Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst: Difference between revisions

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DOI 10.1021/jacs.8b09740
Authors Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert,
Submitted 07.12.2018
Published online 07.12.2018
Licenses -
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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===Catalysts===
===Catalysts===
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<chemform smiles="C1C=C2C(C3C=CC([N+](C)(C)C)=CC=3)=C3C=CC4C(C5C=CC([N+](C)(C)C)=CC=5)=C5N6~[Fe](~Cl)7(~N2C=1C(C1C=CC([N+](C)(C)C)=CC=1)=C1N7=C(C(C2C=CC([N+](C)(C)C)=CC=2)=C6C=C5)C=C1)N3=4.[Cl-].[Cl-].[Cl-].[Cl-]" inchi="1S/C56H60N8.5ClH.Fe/c1-61(2,3)41-21-13-37(14-22-41)53-45-29-31-47(57-45)54(38-15-23-42(24-16-38)62(4,5)6)49-33-35-51(59-49)56(40-19-27-44(28-20-40)64(10,11)12)52-36-34-50(60-52)55(48-32-30-46(53)58-48)39-17-25-43(26-18-39)63(7,8)9;;;;;;/h13-36H,1-12H3;5*1H;/q+2;;;;;;+3/p-5/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-;;;;;;" inchikey="NRVILUOLTIKJEU-NGWNFTKISA-I" height="200px" width="300px" float="none">
  -INDIGO-12132211272D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
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M  V30 COUNTS 65 76 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 6.04424 -2.5609 0.0 0
M  V30 2 C 7.33133 -1.66667 0.0 0
M  V30 3 C 6.36602 -1.6242 0.0 0
M  V30 4 C 7.56769 -2.60624 0.0 0
M  V30 5 N 6.78397 -3.14046 0.0 0
M  V30 6 C 4.63287 -3.92379 0.0 0
M  V30 7 C 4.532 -5.51407 0.0 0
M  V30 8 N 5.16816 -4.74793 0.0 0
M  V30 9 C 3.63825 -5.15661 0.0 0
M  V30 10 C 3.69714 -4.16923 0.0 0
M  V30 11 C 8.75201 -4.00987 0.0 0
M  V30 12 C 9.58697 -5.32603 0.0 0
M  V30 13 C 9.63842 -4.3551 0.0 0
M  V30 14 C 8.65581 -5.58713 0.0 0
M  V30 15 N 8.10856 -4.76374 0.0 0
M  V30 16 C 7.01046 -7.93253 0.0 0
M  V30 17 C 5.78378 -6.99601 0.0 0
M  V30 18 C 6.03403 -7.92348 0.0 0
M  V30 19 N 6.54571 -6.43131 0.0 0
M  V30 20 C 7.28367 -7.01054 0.0 0
M  V30 21 C 5.0119 -2.87292 0.0 0
M  V30 22 C 8.51405 -2.9837 0.0 0
M  V30 23 C 8.29876 -6.63698 0.0 0
M  V30 24 C 4.79605 -6.58792 0.0 0
M  V30 25 C 4.32364 -2.14745 0.0 0
M  V30 26 C 9.27269 -2.33219 0.0 0
M  V30 27 C 9.01458 -7.33526 0.0 0
M  V30 28 C 4.03772 -7.2398 0.0 0
M  V30 29 C 3.59147 -8.91156 0.0 0
M  V30 30 C 4.29709 -8.20631 0.0 0
M  V30 31 C 2.62446 -8.65315 0.0 0
M  V30 32 C 3.06684 -6.98035 0.0 0
M  V30 33 C 2.36426 -7.69206 0.0 0
M  V30 34 C 10.6863 -7.78151 0.0 0
M  V30 35 C 9.9811 -7.07589 0.0 0
M  V30 36 C 10.4279 -8.74852 0.0 0
M  V30 37 C 8.75513 -8.30614 0.0 0
M  V30 38 C 9.46685 -9.00872 0.0 0
M  V30 39 C 9.71894 -0.660424 0.0 0
M  V30 40 C 9.01332 -1.36567 0.0 0
M  V30 41 C 10.6859 -0.918838 0.0 0
M  V30 42 C 10.2436 -2.59164 0.0 0
