Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 14:43, 12 December 2022

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	1	2	13
2.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	2	4	21
3.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	13	8	62
4.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	8	8	34
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	7	9	40
6.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	4	27

Investigation-Name: Table 1

Literature

[PRo15] Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light. Alonso Rosas-Hernández, Henrik Junge, Matthias Beller, ChemCatChem 2015, Vol. 7, Pages 3316-3321. DOI2: 10.1002/cctc.201500494
Publication: Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light

Investigations

CO2 reduction experiments (Molecular process, Photocatalytic CO2 conversion experiments)
Optimization of concentrations (Molecular process, Photocatalytic CO2 conversion experiments)
Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 2 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 3 - CV (Assay, Cyclic Voltammetry experiments)

@@ Line 306: / Line 306: @@
 M  V30 37 8 27 25
 M  V30 38 8 26 25
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform><chemform smiles="C1C2C3C=CC=CC=3~[Ir]3(~C4C=CC=CC=4C4C=CC=CN=4~3)3(~N4=C(C5N~3=CC=CC=5)C=CC=C4)~N=2C=CC=1.P(F)(F)(F)(F)(F)F" inchi="1S/2C11H9N.C10H8N2.F6P.Ir/c2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-7(2,3,4,5)6;/h2*1-9H;1-8H;;" inchikey="YLYRMTZQAOANTD-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-12122214422D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 44 51 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 6.86521 -4.85135 0.0 0
+M  V30 2 C 8.41771 -4.69374 0.0 0
+M  V30 3 C 7.49611 -4.29588 0.0 0
+M  V30 4 C 8.59253 -5.83511 0.0 0
+M  V30 5 C 7.08033 -5.78282 0.0 0
+M  V30 6 N 8.11488 -6.23567 0.0 0
+M  V30 7 C 4.87789 -6.03109 0.0 0
+M  V30 8 C 6.55161 -6.17412 0.0 0
+M  V30 9 C 5.65652 -5.63903 0.0 0
+M  V30 10 C 6.70386 -7.1489 0.0 0
+M  V30 11 C 4.86086 -7.04446 0.0 0
+M  V30 12 C 5.78608 -7.65601 0.0 0
+M  V30 13 C 8.0594 -9.2927 0.0 0
+M  V30 14 C 9.54214 -8.78128 0.0 0
+M  V30 15 N 8.79341 -8.63647 0.0 0
+M  V30 16 C 9.81309 -9.84419 0.0 0
+M  V30 17 C 8.29341 -10.2043 0.0 0
+M  V30 18 C 9.12893 -10.5036 0.0 0
+M  V30 19 C 9.10181 -5.24617 0.0 0
+M  V30 20 C 10.8976 -5.28114 0.0 0
+M  V30 21 C 10.0549 -4.75542 0.0 0
+M  V30 22 C 10.8699 -6.15407 0.0 0
+M  V30 23 N 9.1085 -6.4053 0.0 0
+M  V30 24 C 10.0024 -6.72701 0.0 0
+M  V30 25 C 10.2008 -7.25568 0.0 0
+M  V30 26 C 11.7569 -8.07717 0.0 0
+M  V30 27 C 11.2664 -7.30936 0.0 0
+M  V30 28 C 11.2618 -8.93626 0.0 0
+M  V30 29 N 9.55862 -7.95889 0.0 0
+M  V30 30 C 10.1287 -8.92474 0.0 0
+M  V30 31 Ir 8.17869 -7.44217 0.0 0
+M  V30 32 C 5.79321 -8.64181 0.0 0
+M  V30 33 C 7.16286 -8.04741 0.0 0
+M  V30 34 C 6.53603 -7.81358 0.0 0
+M  V30 35 C 7.38389 -9.10258 0.0 0
+M  V30 36 C 6.06915 -9.51366 0.0 0
+M  V30 37 C 6.79378 -9.63661 0.0 0
+M  V30 38 P 14.3 -3.6 0.0 0
+M  V30 39 F 14.3 -2.6 0.0 0
+M  V30 40 F 15.3 -3.6 0.0 0
+M  V30 41 F 13.3 -3.6 0.0 0
+M  V30 42 F 14.3 -4.6 0.0 0
+M  V30 43 F 15.0071 -4.30711 0.0 0
+M  V30 44 F 13.5929 -2.89289 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 2 9 7
+M  V30 8 2 10 8
+M  V30 9 1 7 11
+M  V30 10 1 8 9
+M  V30 11 2 11 12
+M  V30 12 1 12 10
+M  V30 13 2 15 13
+M  V30 14 2 16 14
+M  V30 15 1 13 17
+M  V30 16 1 14 15
+M  V30 17 2 17 18
+M  V30 18 1 18 16
+M  V30 19 2 21 19
+M  V30 20 2 22 20
+M  V30 21 1 19 23
+M  V30 22 1 20 21
+M  V30 23 2 23 24
+M  V30 24 1 24 22
+M  V30 25 2 27 25
+M  V30 26 2 28 26
+M  V30 27 1 25 29
+M  V30 28 1 26 27
+M  V30 29 2 29 30
+M  V30 30 1 30 28
+M  V30 31 1 8 5
+M  V30 32 1 24 25
+M  V30 33 8 6 31
+M  V30 34 8 10 31
+M  V30 35 8 15 31
+M  V30 36 8 31 29
+M  V30 37 8 23 31
+M  V30 38 2 34 32
+M  V30 39 2 35 33
+M  V30 40 1 32 36
+M  V30 41 1 33 34
+M  V30 42 2 36 37
+M  V30 43 1 37 35
+M  V30 44 1 35 13
+M  V30 45 8 33 31
+M  V30 46 1 38 39
+M  V30 47 1 38 40
+M  V30 48 1 38 41
+M  V30 49 1 38 42
+M  V30 50 1 38 43
+M  V30 51 1 38 44
 M  V30 END BOND
 M  V30 END CTAB

Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 14:43, 12 December 2022

Literature

Investigations

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