.9461 -1.87993 0.0 0 | |||
M V30 44 C 2.65188 -1.7012 0.0 0 | |||
M V30 45 C 3.35713 -2.40682 0.0 0 | |||
M V30 46 C 2.91029 -0.734192 0.0 0 | |||
M V30 47 C 4.58309 -1.17657 0.0 0 | |||
M V30 48 C 3.87138 -0.473995 0.0 0 | |||
M V30 49 N 2.20203 -0.0282408 0.0 0 CHG=1 | |||
M V30 50 N 11.3919 -0.210578 0.0 0 CHG=1 | |||
M V30 51 N 11.1362 -9.45447 0.0 0 CHG=1 | |||
M V30 52 N 1.91851 -9.36141 0.0 0 CHG=1 | |||
M V30 53 C 1.83427 0.838106 0.0 0 | |||
M V30 54 C 1.23653 -0.288636 0.0 0 | |||
M V30 55 C 2.94253 0.832155 0.0 0 | |||
M V30 56 C 12.3582 -0.46782 0.0 0 | |||
M V30 57 C 11.9565 0.604924 0.0 0 | |||
M V30 58 C 10.8756 0.496664 0.0 0 | |||
M V30 59 C 10.879 -10.4208 0.0 0 | |||
M V30 60 C 12.1017 -9.19408 0.0 0 | |||
M V30 61 C 11.8445 -10.1604 0.0 0 | |||
M V30 62 C 1.00216 -10.0292 0.0 0 | |||
M V30 63 C 2.17891 -10.3269 0.0 0 | |||
M V30 64 C 1.05811 -8.89591 0.0 0 | |||
M V30 65 Fe 6.65 -4.7 0.0 0 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 2 1 5 | |||
M V30 2 2 2 3 | |||
M V30 3 1 3 1 | |||
M V30 4 1 4 2 | |||
M V30 5 1 5 4 | |||
M V30 6 1 6 10 | |||
M V30 7 1 7 8 | |||
M V30 8 1 8 6 | |||
M V30 9 1 9 7 | |||
M V30 10 2 10 9 | |||
M V30 11 1 11 15 | |||
M V30 12 1 12 13 | |||
M V30 13 2 13 11 | |||
M V30 14 2 14 12 | |||
M V30 15 1 15 14 | |||
M V30 16 1 16 20 | |||
M V30 17 1 17 18 | |||
M V30 18 2 18 16 | |||
M V30 19 2 19 17 | |||
M V30 20 1 20 19 | |||
M V30 21 1 1 21 | |||
M V30 22 2 21 6 | |||
M V30 23 2 4 22 | |||
M V30 24 1 22 11 | |||
M V30 25 1 14 23 | |||
M V30 26 2 23 20 | |||
M V30 27 1 17 24 | |||
M V30 28 2 24 7 | |||
M V30 29 1 21 25 | |||
M V30 30 1 22 26 | |||
M V30 31 1 23 27 | |||
M V30 32 1 24 28 | |||
M V30 33 2 30 28 | |||
M V30 34 2 31 29 | |||
M V30 35 1 28 32 | |||
M V30 36 1 29 30 | |||
M V30 37 2 32 33 | |||
M V30 38 1 33 31 | |||
M V30 39 2 35 27 | |||
M V30 40 2 36 34 | |||
M V30 41 1 27 37 | |||
M V30 42 1 34 35 | |||
M V30 43 2 37 38 | |||
M V30 44 1 38 36 | |||
M V30 45 2 40 26 | |||
M V30 46 2 41 39 | |||
M V30 47 1 26 42 | |||
M V30 48 1 39 40 | |||
M V30 49 2 42 43 | |||
M V30 50 1 43 41 | |||
M V30 51 2 45 25 | |||
M V30 52 2 46 44 | |||
M V30 53 1 25 47 | |||
M V30 54 1 44 45 | |||
M V30 55 2 47 48 | |||
M V30 56 1 48 46 | |||
M V30 57 1 46 49 | |||
M V30 58 1 41 50 | |||
M V30 59 1 36 51 | |||
M V30 60 1 31 52 | |||
M V30 61 1 49 53 | |||
M V30 62 1 49 54 | |||
M V30 63 1 49 55 | |||
M V30 64 1 50 56 | |||
M V30 65 1 50 57 | |||
M V30 66 1 50 58 | |||
M V30 67 1 51 59 | |||
M V30 68 1 51 60 | |||
M V30 69 1 51 61 | |||
