Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands: Difference between revisions

Revision as of 15:09, 12 July 2023

Catalyst

Photosensitizer

Investigation

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON H2	TON HCOOH
1.	Ru(py)-(MeNdpp)2(CO)2Cl	0.025	[Ru(bpy)3][PF6]	0.025	TEOA	DMF	405		380
2.	Ru(py)-(MeNdpp)2(CO)2Cl	0.05	[Ru(bpy)3][PF6]	0.05	TEOA	DMF	405		210
3.	Ru(py)-(MeNdpp)2(CO)2Cl	0.1	[Ru(bpy)3][PF6]	0.1	TEOA	DMF	405	57.5	363
4.	Ru(py)-(MeNdpp)2(CO)2Cl	0.5	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	14	162
5.	Ru(py)-(MeNdpp)2(CO)2Cl	1	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	13.3	90.5
6.	Ru(py)-(HNdpp)2(CO)2Cl	0.5	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	14	70.5
7.	Ru(py)-(HNdpp)2(CO)2Cl	1	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	12	44.5
8.	Ru(py)-(HNdpp)2(CO)2Cl	2	[Ru(bpy)3][PF6]	1	TEOA	DMF	405	9.3	41.5

Investigation-Name: Table 1

Sacrificial electron donor

TEOA

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1002/cssc.201901326
Authors	Yasmeen Hameed, Gyandshwar Kumar Rao, Jeffrey S. Ovens, Bulat Gabidullin, Darrin Richeson,
Submitted	11.06.2019
Published online	03.07.2019
Licenses	http://onlinelibrary.wiley.com/termsAndConditions#vor, http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects	General Energy, General Materials Science, General Chemical Engineering, Environmental Chemistry
Go to literature page

@@ Line 73: / Line 73: @@
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+M  V30 0.000000) LABEL=Ph
+M  V30 2 SUP 2 ATOMS=(6 16 28 29 30 31 32) BRKXYZ=(9 0.000000 0.000000 0.0000-
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+M  V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
+M  V30 0.000000) LABEL=Ph
+M  V30 3 SUP 3 ATOMS=(6 13 33 34 35 36 37) BRKXYZ=(9 0.000000 0.000000 0.0000-
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+M  V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
+M  V30 0.000000) LABEL=Ph
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+M  V30 000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -
+M  V30 0.000000) LABEL=Ph
+M  V30 END SGROUP
+M  V30 END CTAB
+M  END
+</chemform>  <chemform smiles="C1C2N([*])P([Ru+]3(P(C4C=CC=CC=4)(C4C=CC=CC=4)N([*])C(N=23)=CC=1)(~Cl)([C-]#[O+])[C-]#[O+])(C1C=CC=CC=1)C1C=CC=CC=1.[Cl-]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,Me">
+  -INDIGO-07122316072D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
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+M  V30 BEGIN ATOM
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+M  V30 2 C 9.69015 -2.27459 0.0 0
+M  V30 3 C 8.82664 -1.77497 0.0 0
+M  V30 4 C 9.69015 -3.27553 0.0 0
+M  V30 5 C 7.95985 -3.28002 0.0 0
+M  V30 6 N 8.82882 -3.77503 0.0 0
+M  V30 7 N 7.09528 -3.78253 0.0 0
+M  V30 8 N 10.5567 -3.7747 0.0 0
+M  V30 9 P 7.09528 -4.78253 0.0 0
+M  V30 10 P 10.5567 -4.7747 0.0 0
+M  V30 11 R# 11.4227 -3.2747 0.0 0 RGROUPS=(1 1)
+M  V30 12 R# 6.22925 -3.28253 0.0 0 RGROUPS=(1 1)
+M  V30 13 C 6.09528 -4.78253 0.0 0
+M  V30 14 C 6.38817 -5.48963 0.0 0
+M  V30 15 C 11.2638 -5.48181 0.0 0
+M  V30 16 C 11.5567 -4.7747 0.0 0
+M  V30 17 Ru 8.825 -4.85 0.0 0 CHG=1
+M  V30 18 C 8.325 -5.71603 0.0 0 CHG=-1
+M  V30 19 C 9.325 -5.71603 0.0 0 CHG=-1
+M  V30 20 Cl 9.53211 -4.14289 0.0 0
+M  V30 21 O 7.7 -6.69103 0.0 0 CHG=1
+M  V30 22 O 10.025 -6.69103 0.0 0 CHG=1
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+M  V30 31 C 13.0538 -5.64238 0.0 0
+M  V30 32 C 12.053 -5.64015 0.0 0
+M  V30 33 C 5.59316 -5.64832 0.0 0
+M  V30 34 C 4.59742 -5.6483 0.0 0
+M  V30 35 C 4.09405 -4.78409 0.0 0
+M  V30 36 C 4.59818 -3.91484 0.0 0
+M  V30 37 C 5.59893 -3.91708 0.0 0
+M  V30 38 C 6.64533 -6.4569 0.0 0
+M  V30 39 C 5.94122 -7.16097 0.0 0
+M  V30 40 C 4.9742 -6.90582 0.0 0
+M  V30 41 C 4.71601 -5.9347 0.0 0
+M  V30 42 C 5.42523 -5.22864 0.0 0
+M  V30 43 Cl 12.15 -2.15 0.0 0 CHG=-1
+M  V30 END ATOM
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+M  V30 19 8 17 20
 M  V30 20 3 18 21
 M  V30 21 3 19 22

Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands: Difference between revisions

Revision as of 15:09, 12 July 2023

Contents

Catalyst

Photosensitizer

Investigation

Sacrificial electron donor

Investigations

Topics

Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands: Difference between revisions

Revision as of 15:09, 12 July 2023

Catalyst

Photosensitizer

Investigation

Sacrificial electron donor

Investigations

Current site

Topics