Electrocatalytic Reduction of CO2 to Ethylene by Molecular Cu-Complex Immobilized on Graphitized Mesoporous Carbon: Difference between revisions

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==== Catalyst ====
==== Catalyst ====
<chemform smiles="[Cu]123(N4=C(CN1(CC1NC5C(N=12)=CC=CC=5)CC1NC2C(N=13)=CC=CC=2)NC1C4=CC=CC=1)1Cl[Cu]234(N(CC5NC6C(N=52)=CC=CC=6)(CC2NC5C(N=23)=CC=CC=5)CC2NC3C(N=24)=CC=CC=3)Cl1" inchi="1S/2C24H21N7.2ClH.2Cu/c2*1-2-8-17-16(7-1)25-22(26-17)13-31(14-23-27-18-9-3-4-10-19(18)28-23)15-24-29-20-11-5-6-12-21(20)30-24;;;;/h2*1-12H,13-15H2,(H,25,26)(H,27,28)(H,29,30);2*1H;;" inchikey="PYXUXRSTRODUJL-UHFFFAOYSA-N" height="200px" width="300px" float="none" margin="0px 0px 0px 0px">
<chemform smiles="[Cu+]123(~N4=C(CN~1(CC1NC5C(N=1~2)=CC=CC=5)CC1NC2C(N=1~3)=CC=CC=2)NC1C4=CC=CC=1)1~[Cl-]~[Cu+]234(~N(CC5NC6C(N=5~2)=CC=CC=6)(CC2NC5C(N=2~3)=CC=CC=5)CC2NC3C(N=2~4)=CC=CC=3)~[Cl-]~1" inchi="1S/2C24H21N7.2ClH.2Cu/c2*1-2-8-17-16(7-1)25-22(26-17)13-31(14-23-27-18-9-3-4-10-19(18)28-23)15-24-29-20-11-5-6-12-21(20)30-24;;;;/h2*1-12H,13-15H2,(H,25,26)(H,27,28)(H,29,30);2*1H;;/q;;;;2*+1/p-2" inchikey="JHYRJWCOLBSREV-UHFFFAOYSA-L" height="200px" width="300px" float="none" margin="0px 0px 0px 0px">
   -INDIGO-04012615112D
   -INDIGO-04012615162D


