Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst/Photocatalytic reduction of CO: Difference between revisions

Revision as of 11:02, 26 February 2024

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1			DMF						CO					Visible light (>435)	47				10			21									0%; 32.3%; 67.7%; 0%; 0%			No
Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1			DMF				TFE		CO					Visible light (>435)	47				10			21									0%; 32.3%; 67.7%; 0%; 0%			No

@@ Line 1: / Line 1: @@
 {{Photocatalytic CO2 conversion experiments
 |experiments={{Photocatalytic CO2 conversion
+|catalyst=Molecule:100826
 |cat conc=0.01
 |PS=Molecule:100493
@@ Line 7: / Line 8: @@
 |e-D conc=0.1
 |solvent A=Molecule:100529
+|feedstock gas=CO
+|λexc=Visible light (>435)
+|irr time=47
+|TON CH4=10
+|TON H2=21
+|include=No
+}}{{Photocatalytic CO2 conversion
+|catalyst=Molecule:100826
+|cat conc=0.01
+|PS=Molecule:100493
+|PS conc=1
+|e-D=Molecule:100505
+|e-D conc=0.1
+|solvent A=Molecule:100529
+|additives=TFE
 |feedstock gas=CO
 |λexc=Visible light (>435)