M  V30 43 C 10.9461 -1.87993 0.0 0
M  V30 44 C 2.65188 -1.7012 0.0 0
M  V30 45 C 3.35713 -2.40682 0.0 0
M  V30 46 C 2.91029 -0.734192 0.0 0
M  V30 47 C 4.58309 -1.17657 0.0 0
M  V30 48 C 3.87138 -0.473995 0.0 0
M  V30 49 N 2.20203 -0.0282408 0.0 0 CHG=1
M  V30 50 N 11.3919 -0.210578 0.0 0 CHG=1
M  V30 51 N 11.1362 -9.45447 0.0 0 CHG=1
M  V30 52 N 1.91851 -9.36141 0.0 0 CHG=1
M  V30 53 C 1.83427 0.838106 0.0 0
M  V30 54 C 1.23653 -0.288636 0.0 0
M  V30 55 C 2.94253 0.832155 0.0 0
M  V30 56 C 12.3582 -0.46782 0.0 0
M  V30 57 C 11.9565 0.604924 0.0 0
M  V30 58 C 10.8756 0.496664 0.0 0
M  V30 59 C 10.879 -10.4208 0.0 0
M  V30 60 C 12.1017 -9.19408 0.0 0
M  V30 61 C 11.8445 -10.1604 0.0 0
M  V30 62 C 1.00216 -10.0292 0.0 0
M  V30 63 C 2.17891 -10.3269 0.0 0
M  V30 64 C 1.05811 -8.89591 0.0 0
M  V30 65 Fe 6.65 -4.7 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 1 5
M  V30 2 2 2 3
M  V30 3 1 3 1
M  V30 4 1 4 2
M  V30 5 1 5 4
M  V30 6 1 6 10
M  V30 7 1 7 8
M  V30 8 1 8 6
M  V30 9 1 9 7
M  V30 10 2 10 9
M  V30 11 1 11 15
M  V30 12 1 12 13
M  V30 13 2 13 11
M  V30 14 2 14 12
M  V30 15 1 15 14
M  V30 16 1 16 20
M  V30 17 1 17 18
M  V30 18 2 18 16
M  V30 19 2 19 17
M  V30 20 1 20 19
M  V30 21 1 1 21
M  V30 22 2 21 6
M  V30 23 2 4 22
M  V30 24 1 22 11
M  V30 25 1 14 23
M  V30 26 2 23 20
M  V30 27 1 17 24
M  V30 28 2 24 7
M  V30 29 1 21 25
M  V30 30 1 22 26
M  V30 31 1 23 27
M  V30 32 1 24 28
M  V30 33 2 30 28
M  V30 34 2 31 29
M  V30 35 1 28 32
M  V30 36 1 29 30
M  V30 37 2 32 33
M  V30 38 1 33 31
M  V30 39 2 35 27
M  V30 40 2 36 34
M  V30 41 1 27 37
M  V30 42 1 34 35
M  V30 43 2 37 38
M  V30 44 1 38 36
M  V30 45 2 40 26
M  V30 46 2 41 39
M  V30 47 1 26 42
M  V30 48 1 39 40
M  V30 49 2 42 43
M  V30 50 1 43 41
M  V30 51 2 45 25
M  V30 52 2 46 44
M  V30 53 1 25 47
M  V30 54 1 44 45
M  V30 55 2 47 48
M  V30 56 1 48 46
M  V30 57 1 46 49
M  V30 58 1 41 50
M  V30 59 1 36 51
M  V30 60 1 31 52
M  V30 61 1 49 53
M  V30 62 1 49 54
M  V30 63 1 49 55
M  V30 64 1 50 56
M  V30 65 1 50 57
M  V30 66 1 50 58
M  V30 67 1 51 59
M  V30 68 1 51 60
M  V30 69 1 51 61
M  V30 70 1 52 62
M  V30 71 1 52 63
M  V30 72 1 52 64
M  V30 73 8 5 65
M  V30 74 8 8 65
M  V30 75 8 15 65
M  V30 76 8 19 65
M  V30 END BOND
M  V30 END CTAB
M  END
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   -INDIGO-01262316122D
   -INDIGO-01262316122D


Revision as of 17:39, 27 November 2023


Catalysts

Photosensitizers

5,10-Di(2-naphthyl)-5,10-dihydrophenazine 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine

Investigations

  1. REDIRECT Photocatalytic reduction of CO2
Investigation-Name: Table 1

Sacrificial Electron Donor

DIPEA TEA TEOA BIH

Additives

H2O PhOH TFE

Investigations

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