Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH: Difference between revisions
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==== Catalyst==== | ==== Catalyst==== | ||
<chemform smiles="C1C=CN2[Mn+]([Br-])(C#O)(C#O)(C#O)N3=CC=CC4C(=O)C(=O)C=1C=2C=43" inchi="1S/C12H6N2O2. | <chemform smiles="C1C=CN2[Mn+]([Br-])([C-]#[O+])([C-]#[O+])([C-]#[O+])N3=CC=CC4C(=O)C(=O)C=1C=2C=43" inchikey="KOYXLRUHHLMCRS-UHFFFAOYSA-M" inchi="1S/C12H6N2O2.3CO.BrH.Mn/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;3*1-2;;/h1-6H;;;;1H;/q;;;;;+1/p-1" float="none" width="200" height="200"> | ||
-INDIGO- | -INDIGO-01102415542D | ||
0 0 0 0 0 0 0 0 0 0 0 V3000 | 0 0 0 0 0 0 0 0 0 0 0 V3000 | ||
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M V30 16 O 9.39805 -1.2925 0.0 0 | M V30 16 O 9.39805 -1.2925 0.0 0 | ||
M V30 17 Mn 8.375 -5.525 0.0 0 CHG=1 | M V30 17 Mn 8.375 -5.525 0.0 0 CHG=1 | ||
M V30 18 C 7.50897 -6.025 0.0 0 | M V30 18 C 7.50897 -6.025 0.0 0 CHG=-1 | ||
M V30 19 C 9.24102 -6.025 0.0 0 | M V30 19 C 9.24102 -6.025 0.0 0 CHG=-1 | ||
M V30 20 C 8.375 -6.525 0.0 0 | M V30 20 C 8.375 -6.525 0.0 0 CHG=-1 | ||
M V30 21 Br 8.375 -4.525 0.0 0 CHG=-1 | M V30 21 Br 8.375 -4.525 0.0 0 CHG=-1 | ||
M V30 22 O 6.64295 -6.525 0.0 0 | M V30 22 O 6.64295 -6.525 0.0 0 CHG=1 | ||
M V30 23 O 8.375 -7.525 0.0 0 | M V30 23 O 8.375 -7.525 0.0 0 CHG=1 | ||
M V30 24 O 10.1071 -6.525 0.0 0 | M V30 24 O 10.1071 -6.525 0.0 0 CHG=1 | ||
M V30 END ATOM | M V30 END ATOM | ||
M V30 BEGIN BOND | M V30 BEGIN BOND | ||
Revision as of 15:55, 10 January 2024
Catalyst
Mn(phdk)(CO)3Br
Mn(phdk)(CO)3(MeCN)
Mn(phen)(CO)3Br
Mn(bpy)(CO)3Br
Photosensitizer
Investigation
Investigation-Name: Table 1
Sacrificial electron donor
Investigations
- Photocatalytic CO2 reduction with the Mn complexes under various conditions. (Molecular process, Photocatalytic CO2 conversion experiments)
