An integrated Re(I) photocatalyst and sensitizer that activates the formation of formic acid from reduction of CO2: Difference between revisions
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=== Catalyst=== | |||
=== Catalyst === | |||
<chemform smiles="C1C=C2C3C=CC=CN=3[Re+]([C-]#[O+])([C-]#[O+])3(N4C=CC=CC=4C4N3=CC=CC=4)N2=CC=1.S(C(F)(F)F)([O-])(=O)=O" inchi="1S/2C10H8N2.CHF3O3S.2CO.Re/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2-1(3,4)8(5,6)7;2*1-2;/h2*1-8H;(H,5,6,7);;;/q;;;;;+1/p-1" inchikey="SQEHJZNRDJMTCB-UHFFFAOYSA-M" height="200px" width="300px" float="none"> | <chemform smiles="C1C=C2C3C=CC=CN=3[Re+]([C-]#[O+])([C-]#[O+])3(N4C=CC=CC=4C4N3=CC=CC=4)N2=CC=1.S(C(F)(F)F)([O-])(=O)=O" inchi="1S/2C10H8N2.CHF3O3S.2CO.Re/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2-1(3,4)8(5,6)7;2*1-2;/h2*1-8H;(H,5,6,7);;;/q;;;;;+1/p-1" inchikey="SQEHJZNRDJMTCB-UHFFFAOYSA-M" height="200px" width="300px" float="none"> | ||
-INDIGO-05192310272D | -INDIGO-05192310272D | ||
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</chemform> | </chemform> | ||
=== Photosensitizer === | ===Photosensitizer=== | ||
{{#moleculelink:|link=HNVRWFFXWFXICS-UHFFFAOYSA-N|image=true}} | |||
===Investigation=== | |||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | |||
=== Sacrificial electron donor === | === Sacrificial electron donor=== | ||
{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}} | |||
Revision as of 10:10, 7 July 2023
Investigations
- Effect of proton donor (Molecular process, Photocatalytic CO2 conversion experiments)
- Solvent effect study between DMA DMF and acetonitrile (Molecular process, Photocatalytic CO2 conversion experiments)
- Study on the concentration of catalyst (Molecular process, Photocatalytic CO2 conversion experiments)
- Time profile in DMF (Molecular process, Photocatalytic CO2 conversion experiments)
