Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 14:25, 12 December 2022

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	1	2	13
2.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	2	4	21
3.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	13	8	62
4.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	8	8	34
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	7	9	40
6.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	4	27

Investigation-Name: Table 1

Literature

[PRo15] Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light. Alonso Rosas-Hernández, Henrik Junge, Matthias Beller, ChemCatChem 2015, Vol. 7, Pages 3316-3321. DOI2: 10.1002/cctc.201500494
Publication: Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light

Investigations

CO2 reduction experiments (Molecular process, Photocatalytic CO2 conversion experiments)
Optimization of concentrations (Molecular process, Photocatalytic CO2 conversion experiments)
Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 2 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 3 - CV (Assay, Cyclic Voltammetry experiments)

@@ Line 1: / Line 1: @@
 [[Category:Photocatalytic CO2 conversion to HCOOH]]
+{{#literature:|doi=http://dx.doi.org/10.1002/cctc.201500494}}
+<chemform smiles="C1C=CN2~[Ru](~[*])(~[*])3(~N4C=CC=CC=4C4N~3=CC=CC=4)~N3C=CC=CC=3C=2C=1" inchi="" inchikey="" height="200px" width="300px" float="none" r1="Cl,Cl,H" r2="Cl,CO,CO">
+  -INDIGO-12122214162D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 27 32 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 4.42164 -3.4051 0.0 0
+M  V30 2 C 6.16573 -3.41315 0.0 0
+M  V30 3 C 5.23126 -2.93902 0.0 0
+M  V30 4 N 6.24607 -4.34967 0.0 0
+M  V30 5 C 4.43988 -4.2752 0.0 0
+M  V30 6 C 5.33647 -4.80741 0.0 0
+M  V30 7 C 7.1536 -2.01998 0.0 0
+M  V30 8 C 8.69562 -2.15033 0.0 0
+M  V30 9 C 7.97052 -1.65293 0.0 0
+M  V30 10 C 8.6606 -3.11885 0.0 0
+M  V30 11 C 7.04069 -2.96795 0.0 0
+M  V30 12 N 7.81868 -3.57293 0.0 0
+M  V30 13 C 5.6923 -5.52361 0.0 0
+M  V30 14 C 6.93663 -6.52444 0.0 0
+M  V30 15 N 6.60503 -5.6549 0.0 0
+M  V30 16 C 6.34029 -7.29343 0.0 0
+M  V30 17 C 5.12026 -6.37657 0.0 0
+M  V30 18 C 5.48652 -7.18714 0.0 0
+M  V30 19 C 7.64521 -6.74796 0.0 0
+M  V30 20 C 9.23795 -6.29939 0.0 0
+M  V30 21 N 8.25086 -6.00768 0.0 0
+M  V30 22 C 9.43514 -7.33957 0.0 0
+M  V30 23 C 7.96229 -7.64558 0.0 0
+M  V30 24 C 8.77162 -7.93243 0.0 0
+M  V30 25 R# 8.45093 -4.23617 0.0 0 RGROUPS=(1 1)
+M  V30 26 R# 8.54195 -5.09895 0.0 0 RGROUPS=(1 2)
+M  V30 27 Ru 7.51723 -4.8062 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 2 9 7
+M  V30 8 2 10 8
+M  V30 9 1 7 11
+M  V30 10 1 8 9
+M  V30 11 2 11 12
+M  V30 12 1 12 10
+M  V30 13 2 15 13
+M  V30 14 2 16 14
+M  V30 15 1 13 17
+M  V30 16 1 14 15
+M  V30 17 2 17 18
+M  V30 18 1 18 16
+M  V30 19 2 21 19
+M  V30 20 2 22 20
+M  V30 21 1 19 23
+M  V30 22 1 20 21
+M  V30 23 2 23 24
+M  V30 24 1 24 22
+M  V30 25 1 2 11
+M  V30 26 1 14 19
+M  V30 27 8 4 27
+M  V30 28 8 12 27
+M  V30 29 8 15 27
+M  V30 30 8 21 27
+M  V30 31 8 27 26
+M  V30 32 8 27 25