   0  0  0  0  0  0  0  0  0  0  0 V3000
   0  0  0  0  0  0  0  0  0  0  0 V3000
Line 23: Line 23:
M  V30 COUNTS 66 84 0 0 0
M  V30 COUNTS 66 84 0 0 0
M  V30 BEGIN ATOM
M  V30 BEGIN ATOM
M  V30 1 Cu 1.92517 -1.12471 0.0 0
M  V30 1 Cu 5.75017 -3.57471 0.0 0 CHG=1
M  V30 2 Cu 5.77098 -1.12471 0.0 0
M  V30 2 Cu 9.59598 -3.57471 0.0 0 CHG=1
M  V30 3 Cl 4.24012 -0.0608267 0.0 0
M  V30 3 Cl 8.06512 -2.51083 0.0 0 CHG=-1
M  V30 4 Cl 3.41869 -2.18909 0.0 0
M  V30 4 Cl 7.24369 -4.63909 0.0 0 CHG=-1
M  V30 5 C -1.00262 -3.14394 0.0 0
M  V30 5 C 2.82238 -5.59394 0.0 0
M  V30 6 C -1.36106 -3.76475 0.0 0
M  V30 6 C 2.46394 -6.21475 0.0 0
M  V30 7 C -1.00262 -4.38555 0.0 0
M  V30 7 C 2.82238 -6.83556 0.0 0
M  V30 8 C -0.285733 -4.38555 0.0 0
M  V30 8 C 3.53927 -6.83556 0.0 0
M  V30 9 C 0.0727113 -3.76475 0.0 0
M  V30 9 C 3.89771 -6.21475 0.0 0
M  V30 10 C -0.285733 -3.14394 0.0 0
M  V30 10 C 3.53927 -5.59394 0.0 0
M  V30 11 N -0.0641944 -2.4619 0.0 0
M  V30 11 N 3.76081 -4.9119 0.0 0
M  V30 12 C -0.644177 -2.04073 0.0 0
M  V30 12 C 3.18082 -4.49073 0.0 0
M  V30 13 N -1.22416 -2.4619 0.0 0
M  V30 13 N 2.60084 -4.9119 0.0 0
M  V30 14 C 1.86792 -3.97434 0.0 0
M  V30 14 C 5.69292 -6.42434 0.0 0
M  V30 15 C 1.95454 -4.68575 0.0 0
M  V30 15 C 5.77954 -7.13575 0.0 0
M  V30 16 C 2.61418 -4.96653 0.0 0
M  V30 16 C 6.43918 -7.41653 0.0 0
M  V30 17 C 3.18719 -4.5354 0.0 0
M  V30 17 C 7.01219 -6.9854 0.0 0
M  V30 18 C 3.10057 -3.82399 0.0 0
M  V30 18 C 6.92557 -6.27399 0.0 0
M  V30 19 C 2.44093 -3.54321 0.0 0
M  V30 19 C 6.26593 -5.99321 0.0 0
M  V30 20 N 2.20794 -2.86515 0.0 0
M  V30 20 N 6.03294 -5.31515 0.0 0
M  V30 21 C 1.49106 -2.8771 0.0 0
M  V30 21 C 5.31606 -5.3271 0.0 0
M  V30 22 N 1.28097 -3.56263 0.0 0
M  V30 22 N 5.10597 -6.01263 0.0 0
M  V30 23 C 1.97545 1.83445 0.0 0
M  V30 23 C 5.80045 -0.615553 0.0 0
M  V30 24 C 2.47727 2.34672 0.0 0
M  V30 24 C 6.30227 -0.103277 0.0 0
M  V30 25 C 3.17126 2.1685 0.0 0
M  V30 25 C 6.99626 -0.281503 0.0 0
M  V30 26 C 3.36442 1.47799 0.0 0
M  V30 26 C 7.18942 -0.972006 0.0 0
M  V30 27 C 2.8631 0.965717 0.0 0
M  V30 27 C 6.6881 -1.48428 0.0 0
M  V30 28 C 2.16861 1.14394 0.0 0
M  V30 28 C 5.99361 -1.30606 0.0 0
M  V30 29 N 1.5717 0.746668 0.0 0
M  V30 29 N 5.3967 -1.70333 0.0 0
M  V30 30 C 1.00964 1.19223 0.0 0
M  V30 30 C 4.83464 -1.25777 0.0 0
M  V30 31 N 1.25956 1.86382 0.0 0
M  V30 31 N 5.08456 -0.586181 0.0 0
M  V30 32 N 0.543667 -0.322192 0.0 0
M  V30 32 N 4.36867 -2.77219 0.0 0
M  V30 33 N 7.37651 -1.74103 0.0 0
M  V30 33 N 11.2015 -4.19103 0.0 0
M  V30 34 C 0.282302 0.685932 0.0 0
M  V30 34 C 4.1073 -1.76407 0.0 0
M  V30 35 C -0.539133 -1.06895 0.0 0
M  V30 35 C 3.28587 -3.51895 0.0 0
M  V30 36 C 0.543667 -1.62902 0.0 0
M  V30 36 C 4.36867 -4.07902 0.0 0
M  V30 37 C 5.46929 -4.09034 0.0 0
M  V30 37 C 9.29429 -6.54034 0.0 0
M  V30 38 C 4.89876 -4.52395 0.0 0
M  V30 38 C 8.72376 -6.97395 0.0 0
M  V30 39 C 4.23763 -4.24666 0.0 0
M  V30 39 C 8.06263 -6.69666 0.0 0
M  V30 40 C 4.14752 -3.53525 0.0 0
M  V30 40 C 7.97252 -5.98525 0.0 0
M  V30 41 C 4.71805 -3.10163 0.0 0
M  V30 41 C 8.54305 -5.55163 0.0 0
