Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate: Difference between revisions

Revision as of 14:12, 28 November 2023

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	.	.	.	.	TON HCOOH	.	.	.
1.	Ni(pbi)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O					14000
2.	Ni(pbt)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O					13100

Investigation-Name: Table 1

DOI	10.1021/jacs.0c08145
Authors	Sung Eun Lee, Azam Nasirian, Ye Eun Kim, Pegah Tavakoli Fard, Youngmee Kim, Byeongmoon Jeong, Sung-Jin Kim, Jin-Ook Baeg, Jinheung Kim,
Submitted	19.10.2020
Published online	19.10.2020
Licenses	https://doi.org/10.15223/policy-029, https://doi.org/10.15223/policy-037, https://doi.org/10.15223/policy-045,
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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@@ Line 3: / Line 3: @@
 ==== Catalyst====
-<chemform smiles="C1C=CC=N2[Ni]3(~SC4=CC=CC=N43)(N3=C(NC4C=CC=CC=43)C=12)1~SC2N1=CC=CC=2" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" height="200px" width="300px" float="none">
+<chemform smiles="C1C=CC=N2[Ni+2]3([S-]C4=CC=CC=N43)(N3=C(NC4C=CC=CC=43)C=12)1[S-]C2N1=CC=CC=2" inchi="1S/C12H9N3.2C5H5NS.Ni/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11;2*7-5-3-1-2-4-6-5;/h1-8H,(H,14,15);2*1-4H,(H,6,7);/q;;;+2/p-2" inchikey="CLQAFMRCKIGWOF-UHFFFAOYSA-L" height="200px" width="300px" float="none">
-   -INDIGO-01252311222D
+   -INDIGO-11282314122D
   0  0  0  0  0  0  0  0  0  0 V3000
@@ Line 37: / Line 37: @@
 M  V30 26 C 8.16095 -7.60143 0.0 0
 M  V30 27 C 8.9122 -8.40358 0.0 0
-M  V30 28 S 7.004 -4.94982 0.0 0
+M  V30 28 S 7.004 -4.94982 0.0 0 CHG=-1
-M  V30 29 S 7.15093 -7.50667 0.0 0
+M  V30 29 S 7.15093 -7.50667 0.0 0 CHG=-1
-M  V30 30 Ni 7.08398 -6.24492 0.0 0
+M  V30 30 Ni 7.08398 -6.24492 0.0 0 CHG=2
 M  V30 END ATOM
 M  V30 BEGIN BOND
@@ Line 74: / Line 74: @@
 M  V30 31 1 26 29
 M  V30 32 10 20 30
-M  V30 33 8 28 30
+M  V30 33 10 28 30
 M  V30 34 10 11 30
 M  V30 35 10 2 30
 M  V30 36 10 22 30
-M  V30 37 8 29 30
+M  V30 37 10 29 30
 M  V30 END BOND
 M  V30 END CTAB