Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH: Difference between revisions

Revision as of 15:55, 10 January 2024

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	λexc [nm]	TON CO	TON HCOOH
1.	Mn(phdk)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		480	8	52
2.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		480	15	58
3.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		480	9	48
4.	Mn(bpy)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		480	47	15
5.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		500	7	40
6.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		457	7	34
7.	Mn(phdk)(CO)3(MeCN)	2	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		480	5	18
8.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	200	BNAH	0.1	MeCN		480	8	52
9.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		480
10.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		500
11.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100			MeCN		480	3
12.	Mn(phdk)(CO)3(MeCN)				BNAH	0.1	MeCN		500
13.	Mn(phdk)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	Argon gas	480
14.			Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		480
15.			Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		480
16.	Mn(phdk)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	DMF		480	21	22
17.	Mn(phdk)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	DMF		480	2
18.	Mn(phdk)(CO)3Br		Ru(bpy)3Cl2	100			DMF		480	9	13
19.	Mn(phen)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	DMF		480	17	4
20.	Mn(bpy)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	DMF		480	6	39
21.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100			H2O	ascorbic acid/NaA	480
22.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100			H2O	ascorbic acid/NaA	500

Investigation-Name: Table 1

DOI	10.1016/j.electacta.2017.04.080
Authors	Matthew Stanbury, Jean-Daniel Compain, Monica Trejo, Parker Smith, Eric Gouré, Sylvie Chardon-Noblat,
Submitted	18.04.2017
Licenses	https://www.elsevier.com/tdm/userlicense/1.0/,
Subjects	Electrochemistry, General Chemical Engineering
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@@ Line 4: / Line 4: @@
 ==== Catalyst====
-<chemform smiles="C1C=CN2[Mn+]([Br-])(C#O)(C#O)(C#O)N3=CC=CC4C(=O)C(=O)C=1C=2C=43" inchi="1S/C12H6N2O2.3CHO.BrH.Mn/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;3*1-2;;/h1-6H;3*1H;1H;/q;;;;;+1/p-1" inchikey="ZMUYZQUZOJZTSM-UHFFFAOYSA-M" height="200px" width="300px" float="none">
+<chemform smiles="C1C=CN2[Mn+]([Br-])([C-]#[O+])([C-]#[O+])([C-]#[O+])N3=CC=CC4C(=O)C(=O)C=1C=2C=43" inchikey="KOYXLRUHHLMCRS-UHFFFAOYSA-M" inchi="1S/C12H6N2O2.3CO.BrH.Mn/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;3*1-2;;/h1-6H;;;;1H;/q;;;;;+1/p-1" float="none" width="200" height="200">
-   -INDIGO-02132316042D
+   -INDIGO-01102415542D
   0  0  0  0  0  0  0  0  0  0 V3000
@@ Line 28: / Line 28: @@
 M  V30 16 O 9.39805 -1.2925 0.0 0
 M  V30 17 Mn 8.375 -5.525 0.0 0 CHG=1
-M  V30 18 C 7.50897 -6.025 0.0 0
+M  V30 18 C 7.50897 -6.025 0.0 0 CHG=-1
-M  V30 19 C 9.24102 -6.025 0.0 0
+M  V30 19 C 9.24102 -6.025 0.0 0 CHG=-1
-M  V30 20 C 8.375 -6.525 0.0 0
+M  V30 20 C 8.375 -6.525 0.0 0 CHG=-1
 M  V30 21 Br 8.375 -4.525 0.0 0 CHG=-1
-M  V30 22 O 6.64295 -6.525 0.0 0
+M  V30 22 O 6.64295 -6.525 0.0 0 CHG=1
-M  V30 23 O 8.375 -7.525 0.0 0
+M  V30 23 O 8.375 -7.525 0.0 0 CHG=1
-M  V30 24 O 10.1071 -6.525 0.0 0
+M  V30 24 O 10.1071 -6.525 0.0 0 CHG=1
 M  V30 END ATOM
 M  V30 BEGIN BOND