An integrated Re(I) photocatalyst and sensitizer that activates the formation of formic acid from reduction of CO2: Difference between revisions
From ChemWiki
publication
| About |
|---|
(Added molecules) |
(Added investigation) |
||
| Line 4: | Line 4: | ||
=== Investigation === | === Investigation === | ||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | |||
=== Catalyst === | === Catalyst === | ||
<chemform smiles="C1C=C2C3C=CC=CN=3[Re+]([C-]#[O+])([C-]#[O+])3(N4C=CC=CC=4C4N3=CC=CC=4)N2=CC=1.S(C(F)(F)F)([O-])(=O)=O" inchi="1S/2C10H8N2.CHF3O3S.2CO.Re/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2-1(3,4)8(5,6)7;2*1-2;/h2*1-8H;(H,5,6,7);;;/q;;;;;+1/p-1" inchikey="SQEHJZNRDJMTCB-UHFFFAOYSA-M" height="200px" width="300px" float="none"> | <chemform smiles="C1C=C2C3C=CC=CN=3[Re+]([C-]#[O+])([C-]#[O+])3(N4C=CC=CC=4C4N3=CC=CC=4)N2=CC=1.S(C(F)(F)F)([O-])(=O)=O" inchi="1S/2C10H8N2.CHF3O3S.2CO.Re/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2-1(3,4)8(5,6)7;2*1-2;/h2*1-8H;(H,5,6,7);;;/q;;;;;+1/p-1" inchikey="SQEHJZNRDJMTCB-UHFFFAOYSA-M" height="200px" width="300px" float="none"> | ||
| Line 98: | Line 100: | ||
=== Photosensitizer === | === Photosensitizer === | ||
<chemform smiles="" inchi="" inchikey="HNVRWFFXWFXICS-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform> | <chemform smiles="" inchi="" inchikey="HNVRWFFXWFXICS-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform> | ||
=== Sacrificial electron donor === | === Sacrificial electron donor === | ||
<chemform smiles="" inchi="" inchikey="GSEJCLTVZPLZKY-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform> | <chemform smiles="" inchi="" inchikey="GSEJCLTVZPLZKY-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform> | ||
Revision as of 09:45, 19 May 2023
Investigations
- Effect of proton donor (Molecular process, Photocatalytic CO2 conversion experiments)
- Solvent effect study between DMA DMF and acetonitrile (Molecular process, Photocatalytic CO2 conversion experiments)
- Study on the concentration of catalyst (Molecular process, Photocatalytic CO2 conversion experiments)
- Time profile in DMF (Molecular process, Photocatalytic CO2 conversion experiments)