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform><chemform smiles="C12C3N(~[Ru]4(~OC(=O)O~4)(~N=1C=CC=C2)1~N2C=CC=CC=2C2C=CC=CN=2~1)=CC=CC=3" inchi="1S/2C10H8N2.CH2O3.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2-1(3)4;/h2*1-8H;(H2,2,3,4);" inchikey="IFHMCSXTESYUKW-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-12122214192D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 29 35 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 6.56741 -6.68319 0.0 0
+M  V30 2 C 8.11231 -6.66374 0.0 0
+M  V30 3 N 7.27159 -6.16192 0.0 0
+M  V30 4 C 8.03707 -7.70884 0.0 0
+M  V30 5 C 6.56426 -7.64408 0.0 0
+M  V30 6 C 7.25438 -8.11292 0.0 0
+M  V30 7 C 4.53118 -5.87604 0.0 0
+M  V30 8 C 5.94132 -6.45732 0.0 0
+M  V30 9 N 5.62526 -5.32717 0.0 0
+M  V30 10 C 5.3951 -7.26705 0.0 0
+M  V30 11 C 4.21463 -6.83191 0.0 0
+M  V30 12 C 4.663 -7.38484 0.0 0
+M  V30 13 C 4.1135 -3.04669 0.0 0
+M  V30 14 C 5.67958 -3.31686 0.0 0
+M  V30 15 C 4.90041 -2.7337 0.0 0
+M  V30 16 N 5.75336 -4.35759 0.0 0
+M  V30 17 C 4.01212 -3.97499 0.0 0
+M  V30 18 C 4.86237 -4.70365 0.0 0
+M  V30 19 C 6.35435 -2.08934 0.0 0
+M  V30 20 C 7.92555 -2.17068 0.0 0
+M  V30 21 C 7.10211 -1.68986 0.0 0
+M  V30 22 C 8.00648 -3.2044 0.0 0
+M  V30 23 C 6.41645 -3.04684 0.0 0
+M  V30 24 N 7.24402 -3.65388 0.0 0
+M  V30 25 Ru 7.016 -4.96602 0.0 0
+M  V30 26 O 7.88207 -4.26835 0.0 0
+M  V30 27 O 7.92258 -5.58581 0.0 0
+M  V30 28 C 8.60103 -4.9236 0.0 0
+M  V30 29 O 9.63033 -4.89734 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 2 9 7
+M  V30 8 2 10 8
+M  V30 9 1 7 11
+M  V30 10 1 8 9
+M  V30 11 2 11 12
+M  V30 12 1 12 10
+M  V30 13 2 15 13
+M  V30 14 2 16 14
+M  V30 15 1 13 17
+M  V30 16 1 14 15
+M  V30 17 2 17 18
+M  V30 18 1 18 16
+M  V30 19 2 21 19
+M  V30 20 2 22 20
+M  V30 21 1 19 23
+M  V30 22 1 20 21
+M  V30 23 2 23 24
+M  V30 24 1 24 22
+M  V30 25 1 14 23
+M  V30 26 1 8 1
+M  V30 27 8 16 25
+M  V30 28 8 24 25
+M  V30 29 8 9 25
+M  V30 30 8 3 25
+M  V30 31 1 26 28
+M  V30 32 1 27 28
+M  V30 33 2 28 29
+M  V30 34 8 26 25
+M  V30 35 8 27 25
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform><chemform smiles="C1C=CN2~[Ru](~C#O)(~O([H])[H])3(~N4C=CC=CC=4C4N~3=CC=CC=4)~N3C=CC=CC=3C=2C=1" inchi="1S/2C10H8N2.CHO.H2O.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-2;;/h2*1-8H;1H;1H2;" inchikey="FMDXTMDWVPGKIR-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-12122214222D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 30 35 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 4.88353 -4.01367 0.0 0
+M  V30 2 C 6.49467 -4.14508 0.0 0
+M  V30 3 C 5.65227 -3.62021 0.0 0
+M  V30 4 N 6.59022 -5.14567 0.0 0
+M  V30 5 C 4.85996 -4.97527 0.0 0
+M  V30 6 C 5.77142 -5.58913 0.0 0
+M  V30 7 C 7.02354 -2.8684 0.0 0
+M  V30 8 C 8.59272 -2.82698 0.0 0
+M  V30 9 C 7.73189 -2.39265 0.0 0
+M  V30 10 C 8.69857 -3.84084 0.0 0
+M  V30 11 C 7.09288 -3.79375 0.0 0
+M  V30 12 N 8.03247 -4.33342 0.0 0
+M  V30 13 C 7.38633 -7.34736 0.0 0
+M  V30 14 C 5.9367 -7.55656 0.0 0
+M  V30 15 C 6.74404 -7.90844 0.0 0
+M  V30 16 C 5.83442 -6.56452 0.0 0
+M  V30 17 N 7.19184 -6.19665 0.0 0
+M  V30 18 C 6.56743 -5.9679 0.0 0
+M  V30 19 C 8.07224 -7.64104 0.0 0
+M  V30 20 C 9.73101 -7.40193 0.0 0
+M  V30 21 N 8.69266 -7.00028 0.0 0
+M  V30 22 C 9.81611 -8.45063 0.0 0
+M  V30 23 C 8.18872 -8.58778 0.0 0
+M  V30 24 C 9.00146 -8.99698 0.0 0
+M  V30 25 Ru 7.94968 -5.63386 0.0 0