M V30 70 1 52 62 | |||
M V30 71 1 52 63 | |||
M V30 72 1 52 64 | |||
M V30 73 8 5 65 | |||
M V30 74 8 8 65 | |||
M V30 75 8 15 65 | |||
M V30 76 8 19 65 | |||
M V30 END BOND | |||
M V30 END CTAB | |||
M END | |||
</chemform> | |||
=== Photosensitizer === | |||
<chemform smiles="C1C=CC2N(C3C=C4C=CC=CC4=CC=3)C3C=CC=CC=3N(C3C=C4C=CC=CC4=CC=3)C=2C=1" inchi="1S/C32H22N2/c1-3-11-25-21-27(19-17-23(25)9-1)33-29-13-5-7-15-31(29)34(32-16-8-6-14-30(32)33)28-20-18-24-10-2-4-12-26(24)22-28/h1-22H" inchikey="HPIOBCHPZVAATK-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | |||
-INDIGO-12132211302D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 34 40 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C 3.91233 -5.02307 0.0 0 | |||
M V30 2 C 5.61175 -5.0949 0.0 0 | |||
M V30 3 C 4.79605 -4.57907 0.0 0 | |||
M V30 4 C 5.54977 -6.15186 0.0 0 | |||
M V30 5 C 3.85256 -6.01368 0.0 0 | |||
M V30 6 C 4.67931 -6.56731 0.0 0 | |||
M V30 7 N 6.52883 -4.61422 0.0 0 | |||
M V30 8 C 7.35622 -5.19678 0.0 0 | |||
M V30 9 N 6.38401 -6.72673 0.0 0 | |||
M V30 10 C 7.28677 -6.24949 0.0 0 | |||
M V30 11 C 8.23608 -4.78358 0.0 0 | |||
M V30 12 C 9.05543 -5.32508 0.0 0 | |||
M V30 13 C 8.12301 -6.76849 0.0 0 | |||
M V30 14 C 9.0033 -6.3106 0.0 0 | |||
M V30 15 C 5.92738 -1.93392 0.0 0 | |||
M V30 16 C 7.61282 -2.10418 0.0 0 | |||
M V30 17 C 6.81538 -1.53199 0.0 0 | |||
M V30 18 C 7.53648 -3.11073 0.0 0 | |||
M V30 19 C 5.80613 -2.9432 0.0 0 | |||
M V30 20 C 6.61436 -3.57057 0.0 0 | |||
M V30 21 C 6.91444 -0.543705 0.0 0 | |||
M V30 22 C 7.81662 -0.136082 0.0 0 | |||
M V30 23 C 8.5177 -1.68395 0.0 0 | |||
M V30 24 C 8.61162 -0.704955 0.0 0 | |||
M V30 25 C 5.44403 -8.2802 0.0 0 | |||
M V30 26 C 7.16488 -8.3212 0.0 0 | |||
M V30 27 C 6.33191 -7.77319 0.0 0 | |||
M V30 28 C 7.12347 -9.33368 0.0 0 | |||
M V30 29 C 5.42799 -9.29335 0.0 0 | |||
M V30 30 C 6.26482 -9.80583 0.0 0 | |||
M V30 31 C 7.9617 -9.8423 0.0 0 | |||
M V30 32 C 7.94554 -10.8177 0.0 0 | |||
M V30 33 C 6.24409 -10.7847 0.0 0 | |||
M V30 34 C 7.09136 -11.2935 0.0 0 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 2 3 1 | |||
M V30 2 2 4 2 | |||
M V30 3 1 1 5 | |||
M V30 4 1 2 3 | |||
M V30 5 2 5 6 | |||
M V30 6 1 6 4 | |||
M V30 7 1 8 7 | |||
M V30 8 1 4 9 | |||
M V30 9 1 7 2 | |||
M V30 10 1 9 10 | |||
M V30 11 2 10 8 | |||
M V30 12 2 12 11 | |||
M V30 13 1 10 13 | |||
M V30 14 1 11 8 | |||
M V30 15 2 13 14 | |||
M V30 16 1 14 12 | |||
M V30 17 2 17 15 | |||
M V30 18 2 18 16 | |||
M V30 19 1 15 19 | |||
M V30 20 1 16 17 | |||
