Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands: Difference between revisions

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DOI 10.1002/cssc.201901326
Authors Yasmeen Hameed, Gyandshwar Kumar Rao, Jeffrey S. Ovens, Bulat Gabidullin, Darrin Richeson,
Submitted 11.06.2019
Published online 03.07.2019
Licenses http://onlinelibrary.wiley.com/termsAndConditions#vor, http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects General Energy, General Materials Science, General Chemical Engineering, Environmental Chemistry
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(corrected structure)
(deleted useless molecule)
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==== Catalyst====
==== Catalyst====
<chemform smiles="C1C2N([*])P([Ru]3(P(C4C=CC=CC=4)(C4C=CC=CC=4)N([*])C(N=23)=CC=1)(Cl)(C#O)C#O)(C1C=CC=CC=1)C1C=CC=CC=1" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,Me">
<chemform smiles="C1C2N([*])P([Ru+]3(P(C4C=CC=CC=4)(C4C=CC=CC=4)N([*])C(N=23)=CC=1)(~Cl)([C-]#[O+])[C-]#[O+])(C1C=CC=CC=1)C1C=CC=CC=1.[Cl-]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,Me">
  -INDIGO-02132315442D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 42 48 4 0 0
M  V30 BEGIN ATOM
M  V30 1 C 7.95985 -2.27507 0.0 0
M  V30 2 C 9.69015 -2.27459 0.0 0
M  V30 3 C 8.82664 -1.77497 0.0 0
M  V30 4 C 9.69015 -3.27553 0.0 0
M  V30 5 C 7.95985 -3.28002 0.0 0
M  V30 6 N 8.82882 -3.77503 0.0 0
M  V30 7 N 7.09528 -3.78253 0.0 0
M  V30 8 N 10.5567 -3.7747 0.0 0
M  V30 9 P 7.09528 -4.78253 0.0 0
M  V30 10 P 10.5567 -4.7747 0.0 0
M  V30 11 R# 11.4227 -3.2747 0.0 0 RGROUPS=(1 1)
M  V30 12 R# 6.22925 -3.28253 0.0 0 RGROUPS=(1 1)
M  V30 13 C 6.09528 -4.78253 0.0 0
M  V30 14 C 6.38817 -5.48963 0.0 0
M  V30 15 C 11.2638 -5.48181 0.0 0
M  V30 16 C 11.5567 -4.7747 0.0 0
M  V30 17 Ru 8.825 -4.85 0.0 0
M  V30 18 C 8.325 -5.71603 0.0 0
M  V30 19 C 9.325 -5.71603 0.0 0
M  V30 20 Cl 9.53211 -4.14289 0.0 0
M  V30 21 O 8.325 -6.71603 0.0 0
M  V30 22 O 9.325 -6.71603 0.0 0
M  V30 23 C 12.231 -5.22465 0.0 0
M  V30 24 C 12.9351 -5.92876 0.0 0
M  V30 25 C 12.6799 -6.89577 0.0 0
M  V30 26 C 11.7088 -7.15396 0.0 0
M  V30 27 C 11.0028 -6.44474 0.0 0
M  V30 28 C 12.0588 -3.9089 0.0 0
M  V30 29 C 13.0545 -3.90893 0.0 0
M  V30 30 C 13.5579 -4.77313 0.0 0
M  V30 31 C 13.0538 -5.64238 0.0 0
M  V30 32 C 12.053 -5.64015 0.0 0
M  V30 33 C 5.59316 -5.64832 0.0 0
M  V30 34 C 4.59742 -5.6483 0.0 0
M  V30 35 C 4.09405 -4.78409 0.0 0
M  V30 36 C 4.59818 -3.91484 0.0 0
M  V30 37 C 5.59893 -3.91708 0.0 0
M  V30 38 C 6.64533 -6.4569 0.0 0
M  V30 39 C 5.94122 -7.16097 0.0 0
M  V30 40 C 4.9742 -6.90582 0.0 0
M  V30 41 C 4.71601 -5.9347 0.0 0
M  V30 42 C 5.42523 -5.22864 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 1 5 7
M  V30 8 1 4 8
M  V30 9 1 7 9
M  V30 10 1 8 10
M  V30 11 1 8 11
M  V30 12 1 7 12
M  V30 13 1 9 13
M  V30 14 1 9 14
M  V30 15 1 10 15
M  V30 16 1 10 16
M  V30 17 10 17 18
M  V30 18 10 17 19
M  V30 19 10 17 20
M  V30 20 3 18 21
M  V30 21 3 19 22
M  V30 22 10 9 17
M  V30 23 10 6 17
M  V30 24 10 10 17
M  V30 25 2 23 15
M  V30 26 1 24 23
M  V30 27 2 25 24
M  V30 28 1 26 25
M  V30 29 2 27 26
M  V30 30 1 15 27
M  V30 31 2 28 16
M  V30 32 1 29 28
M  V30 33 2 30 29
M  V30 34 1 31 30
M  V30 35 2 32 31
M  V30 36 1 16 32
M  V30 37 2 33 13
M  V30 38 1 34 33
M  V30 39 2 35 34
M  V30 40 1 36 35
M  V30 41 2 37 36
M  V30 42 1 13 37
M  V30 43 2 38 14
M  V30 44 1 39 38
M  V30 45 2 40 39
M  V30 46 1 41 40
M  V30 47 2 42 41
M  V30 48 1 14 42
M  V30 END BOND
M  V30 BEGIN SGROUP
M  V30 1 SUP 1 ATOMS=(6 15 23 24 25 26 27) BRKXYZ=(9 0.000000 0.000000 0.0000-
M  V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M  V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M  V30 0.000000) LABEL=Ph
M  V30 2 SUP 2 ATOMS=(6 16 28 29 30 31 32) BRKXYZ=(9 0.000000 0.000000 0.0000-
M  V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M  V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M  V30 0.000000) LABEL=Ph
M  V30 3 SUP 3 ATOMS=(6 13 33 34 35 36 37) BRKXYZ=(9 0.000000 0.000000 0.0000-
M  V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M  V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M  V30 0.000000) LABEL=Ph
M  V30 4 SUP 4 ATOMS=(6 14 38 39 40 41 42) BRKXYZ=(9 0.000000 0.000000 0.0000-
M  V30 00 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.-
M  V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
M  V30 0.000000) LABEL=Ph
M  V30 END SGROUP
M  V30 END CTAB
M  END
</chemform>  <chemform smiles="C1C2N([*])P([Ru+]3(P(C4C=CC=CC=4)(C4C=CC=CC=4)N([*])C(N=23)=CC=1)(~Cl)([C-]#[O+])[C-]#[O+])(C1C=CC=CC=1)C1C=CC=CC=1.[Cl-]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,Me">
   -INDIGO-07122316072D
   -INDIGO-07122316072D


