Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis: Difference between revisions

From ChemWiki
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DOI 10.1021/acs.jpcc.8b00950
Authors Heng Rao, Julien Bonin, Marc Robert,
Submitted 28.04.2018
Published online 28.04.2018
Licenses -
Subjects Surfaces, Coatings and Films, Physical and Theoretical Chemistry, General Energy, Electronic, Optical and Magnetic Materials
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(Added CV investigation)
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====Photosensitizer====
====Photosensitizer====
<chemform smiles="C1C=C2C3C([Ir+]4(N5C(C6N4=CC=CC=6)=CC=CC=5)4(N5C(C6C4=CC=CC=6)=CC=CC=5)N2=CC=1)=CC=CC=3" inchi="1S/2C11H9N.C10H8N2.Ir/c2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h2*1-9H;1-8H;/q;;;+1" inchikey="WEEPMIZXGXTKSO-UHFFFAOYSA-N" height="200px" width="300px" float="none">
<chemform smiles="C1C=C[C-]2[Ir+3]3([C-]4C=CC=CC=4C4C=CC=CN=43)3(N4=CC=CC=C4C4C=CC=CN=43)N3=CC=CC=C3C=2C=1.[P-](F)(F)(F)(F)(F)F" inchi="" inchikey="" height="200px" width="300px" float="none"></chemform>{{#moleculelink:|link=UEEXRMUCXBPYOV-UHFFFAOYSA-N|image=true}}
  -INDIGO-01262315082D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 37 45 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 4.45797 -3.44045 0.0 0
M  V30 2 C 5.96133 -3.36319 0.0 0
M  V30 3 C 5.12223 -3.03828 0.0 0
M  V30 4 N 6.18456 -4.17527 0.0 0
M  V30 5 C 4.46811 -4.21322 0.0 0
M  V30 6 C 5.26148 -4.65508 0.0 0
M  V30 7 C 4.51917 -5.73215 0.0 0
M  V30 8 C 6.22384 -5.76587 0.0 0
M  V30 9 C 5.27077 -5.2974 0.0 0
M  V30 10 C 6.0193 -6.57651 0.0 0
M  V30 11 C 4.5162 -6.49701 0.0 0
M  V30 12 C 5.18205 -6.90334 0.0 0
M  V30 13 C 7.51732 -7.30385 0.0 0
M  V30 14 C 8.97092 -7.39426 0.0 0
M  V30 15 C 8.09356 -6.79102 0.0 0
M  V30 16 C 8.96182 -8.29372 0.0 0
M  V30 17 C 7.6068 -8.20544 0.0 0
M  V30 18 C 8.27229 -8.63762 0.0 0
M  V30 19 N 9.48753 -6.07146 0.0 0
M  V30 20 C 11.0499 -6.53021 0.0 0
M  V30 21 C 10.3685 -5.88703 0.0 0
M  V30 22 C 10.9588 -7.31958 0.0 0
M  V30 23 C 9.51277 -7.13327 0.0 0
M  V30 24 C 10.258 -7.63524 0.0 0
M  V30 25 C 7.60897 -1.47271 0.0 0
M  V30 26 C 9.01802 -1.50872 0.0 0
M  V30 27 C 8.3457 -1.08144 0.0 0
M  V30 28 C 8.89639 -2.52314 0.0 0
M  V30 29 C 7.45099 -2.43365 0.0 0
M  V30 30 N 8.05713 -3.03115 0.0 0
M  V30 31 C 9.48728 -2.84506 0.0 0
M  V30 32 C 10.8821 -2.79881 0.0 0
M  V30 33 C 10.2032 -2.4236 0.0 0
M  V30 34 C 10.9119 -3.6346 0.0 0
M  V30 35 N 9.37872 -3.98759 0.0 0
M  V30 36 C 10.1731 -4.23891 0.0 0
M  V30 37 Ir 7.92552 -4.9583 0.0 0 CHG=1
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 2 9 7
M  V30 8 2 10 8
M  V30 9 1 7 11
M  V30 10 1 8 9
M  V30 11 2 11 12
M  V30 12 1 12 10
M  V30 13 2 15 13
M  V30 14 2 16 14
M  V30 15 1 13 17
M  V30 16 1 14 15
M  V30 17 2 17 18
M  V30 18 1 18 16
M  V30 19 2 21 19
M  V30 20 2 22 20
M  V30 21 1 19 23
M  V30 22 1 20 21
M  V30 23 2 23 24
M  V30 24 1 24 22
M  V30 25 2 27 25
M  V30 26 2 28 26
M  V30 27 1 25 29
M  V30 28 1 26 27
M  V30 29 2 29 30
M  V30 30 1 30 28
M  V30 31 2 33 31
M  V30 32 2 34 32
M  V30 33 1 31 35
M  V30 34 1 32 33
M  V30 35 2 35 36
M  V30 36 1 36 34
M  V30 37 1 28 31
M  V30 38 1 14 23
M  V30 39 1 6 9
M  V30 40 10 4 37
M  V30 41 10 8 37
M  V30 42 10 15 37
M  V30 43 10 19 37
M  V30 44 10 35 37
M  V30 45 10 30 37
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>{{#moleculelink:|link=UEEXRMUCXBPYOV-UHFFFAOYSA-N|image=true}}


====Investigation====
====Investigation====

Revision as of 16:30, 1 August 2023


WikiTemplate experiment.pngMissing SI data
This page or an investigation on this page is missing important data. It might be included in the Supporting Information of the publication.

Catalyst

Molecule with key NRVILUOLTIKJEU-NGWNFTKISA-I does not exist.

Photosensitizer

Molecule with key UEEXRMUCXBPYOV-UHFFFAOYSA-N does not exist.

Investigation

  1. REDIRECT Photocatalytic reduction of CO2: conditions optimization
Investigation-Name: Table 1
  1. REDIRECT Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis/Cyclic voltammetry in various conditions
Investigation-Name: Table 2 - CV

Sacrificial electron donor

TEOATEADIPEA

Additives

TFE

Investigations

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