+M  V30 26 O 9.14992 -5.06621 0.0 0
+M  V30 27 C 8.91539 -6.04352 0.0 0
+M  V30 28 O 9.8811 -6.45318 0.0 0
+M  V30 29 H 9.37348 -4.08653 0.0 0
+M  V30 30 H 9.92585 -5.60144 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 2 9 7
+M  V30 8 2 10 8
+M  V30 9 1 7 11
+M  V30 10 1 8 9
+M  V30 11 2 11 12
+M  V30 12 1 12 10
+M  V30 13 2 15 13
+M  V30 14 2 16 14
+M  V30 15 1 13 17
+M  V30 16 1 14 15
+M  V30 17 2 17 18
+M  V30 18 1 18 16
+M  V30 19 2 21 19
+M  V30 20 2 22 20
+M  V30 21 1 19 23
+M  V30 22 1 20 21
+M  V30 23 2 23 24
+M  V30 24 1 24 22
+M  V30 25 1 13 19
+M  V30 26 1 2 11
+M  V30 27 8 4 25
+M  V30 28 8 12 25
+M  V30 29 8 17 25
+M  V30 30 8 21 25
+M  V30 31 8 25 26
+M  V30 32 8 25 27
+M  V30 33 3 27 28
+M  V30 34 1 26 29
+M  V30 35 1 26 30
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform><chemform smiles="C1C=CC2C3C=CC=CN=3~[Ru](~O=C(C)C)(~O=C(C)C)(~N=2C=1)1~N2C=CC=CC=2C2=N~1C=CC=C2" inchi="1S/2C10H8N2.2C3H6O.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-3(2)4;/h2*1-8H;2*1-2H3;" inchikey="XKWYLOQQGBAKSH-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-12122214242D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 33 38 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 5.50573 -7.17225 0.0 0
+M  V30 2 N 6.9043 -7.15427 0.0 0
+M  V30 3 C 6.25586 -6.82978 0.0 0
+M  V30 4 C 6.71695 -8.15589 0.0 0
+M  V30 5 C 5.33916 -7.91747 0.0 0
+M  V30 6 C 5.91415 -8.44484 0.0 0
+M  V30 7 C 7.21625 -8.56484 0.0 0
+M  V30 8 C 8.63947 -8.85859 0.0 0
+M  V30 9 N 8.10539 -8.15209 0.0 0
+M  V30 10 C 8.35907 -9.69478 0.0 0
+M  V30 11 C 7.06492 -9.39434 0.0 0
+M  V30 12 C 7.62204 -9.91148 0.0 0
+M  V30 13 C 5.16785 -4.55363 0.0 0
+M  V30 14 C 6.51757 -4.39553 0.0 0
+M  V30 15 C 5.78824 -4.09545 0.0 0
+M  V30 16 N 6.77993 -5.43252 0.0 0
+M  V30 17 C 5.28775 -5.36582 0.0 0
+M  V30 18 C 6.08144 -5.77947 0.0 0
+M  V30 19 C 6.75408 -3.2373 0.0 0
+M  V30 20 C 8.12511 -3.00621 0.0 0
+M  V30 21 C 7.36697 -2.72554 0.0 0
+M  V30 22 C 8.36806 -3.8652 0.0 0
+M  V30 23 C 7.00126 -4.13112 0.0 0
+M  V30 24 N 7.89367 -4.47269 0.0 0
+M  V30 25 Ru 8.41026 -6.26132 0.0 0
+M  V30 26 O 9.24511 -5.12874 0.0 0
+M  V30 27 O 9.35312 -7.066 0.0 0
+M  V30 28 C 10.4996 -4.95962 0.0 0
+M  V30 29 C 10.811 -3.86385 0.0 0
+M  V30 30 C 11.3172 -5.67688 0.0 0
+M  V30 31 C 10.0768 -7.51261 0.0 0
+M  V30 32 C 10.9279 -7.12955 0.0 0
+M  V30 33 C 10.103 -8.67227 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 2 9 7
+M  V30 8 2 10 8
+M  V30 9 1 7 11
+M  V30 10 1 8 9
+M  V30 11 2 11 12
+M  V30 12 1 12 10
+M  V30 13 2 15 13
+M  V30 14 2 16 14
+M  V30 15 1 13 17
+M  V30 16 1 14 15
+M  V30 17 2 17 18
+M  V30 18 1 18 16
+M  V30 19 2 21 19
+M  V30 20 2 22 20
+M  V30 21 1 19 23
+M  V30 22 1 20 21
+M  V30 23 2 23 24
+M  V30 24 1 24 22
+M  V30 25 1 14 23
+M  V30 26 1 4 7
+M  V30 27 2 26 28
+M  V30 28 1 28 29
+M  V30 29 1 28 30
+M  V30 30 2 27 31
+M  V30 31 1 31 32
+M  V30 32 1 31 33
+M  V30 33 8 24 25
+M  V30 34 8 16 25
+M  V30 35 8 2 25
+M  V30 36 8 9 25
+M  V30 37 8 27 25
+M  V30 38 8 26 25
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}

Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light: Difference between revisions

Revision as of 14:25, 12 December 2022

Literature

Investigations

Current site

Topics