Revision as of 16:09, 27 November 2023


Catalyst

Photosensitizer

Ru(bpy)3

Investigation

catcat conc [µM]PSPS conc [mM]e-Dsolvent A.λexc [nm].TON H2TON HCOOH.
1.

Ru(py)-(MeNdpp)2(CO)2Cl

0.025

[Ru(bpy)3][PF6]

0.025

TEOA

DMF

405380
2.

Ru(py)-(MeNdpp)2(CO)2Cl

0.05

[Ru(bpy)3][PF6]

0.05

TEOA

DMF

405210
3.

Ru(py)-(MeNdpp)2(CO)2Cl

0.1

[Ru(bpy)3][PF6]

0.1

TEOA

DMF

40557.5363
4.

Ru(py)-(MeNdpp)2(CO)2Cl

0.5

[Ru(bpy)3][PF6]

1

TEOA

DMF

40514162
5.

Ru(py)-(MeNdpp)2(CO)2Cl

1

[Ru(bpy)3][PF6]

1

TEOA

DMF

40513.390.5
6.

Ru(py)-(HNdpp)2(CO)2Cl

0.5

[Ru(bpy)3][PF6]

1

TEOA

DMF

4051470.5
7.

Ru(py)-(HNdpp)2(CO)2Cl

1

[Ru(bpy)3][PF6]

1

TEOA

DMF

4051244.5
8.

Ru(py)-(HNdpp)2(CO)2Cl

2

[Ru(bpy)3][PF6]

1

TEOA

DMF

4059.341.5
Investigation-Name: Table 1

Sacrificial electron donor

TEOA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
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