M V30 21 2 19 20 | |||
M V30 22 1 20 18 | |||
M V30 23 2 22 21 | |||
M V30 24 1 16 23 | |||
M V30 25 1 21 17 | |||
M V30 26 2 23 24 | |||
M V30 27 1 24 22 | |||
M V30 28 2 27 25 | |||
M V30 29 2 28 26 | |||
M V30 30 1 25 29 | |||
M V30 31 1 26 27 | |||
M V30 32 2 29 30 | |||
M V30 33 1 30 28 | |||
M V30 34 2 32 31 | |||
M V30 35 1 30 33 | |||
M V30 36 1 31 28 | |||
M V30 37 2 33 34 | |||
M V30 38 1 34 32 | |||
M V30 39 1 9 27 | |||
M V30 40 1 7 20 | |||
M V30 END BOND | |||
M V30 END CTAB | |||
M END | |||
</chemform><chemform smiles="C1C(C2C=CC(C3C=CC=CC=3)=CC=2)=CC2OC3C=C(C4C=CC(C5C=CC=CC=5)=CC=4)C=CC=3N(C3C4C=CC=CC=4C=CC=3)C=2C=1" inchi="1S/C46H31NO/c1-3-10-32(11-4-1)34-18-22-36(23-19-34)39-26-28-43-45(30-39)48-46-31-40(37-24-20-35(21-25-37)33-12-5-2-6-13-33)27-29-44(46)47(43)42-17-9-15-38-14-7-8-16-41(38)42/h1-31H" inchikey="IGGSSEOAGCUGDJ-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | |||
-INDIGO-12132211312D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 48 56 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C 4.03719 -4.80901 0.0 0 | |||
M V30 2 C 5.71793 -4.68897 0.0 0 | |||
M V30 3 C 4.869 -4.26093 0.0 0 | |||
M V30 4 C 5.76956 -5.7007 0.0 0 | |||
M V30 5 C 4.0675 -5.8505 0.0 0 | |||
M V30 6 C 4.95944 -6.25414 0.0 0 | |||
M V30 7 N 6.5454 -4.05737 0.0 0 | |||
M V30 8 C 7.43541 -4.62039 0.0 0 | |||
M V30 9 O 6.65215 -6.129 0.0 0 | |||
M V30 10 C 7.47698 -5.62566 0.0 0 | |||
M V30 11 C 8.25686 -4.11474 0.0 0 | |||
M V30 12 C 9.13626 -4.57924 0.0 0 | |||
M V30 13 C 8.35546 -6.09691 0.0 0 | |||
M V30 14 C 9.219 -5.58639 0.0 0 | |||
M V30 15 C 10.086 -6.21901 0.0 0 | |||
M V30 16 C 11.818 -6.52553 0.0 0 | |||
M V30 17 C 11.0202 -5.88473 0.0 0 | |||
M V30 18 C 11.6894 -7.5674 0.0 0 | |||
M V30 19 C 9.96793 -7.22097 0.0 0 | |||
M V30 20 C 10.7678 -7.87388 0.0 0 | |||
M V30 21 C 12.5001 -8.25494 0.0 0 | |||
M V30 22 C 14.1899 -8.61261 0.0 0 | |||
M V30 23 C 13.4337 -7.96627 0.0 0 | |||
M V30 24 C 14.0381 -9.5616 0.0 0 | |||
M V30 25 C 12.3633 -9.2953 0.0 0 | |||
M V30 26 C 13.1489 -9.91797 0.0 0 | |||
M V30 27 C 1.69302 -6.99297 0.0 0 | |||
M V30 28 C 3.30886 -6.48918 0.0 0 | |||
M V30 29 C 2.39038 -6.28041 0.0 0 | |||
M V30 30 C 3.55288 -7.47778 0.0 0 | |||
M V30 31 C 1.94211 -7.97398 0.0 0 | |||
M V30 32 C 2.85841 -8.18925 0.0 0 | |||
M V30 33 C -0.364828 -9.10174 0.0 0 | |||
M V30 34 C 1.25547 -8.6624 0.0 0 | |||
M V30 35 C 0.342485 -8.42423 0.0 0 | |||
M V30 36 C 1.47751 -9.6572 0.0 0 | |||
M V30 37 C -0.151173 -10.0352 0.0 0 | |||
M V30 38 C 0.76444 -10.3236 0.0 0 | |||
