Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction: Difference between revisions
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====Investigation==== | ====Investigation==== | ||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | {{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | ||
====Sacrificial Electron Donor ==== | |||
==== Sacrificial | In this study, the experiments were done with the sacrificial electron donors TEOA ({{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=false|width=300|height=200}}) and BIH ({{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=false|width=300|height=200}}). | ||
{{#moleculelink:|link= | ====Additives==== | ||
In this study, different additives were used. | |||
[[Category:Photocatalytic CO2 conversion to HCOOH]] | [[Category:Photocatalytic CO2 conversion to HCOOH]] | ||
Revision as of 10:55, 23 January 2024
Catalyst
[K]2[MoO(Hqpdt)2]
[MoO(2Hqpdt)2][NBu4]
[MoO(qpdt)2][NBu4]2
Photosensitizer
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | λexc [nm] | . | TON CO | TON H2 | TON HCOOH | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 50 | 0.5 | 0.1 | 400 | 73 | 670 | 80 | |||||||||
| 2. | 50 | 0.5 | 0.1 | 400 | 13 | 51 | 31 | |||||||||
| 3. | 50 | 0.5 | 0.1 | 400 | 40 | 89 | 83 |
Investigation-Name: Table 1
Sacrificial Electron Donor
In this study, the experiments were done with the sacrificial electron donors TEOA (TEOA) and BIH (BIH).
Additives
In this study, different additives were used.
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