M  V30 42 C 5.37918 -3.37942 0.0 0
M  V30 42 C 9.20418 -5.82942 0.0 0
M  V30 43 N 6.02786 -3.07375 0.0 0
M  V30 43 N 9.85286 -5.52375 0.0 0
M  V30 44 C 6.51873 -3.59598 0.0 0
M  V30 44 C 10.3437 -6.04598 0.0 0
M  V30 45 N 6.17373 -4.22425 0.0 0
M  V30 45 N 9.99873 -6.67425 0.0 0
M  V30 46 C 8.50262 1.72492 0.0 0
M  V30 46 C 12.3276 -0.725078 0.0 0
M  V30 47 C 8.86106 2.34573 0.0 0
M  V30 47 C 12.6861 -0.104272 0.0 0
M  V30 48 C 8.50262 2.96653 0.0 0
M  V30 48 C 12.3276 0.516533 0.0 0
M  V30 49 C 7.78573 2.96653 0.0 0
M  V30 49 C 11.6107 0.516533 0.0 0
M  V30 50 C 7.42729 2.34573 0.0 0
M  V30 50 C 11.2523 -0.104272 0.0 0
M  V30 51 C 7.78573 1.72492 0.0 0
M  V30 51 C 11.6107 -0.725078 0.0 0
M  V30 52 N 7.56419 1.04338 0.0 0
M  V30 52 N 11.3892 -1.40662 0.0 0
M  V30 53 C 8.14418 0.621711 0.0 0
M  V30 53 C 11.9692 -1.82829 0.0 0
M  V30 54 N 8.72416 1.04338 0.0 0
M  V30 54 N 12.5492 -1.40662 0.0 0
M  V30 55 C 5.37619 2.13215 0.0 0
M  V30 55 C 9.20119 -0.317846 0.0 0
M  V30 56 C 4.87935 2.64841 0.0 0
M  V30 56 C 8.70435 0.198413 0.0 0
M  V30 57 C 4.18337 2.47666 0.0 0
M  V30 57 C 8.00837 0.0266596 0.0 0
M  V30 58 C 3.98423 1.78765 0.0 0
M  V30 58 C 7.80923 -0.66235 0.0 0
M  V30 59 C 4.48157 1.27089 0.0 0
M  V30 59 C 8.30657 -1.17911 0.0 0
M  V30 60 C 5.17755 1.44315 0.0 0
M  V30 60 C 9.00255 -1.00685 0.0 0
M  V30 61 N 5.77098 1.04139 0.0 0
M  V30 61 N 9.59598 -1.40861 0.0 0
M  V30 62 C 6.33652 1.48148 0.0 0
M  V30 62 C 10.1615 -0.968522 0.0 0
M  V30 63 N 6.09258 2.15555 0.0 0
M  V30 63 N 9.91758 -0.294447 0.0 0
M  V30 64 C 7.63787 -0.247516 0.0 0
M  V30 64 C 11.4629 -2.69752 0.0 0
M  V30 65 C 8.45931 -0.54622 0.0 0
M  V30 65 C 12.2843 -2.99622 0.0 0
M  V30 66 C 7.30183 -2.97319 0.0 0
M  V30 66 C 11.1268 -5.42319 0.0 0
M  V30 END ATOM
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 BEGIN BOND
M  V30 1 1 1 3
M  V30 1 8 1 3
M  V30 2 1 3 2
M  V30 2 8 3 2
M  V30 3 1 4 1
M  V30 3 8 4 1
M  V30 4 1 4 2
M  V30 4 8 4 2
M  V30 5 2 5 6
M  V30 5 2 5 6
M  V30 6 1 6 7
M  V30 6 1 6 7
Line 125: Line 125:
M  V30 33 1 30 31
M  V30 33 1 30 31
M  V30 34 1 31 23
M  V30 34 1 31 23
M  V30 35 1 11 1
M  V30 35 8 11 1
M  V30 36 1 32 1
M  V30 36 8 32 1
M  V30 37 1 29 1
M  V30 37 8 29 1
M  V30 38 1 20 1
M  V30 38 8 20 1
M  V30 39 1 30 34
M  V30 39 1 30 34
M  V30 40 1 34 32
M  V30 40 1 34 32
Line 165: Line 165:
M  V30 73 1 62 63
M  V30 73 1 62 63
M  V30 74 1 63 55
M  V30 74 1 63 55
M  V30 75 1 61 2
M  V30 75 8 61 2
M  V30 76 1 52 2
M  V30 76 8 52 2
M  V30 77 1 2 43
M  V30 77 8 2 43
M  V30 78 1 33 2
M  V30 78 8 33 2
M  V30 79 1 62 64
M  V30 79 1 62 64
M  V30 80 1 64 33
M  V30 80 1 64 33

Revision as of 15:17, 1 April 2026



Abstract

Summary

Text

Advances and special progress

Text

Additional remarks

Text

Content of the published article in detail

Catalyst

Investigation

Additives

In this study, the addition of X was tested and control experiments under argon atmosphere were conducted.

chemistry, catalysis, catalyst, additives, argon‐atmosphere, reaction‐conditions, experimental‐study, research‐article

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