Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts: Difference between revisions
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====Photosensitizer ==== | ====Photosensitizer ==== | ||
<chemform smiles="C(C1C=CC=CC=1)1C2C=CC3C(C4C=CC=CC=4)=CC4CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu]56N7C8C9N5=C(CCCCP6(C5C=CC=CC=5)C5C=CC=CC=5)C=C(C5C=CC=CC=5)C=9C=CC=8C(C5C=CC=CC=5)=CC=7CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu]56P(C7C=CC=CC=7)(C7C=CC=CC=7)CCCCC(C=1)=N5C=2C=3N=46" inchi="1S/2C56H50N2P2.2Cu/c2*1-7-23-43(24-8-1)53-41-45(27-19-21-39-59(47-29-11-3-12-30-47)48-31-13-4-14-32-48)57-55-51(53)37-38-52-54(44-25-9-2-10-26-44)42-46(58-56(52)55)28-20-22-40-60(49-33-15-5-16-34-49)50-35-17-6-18-36-50;;/h2*1-18,23-26,29-38,41-42H,19-22,27-28,39-40H2;;" inchikey=" | <chemform smiles="C(C1C=CC=CC=1)1C2C=CC3C(C4C=CC=CC=4)=CC4CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu+]56N7C8C9N5=C(CCCCP6(C5C=CC=CC=5)C5C=CC=CC=5)C=C(C5C=CC=CC=5)C=9C=CC=8C(C5C=CC=CC=5)=CC=7CCCCP(C5C=CC=CC=5)(C5C=CC=CC=5)[Cu+]56P(C7C=CC=CC=7)(C7C=CC=CC=7)CCCCC(C=1)=N5C=2C=3N=46.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F" inchi="1S/2C56H50N2P2.2Cu.2F6P/c2*1-7-23-43(24-8-1)53-41-45(27-19-21-39-59(47-29-11-3-12-30-47)48-31-13-4-14-32-48)57-55-51(53)37-38-52-54(44-25-9-2-10-26-44)42-46(58-56(52)55)28-20-22-40-60(49-33-15-5-16-34-49)50-35-17-6-18-36-50;;;2*1-7(2,3,4,5)6/h2*1-18,23-26,29-38,41-42H,19-22,27-28,39-40H2;;;;/q;;2*+1;2*-1" inchikey="LRXMZDJKCHDVRC-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | ||
-INDIGO- | -INDIGO-11282314582D | ||
0 0 0 0 0 0 0 0 0 0 0 V3000 | 0 0 0 0 0 0 0 0 0 0 0 V3000 | ||
M V30 BEGIN CTAB | M V30 BEGIN CTAB | ||
M V30 COUNTS | M V30 COUNTS 136 156 0 0 0 | ||
M V30 BEGIN ATOM | M V30 BEGIN ATOM | ||
M V30 1 C 3.88485 -2.97507 0.0 0 | M V30 1 C 3.88485 -2.97507 0.0 0 | ||
| Line 212: | Line 212: | ||
M V30 51 C 3.01815 -1.47013 0.0 0 | M V30 51 C 3.01815 -1.47013 0.0 0 | ||
M V30 52 C 2.14885 -0.975699 0.0 0 | M V30 52 C 2.14885 -0.975699 0.0 0 | ||
M V30 53 Cu 7.35 -5.075 0.0 0 | M V30 53 Cu 7.35 -5.075 0.0 0 CHG=1 | ||
M V30 54 Cu 12.175 -6.8 0.0 0 | M V30 54 Cu 12.175 -6.8 0.0 0 CHG=1 | ||
M V30 55 P 10.925 -7.925 0.0 0 | M V30 55 P 10.925 -7.925 0.0 0 | ||
M V30 56 P 8.925 -6.875 0.0 0 | M V30 56 P 8.925 -6.875 0.0 0 | ||
| Line 282: | Line 282: | ||
M V30 121 C 9.41815 -0.173926 0.0 0 | M V30 121 C 9.41815 -0.173926 0.0 0 | ||
M V30 122 C 9.41169 0.826128 0.0 0 | M V30 122 C 9.41169 0.826128 0.0 0 | ||
M V30 123 F 18.1295 -1.33125 0.0 0 | |||
M V30 124 P 18.9955 -0.83125 0.0 0 CHG=-1 | |||
M V30 125 F 19.8615 -1.33125 0.0 0 | |||
M V30 126 F 18.9955 0.16875 0.0 0 | |||
M V30 127 F 19.8615 -0.33125 0.0 0 | |||
M V30 128 F 18.9955 -1.83125 0.0 0 | |||
M V30 129 F 18.1295 -0.33125 0.0 0 | |||
M V30 130 F 19.134 -4.3625 0.0 0 | |||
M V30 131 P 20.0 -3.8625 0.0 0 CHG=-1 | |||
M V30 132 F 20.866 -4.3625 0.0 0 | |||
M V30 133 F 20.0 -2.8625 0.0 0 | |||
M V30 134 F 20.866 -3.3625 0.0 0 | |||
M V30 135 F 20.0 -4.8625 0.0 0 | |||
M V30 136 F 19.134 -3.3625 0.0 0 | |||
M V30 END ATOM | M V30 END ATOM | ||
M V30 BEGIN BOND | M V30 BEGIN BOND | ||
| Line 428: | Line 442: | ||
M V30 143 1 122 120 | M V30 143 1 122 120 | ||
M V30 144 1 76 57 | M V30 144 1 76 57 | ||
M V30 145 1 123 124 | |||
M V30 146 1 124 125 | |||
M V30 147 1 124 126 | |||
M V30 148 1 124 127 | |||
M V30 149 1 124 128 | |||
M V30 150 1 124 129 | |||
M V30 151 1 130 131 | |||
M V30 152 1 131 132 | |||
M V30 153 1 131 133 | |||
M V30 154 1 131 134 | |||
M V30 155 1 131 135 | |||
M V30 156 1 131 136 | |||
M V30 END BOND | M V30 END BOND | ||
M V30 END CTAB | M V30 END CTAB | ||
Revision as of 14:58, 28 November 2023
Investigations
- Durability test (Molecular process, Photocatalytic CO2 conversion experiments)
- Results for photocatalytic reduction of CO2 (Molecular process, Photocatalytic CO2 conversion experiments)
