Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction: Difference between revisions

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publication
About
DOI 10.1039/c6sc01913g
Authors Jana Rohacova, Osamu Ishitani,
Submitted 05.07.2016
Published online 2016
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Subjects -
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(faulty molecule)
(changed faulty molecule (wrong CO))
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==== Catalyst====
==== Catalyst====
<chemform smiles="C1C=C2C3C=CC=CN=3[Re+](C#O)(N#CC)(C#O)(C#O)N2=CC=1.[*]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="PF6-">
<chemform smiles="C1C=C2C3C=CC=CN=3[Re+]([C-]#[O+])([C-]#[O+])([C-]#[O+])(N#CC)N2=CC=1.[P-](F)(F)(F)(F)(F)F" inchi="1S/C10H8N2.C2H3N.3CO.F6P.Re/c1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-2-3;3*1-2;1-7(2,3,4,5)6;/h1-8H;1H3;;;;;/q;;;;;-1;+1" inchikey="NZCMNMSVXYOMGS-UHFFFAOYSA-N" height="200px" width="300px" float="none">
   -INDIGO-05042311362D
   -INDIGO-07282314582D


   0  0  0  0  0  0  0  0  0  0  0 V3000
   0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 BEGIN CTAB
M  V30 COUNTS 23 24 0 0 0
M  V30 COUNTS 29 30 0 0 0
M  V30 BEGIN ATOM
M  V30 BEGIN ATOM
M  V30 1 C 4.80985 -3.10007 0.0 0
M  V30 1 C 4.65985 -3.35007 0.0 0
M  V30 2 C 6.54015 -3.09959 0.0 0
M  V30 2 C 6.39015 -3.34959 0.0 0
M  V30 3 C 5.67664 -2.59997 0.0 0
M  V30 3 C 5.52664 -2.84997 0.0 0
M  V30 4 N 6.54015 -4.10053 0.0 0
M  V30 4 N 6.39015 -4.35053 0.0 0
M  V30 5 C 4.80985 -4.10502 0.0 0
M  V30 5 C 4.65985 -4.35502 0.0 0
M  V30 6 C 5.67882 -4.60003 0.0 0
M  V30 6 C 5.52882 -4.85003 0.0 0
M  V30 7 C 5.67882 -5.60003 0.0 0
M  V30 7 C 5.53268 -5.85003 0.0 0
M  V30 8 C 6.5454 -7.09769 0.0 0
M  V30 8 C 6.40503 -7.34433 0.0 0
M  V30 9 N 6.54566 -6.10006 0.0 0
M  V30 9 N 6.40144 -6.3467 0.0 0
M  V30 10 C 5.67889 -7.59875 0.0 0
M  V30 10 C 5.54046 -7.84872 0.0 0
M  V30 11 C 4.80885 -6.10309 0.0 0
M  V30 11 C 4.66465 -6.35643 0.0 0
M  V30 12 C 4.81531 -7.10314 0.0 0
M  V30 12 C 4.67497 -7.35646 0.0 0
M  V30 13 Re 7.4 -5.125 0.0 0 CHG=1
M  V30 13 Re 7.38118 -5.25053 0.0 0 CHG=1
M  V30 14 C 7.4 -6.125 0.0 0
M  V30 14 N 7.38118 -4.25053 0.0 0
M  V30 15 C 8.10711 -4.41789 0.0 0
M  V30 15 C 8.2472 -4.75053 0.0 0 CHG=-1
M  V30 16 N 7.4 -4.125 0.0 0
M  V30 16 C 8.2472 -5.75053 0.0 0 CHG=-1
M  V30 17 C 8.10711 -5.83211 0.0 0
M  V30 17 C 7.38118 -6.25053 0.0 0 CHG=-1
M  V30 18 O 7.4 -7.125 0.0 0
M  V30 18 O 9.11323 -4.25053 0.0 0 CHG=1
M  V30 19 O 8.81421 -6.53921 0.0 0
M  V30 19 O 9.11323 -6.25053 0.0 0 CHG=1
M  V30 20 O 8.81421 -3.71079 0.0 0
M  V30 20 O 7.38118 -7.25053 0.0 0 CHG=1
M  V30 21 C 7.4 -3.125 0.0 0
M  V30 21 C 7.38118 -3.25053 0.0 0
M  V30 22 C 7.4 -2.125 0.0 0
M  V30 22 C 7.38118 -2.25053 0.0 0
M  V30 23 R# 11.025 -1.7 0.0 0 RGROUPS=(1 1)
M  V30 23 P 11.717 -3.475 0.0 0 CHG=-1
M  V30 24 F 12.583 -2.975 0.0 0
M  V30 25 F 10.851 -2.975 0.0 0
M  V30 26 F 11.717 -4.475 0.0 0
M  V30 27 F 12.583 -3.975 0.0 0
M  V30 28 F 11.717 -2.475 0.0 0
M  V30 29 F 10.851 -3.975 0.0 0
M  V30 END ATOM
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 BEGIN BOND
Line 49: Line 55:
M  V30 13 1 12 10
M  V30 13 1 12 10
M  V30 14 10 4 13
M  V30 14 10 4 13
M  V30 15 10 9 13
M  V30 15 10 13 9
M  V30 16 10 13 14
M  V30 16 10 13 14
M  V30 17 10 13 15
M  V30 17 10 13 15
M  V30 18 10 13 16
M  V30 18 10 13 16
M  V30 19 10 13 17
M  V30 19 10 13 17
M  V30 20 3 14 18
M  V30 20 3 15 18
M  V30 21 3 17 19
M  V30 21 3 16 19
M  V30 22 3 15 20
M  V30 22 3 17 20
M  V30 23 3 16 21
M  V30 23 3 14 21
M  V30 24 1 21 22
M  V30 24 1 21 22
M  V30 25 1 23 24
M  V30 26 1 23 25
M  V30 27 1 23 26
M  V30 28 1 23 27
M  V30 29 1 23 28
M  V30 30 1 23 29
M  V30 END BOND
M  V30 END BOND
M  V30 END CTAB
M  V30 END CTAB

Revision as of 14:00, 28 July 2023


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Catalyst

[Re(bpy)(CO)3(MeCN)][PF6]

Photosensitizer

Investigation

Experiment 'Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction/' does not exist.

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A..λexc [nm].TON COTON H2TON HCOOH...
1.

Ru(dtBubpy)(CO)2Cl2

0.05

Molecule:100877

0.05


DMF

4362072290
2.

Ru(dtBubpy)(CO)2Cl2

0.05

Molecule:100877

0.05

BI(OH)H

0.03

DMF

4361649280
3.

[Mn(dtBubpy)(CO)3(MeCN)][PF6]

0.05

Molecule:100877

0.05


DMF

4363285
4.

[Mn(dtBubpy)(CO)3(MeCN)][PF6]

0.05

Molecule:100877

0.05

BI(OH)H

0.03

DMF

4368060
Investigation-Name: Table 2

Sacrificial electron donor

TEOA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
  • Table 2 (Molecular process, Photocatalytic CO2 conversion experiments)
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