Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst: Difference between revisions

From ChemWiki
publication
About
DOI 10.1021/jacs.8b09740
Authors Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert,
Submitted 07.12.2018
Published online 07.12.2018
Licenses -
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
Go to literature page
No edit summary
Line 407: Line 407:
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}
===Additives===
===Additives===
<chemform smiles="O([H])[H]" inchi="1S/H2O/h1H2" inchikey="XLYOFNOQVPJJNP-UHFFFAOYSA-N" height="50px" width="75px" float="none">
In this study, different additives were used. As depicted in the investigation table, water ({{#moleculelink:|link=XLYOFNOQVPJJNP-UHFFFAOYSA-N|image=false|width=300|height=200}},) phenol ({{#moleculelink:|link=ISWSIDIOOBJBQZ-UHFFFAOYSA-N|image=false|width=300|height=200}}), and trifluoroethanol ({{#moleculelink:|link=RHQDFWAXVIIEBN-UHFFFAOYSA-N|image=false|width=300|height=200}}) were used.  
  -INDIGO-12132211442D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 3 2 0 0 0
M  V30 BEGIN ATOM
M  V30 1 O 9.58594 -4.36472 0.0 0
M  V30 2 H 8.66144 -4.74728 0.0 0
M  V30 3 H 10.3792 -4.97276 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 1 1 2
M  V30 2 1 1 3
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform><chemform smiles="C1C=CC=CC=1O" inchi="1S/C6H6O/c7-6-4-2-1-3-5-6/h1-5,7H" inchikey="ISWSIDIOOBJBQZ-UHFFFAOYSA-N" height="100px" width="150px" float="none">
  -INDIGO-12132211452D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 7 7 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 8.20985 -3.70007 0.0 0
M  V30 2 C 9.94015 -3.69959 0.0 0
M  V30 3 C 9.07664 -3.19997 0.0 0
M  V30 4 C 9.94015 -4.70053 0.0 0
M  V30 5 C 8.20985 -4.70502 0.0 0
M  V30 6 C 9.07882 -5.20003 0.0 0
M  V30 7 O 9.07725 -2.19997 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 1 3 7
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform><chemform smiles="C(C(F)(F)F)O" inchi="1S/C2H3F3O/c3-2(4,5)1-6/h6H,1H2" inchikey="RHQDFWAXVIIEBN-UHFFFAOYSA-N" height="50px" width="75px" float="none">
  -INDIGO-12132211472D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 6 5 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 6.82192 -5.03421 0.0 0
M  V30 2 O 7.81584 -5.20252 0.0 0
M  V30 3 C 6.18635 -5.79969 0.0 0
M  V30 4 F 5.41792 -5.15324 0.0 0
M  V30 5 F 5.55273 -6.56115 0.0 0
M  V30 6 F 6.96078 -6.43583 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 1 1 2
M  V30 2 1 1 3
M  V30 3 1 3 4
M  V30 4 1 3 5
M  V30 5 1 3 6
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>
[[Category:Photocatalytic CO2 conversion to CH4]]
[[Category:Photocatalytic CO2 conversion to CH4]]

Revision as of 06:52, 29 December 2023


Catalysts

Fe(pTMAPP)Cl5

Photosensitizers

5,10-Di(2-naphthyl)-5,10-dihydrophenazine 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine

Investigations

  1. REDIRECT Photocatalytic reduction of CO2
Investigation-Name: Table 1

Sacrificial Electron Donor

DIPEA TEA TEOA BIH

Additives

In this study, different additives were used. As depicted in the investigation table, water (H2O,) phenol (PhOH), and trifluoroethanol (TFE) were used.

Investigations

Retrieved from "https://chemwiki.scc.kit.edu/main/mediawiki/index.php?title=Visible-Light-Driven_Conversion_of_CO2_to_CH4_with_an_Organic_Sensitizer_and_an_Iron_Porphyrin_Catalyst&oldid=4672"
Powered by MediaWiki
Powered by Semantic MediaWiki