M V30 39 C 5.63752 -1.25497 0.0 0 | |||
M V30 40 C 7.3359 -1.26278 0.0 0 | |||
M V30 41 C 6.48221 -0.779005 0.0 0 | |||
M V30 42 C 7.34346 -2.28039 0.0 0 | |||
M V30 43 C 5.61899 -2.27884 0.0 0 | |||
M V30 44 C 6.50104 -2.87031 0.0 0 | |||
M V30 45 C 8.17669 -0.755127 0.0 0 | |||
M V30 46 C 9.03041 -1.24419 0.0 0 | |||
M V30 47 C 8.20106 -2.73313 0.0 0 | |||
M V30 48 C 9.03418 -2.21637 0.0 0 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 2 3 1 | |||
M V30 2 2 4 2 | |||
M V30 3 1 1 5 | |||
M V30 4 1 2 3 | |||
M V30 5 2 5 6 | |||
M V30 6 1 6 4 | |||
M V30 7 1 8 7 | |||
M V30 8 1 4 9 | |||
M V30 9 1 7 2 | |||
M V30 10 1 9 10 | |||
M V30 11 2 10 8 | |||
M V30 12 2 12 11 | |||
M V30 13 1 10 13 | |||
M V30 14 1 11 8 | |||
M V30 15 2 13 14 | |||
M V30 16 1 14 12 | |||
M V30 17 2 17 15 | |||
M V30 18 2 18 16 | |||
M V30 19 1 15 19 | |||
M V30 20 1 16 17 | |||
M V30 21 2 19 20 | |||
M V30 22 1 20 18 | |||
M V30 23 2 23 21 | |||
M V30 24 2 24 22 | |||
M V30 25 1 21 25 | |||
M V30 26 1 22 23 | |||
M V30 27 2 25 26 | |||
M V30 28 1 26 24 | |||
M V30 29 2 29 27 | |||
M V30 30 2 30 28 | |||
M V30 31 1 27 31 | |||
M V30 32 1 28 29 | |||
M V30 33 2 31 32 | |||
M V30 34 1 32 30 | |||
M V30 35 2 35 33 | |||
M V30 36 2 36 34 | |||
M V30 37 1 33 37 | |||
M V30 38 1 34 35 | |||
M V30 39 2 37 38 | |||
M V30 40 1 38 36 | |||
M V30 41 2 41 39 | |||
M V30 42 2 42 40 | |||
M V30 43 1 39 43 | |||
M V30 44 1 40 41 | |||
M V30 45 2 43 44 | |||
M V30 46 1 44 42 | |||
M V30 47 2 46 45 | |||
M V30 48 1 42 47 | |||
M V30 49 1 45 40 | |||
M V30 50 2 47 48 | |||
M V30 51 1 48 46 | |||
M V30 52 1 5 28 | |||
M V30 53 1 31 34 | |||
M V30 54 1 14 15 | |||
M V30 55 1 18 21 | |||
M V30 56 1 7 44 | |||
M V30 END BOND | |||
M V30 END CTAB | |||
M END | |||
</chemform> |
Revision as of 11:32, 13 December 2022
Catalyst
Photosensitizer
5,10-Di(2-naphthyl)-5,10-dihydrophenazine 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine
Literature
[VLD18] Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst. Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert, Journal of the American Chemical Society 2018, Vol. 140, Pages 17830-17834. DOI2: 10.1021/jacs.8b09740
Publication: Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst
Publication: Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst
Investigations
- Photocatalytic reduction of CO (Molecular process, Photocatalytic CO2 conversion experiments)
- Photocatalytic reduction of CO2 (Molecular process, Photocatalytic CO2 conversion experiments)