Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst: Difference between revisions

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DOI 10.1021/jacs.8b09740
Authors Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert,
Submitted 07.12.2018
Published online 07.12.2018
Licenses -
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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===Sacrificial Electron Donor ===
===Sacrificial Electron Donor ===
<chemform smiles="N(C(C)C)(C(C)C)CC" inchi="1S/C8H19N/c1-6-9(7(2)3)8(4)5/h7-8H,6H2,1-5H3" inchikey="JGFZNNIVVJXRND-UHFFFAOYSA-N" height="100px" width="150px" float="none">
In this study, the experiments were done with the sacrificial electron donors DIPEA ({{#moleculelink:|link=JGFZNNIVVJXRND-UHFFFAOYSA-N|image=false|width=300|height=200}}), TEOA ({{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=false|width=300|height=200}}), BIH ({{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=false|width=300|height=200}}), and TEA ({{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=false|width=300|height=200}}).
  -INDIGO-12132211432D


  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 9 8 0 0 0
M  V30 BEGIN ATOM
M  V30 1 N 10.1998 -5.92554 0.0 0
M  V30 2 C 10.4587 -6.89118 0.0 0
M  V30 3 C 9.75188 -7.59828 0.0 0
M  V30 4 C 9.23403 -5.66667 0.0 0
M  V30 5 C 8.97539 -4.70042 0.0 0
M  V30 6 C 8.5271 -6.37351 0.0 0
M  V30 7 C 10.9071 -5.21832 0.0 0
M  V30 8 C 11.8733 -5.47693 0.0 0
M  V30 9 C 10.6485 -4.25212 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 1 1 2
M  V30 2 1 2 3
M  V30 3 1 1 4
M  V30 4 1 4 5
M  V30 5 1 4 6
M  V30 6 1 1 7
M  V30 7 1 7 8
M  V30 8 1 7 9
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>
{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}}
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}}
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}
===Additives===
===Additives===
In this study, different additives were used. As depicted in the investigation table, water ({{#moleculelink:|link=XLYOFNOQVPJJNP-UHFFFAOYSA-N|image=false|width=300|height=200}},) phenol ({{#moleculelink:|link=ISWSIDIOOBJBQZ-UHFFFAOYSA-N|image=false|width=300|height=200}}), and trifluoroethanol ({{#moleculelink:|link=RHQDFWAXVIIEBN-UHFFFAOYSA-N|image=false|width=300|height=200}}) were used.  
In this study, different additives were used. As depicted in the investigation table, water ({{#moleculelink:|link=XLYOFNOQVPJJNP-UHFFFAOYSA-N|image=false|width=300|height=200}},) phenol ({{#moleculelink:|link=ISWSIDIOOBJBQZ-UHFFFAOYSA-N|image=false|width=300|height=200}}), and trifluoroethanol ({{#moleculelink:|link=RHQDFWAXVIIEBN-UHFFFAOYSA-N|image=false|width=300|height=200}}) were used.  
[[Category:Photocatalytic CO2 conversion to CH4]]
[[Category:Photocatalytic CO2 conversion to CH4]]

Revision as of 07:01, 29 December 2023


Catalysts

Fe(pTMAPP)Cl5

Photosensitizers

5,10-Di(2-naphthyl)-5,10-dihydrophenazine 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine

Investigations

  1. REDIRECT Photocatalytic reduction of CO2
Investigation-Name: Table 1

Sacrificial Electron Donor

In this study, the experiments were done with the sacrificial electron donors DIPEA (DIPEA), TEOA (TEOA), BIH (BIH), and TEA (TEA).

Additives

In this study, different additives were used. As depicted in the investigation table, water (H2O,) phenol (PhOH), and trifluoroethanol (TFE) were used.

Investigations

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