Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction: Difference between revisions

Revision as of 16:35, 10 January 2024

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Catalyst

[Re(bpy)(CO)3(MeCN)][PF6] Ru(dtBubpy)(CO)2Cl2

Photosensitizer

Investigation

	cat	cat conc [µM]	PS	PS conc [mM]	solvent A	λexc [nm]	TON CO
1.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100878	0.05	DMF	436	27
2.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100878	0.05	DMF	436	98
3.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05	DMF	436	22
4.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05	DMF	436	71
5.			Molecule:100877	0.05	DMF	436	6
6.			Molecule:100877	0.05	DMF	436	8
7.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100879	0.05	DMF	436	20
8.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100879	0.05	DMF	436	32
9.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100880	0.05	DMF	436	11
10.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100880	0.05	DMF	436	48

Investigation-Name: Table 1

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05			DMF	436	20	72	290
2.	Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05	BI(OH)H	0.03	DMF	436	16	49	280
3.	[Mn(dtBubpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05			DMF	436	32		85
4.	[Mn(dtBubpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05	BI(OH)H	0.03	DMF	436	80		60

Investigation-Name: Table 2

Sacrificial electron donor

TEOA

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
Table 2 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1039/c6sc01913g
Authors	Jana Rohacova, Osamu Ishitani,
Submitted	05.07.2016
Published online	2016
Licenses	-
Subjects	-
Go to literature page

@@ Line 74: / Line 74: @@
 M  V30 END CTAB
 M  END
-</chemform><chemform smiles="C(C(C)(C)C)1C=C2C3C=C(C(C)(C)C)C=CN=3[Ru](~Cl)(~Cl)(C#O)(C#O)N2=CC=1" inchi="1S/C18H24N2.2CHO.2ClH.Ru/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2;;;/h7-12H,1-6H3;2*1H;2*1H;/q;;;;;+2/p-2" inchikey="RUJTWEUENVZQPO-UHFFFAOYSA-L" height="200px" width="300px" float="none">
+</chemform><chemform smiles="C(C(C)(C)C)1C=C2C3C=C(C(C)(C)C)C=CN=3[Ru+2]([Cl-])([Cl-])([C-]#[O+])([C-]#[O+])N2=CC=1" inchikey="XUQJAKJUMNDNTK-UHFFFAOYSA-L" inchi="1S/C18H24N2.2CO.2ClH.Ru/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2;;;/h7-12H,1-6H3;;;2*1H;/q;;;;;+2/p-2" float="none" width="200" height="200">
-   -INDIGO-05042311392D
+   -INDIGO-01102416342D
   0  0  0  0  0  0  0  0  0  0 V3000
@@ Line 93: / Line 93: @@
 M  V30 11 C 5.43385 -5.27809 0.0 0
 M  V30 12 C 5.44031 -6.27814 0.0 0
-M  V30 13 Ru 8.325 -4.25 0.0 0
+M  V30 13 Ru 8.325 -4.25 0.0 0 CHG=2
 M  V30 14 C 4.57429 -6.77814 0.0 0
-M  V30 15 C 3.60836 -6.51932 0.0 0
+M  V30 15 C 3.70826 -7.27814 0.0 0
-M  V30 16 C 3.70826 -7.27814 0.0 0
+M  V30 16 C 9.28211 -3.26789 0.0 0 CHG=-1
-M  V30 17 C 4.31547 -7.74407 0.0 0
+M  V30 17 C 9.28211 -5.20711 0.0 0 CHG=-1
-M  V30 18 C 9.03211 -3.54289 0.0 0
+M  V30 18 O 9.98921 -5.91421 0.0 0 CHG=1
-M  V30 19 C 9.03211 -4.95711 0.0 0
+M  V30 19 O 9.98921 -2.56079 0.0 0 CHG=1
-M  V30 20 O 9.73921 -5.66421 0.0 0
+M  V30 20 Cl 8.325 -5.575 0.0 0 CHG=-1
-M  V30 21 O 9.73921 -2.83579 0.0 0
+M  V30 21 Cl 8.325 -2.95 0.0 0 CHG=-1
-M  V30 22 Cl 8.325 -5.25 0.0 0
+M  V30 22 C 4.56882 -1.77507 0.0 0
-M  V30 23 Cl 8.325 -3.25 0.0 0
+M  V30 23 C 3.7028 -1.27507 0.0 0
-M  V30 24 C 4.56882 -1.77507 0.0 0
+M  V30 24 C 4.06882 -2.6411 0.0 0
-M  V30 25 C 3.6029 -2.03389 0.0 0
+M  V30 25 C 5.06882 -0.909045 0.0 0
-M  V30 26 C 3.7028 -1.27507 0.0 0
+M  V30 26 C 5.07429 -7.64417 0.0 0
-M  V30 27 C 4.31 -0.809149 0.0 0
+M  V30 27 C 4.07429 -5.91211 0.0 0
 M  V30 END ATOM
 M  V30 BEGIN BOND
@@ Line 127: / Line 127: @@
 M  V30 16 1 12 14
 M  V30 17 1 14 15
-M  V30 18 1 14 16
+M  V30 18 10 13 16
-M  V30 19 1 14 17
+M  V30 19 10 13 17
-M  V30 20 10 13 18
+M  V30 20 3 17 18
-M  V30 21 10 13 19
+M  V30 21 3 16 19
-M  V30 22 3 19 20
+M  V30 22 10 13 20
-M  V30 23 3 18 21
+M  V30 23 10 13 21
-M  V30 24 8 13 22
+M  V30 24 1 1 22
-M  V30 25 8 13 23
+M  V30 25 1 22 23
-M  V30 26 1 1 24
+M  V30 26 1 22 24
-M  V30 27 1 24 25
+M  V30 27 1 22 25
-M  V30 28 1 24 26
+M  V30 28 1 14 26
-M  V30 29 1 24 27
+M  V30 29 1 14 27
 M  V30 END BOND
 M  V30 END CTAB

Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction: Difference between revisions

Revision as of 16:35, 10 January 2024

Contents

Catalyst

Photosensitizer

Investigation

Sacrificial electron donor

Investigations

Topics

Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction: Difference between revisions

Revision as of 16:35, 10 January 2024

Catalyst

Photosensitizer

Investigation

Sacrificial electron donor

Investigations

Current site

Topics