Photocatalytic CO2 Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid: Difference between revisions
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[[Category:Photocatalytic CO2 conversion to HCOOH]] | [[Category:Photocatalytic CO2 conversion to HCOOH]] | ||
{{BaseTemplate}} | {{BaseTemplate}} | ||
==== Catalyst ==== | ====Catalyst==== | ||
<chemform smiles="C(C1C(C)=CC(C)=CC=1C)1C=C2CP([Ir+3]([H-])([Cl-])34P(C5CCCCC5)(C5CCCCC5)CC5C=C(C6C(C)=CC(C)=CC=6C)C=C(C(C=1)=N23)N=54)(C1CCCCC1)C1CCCCC1.[B-](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1" inchi="1S/C54H74N2P2.C24H20B.ClH.Ir.H/c1-37-27-39(3)53(40(4)28-37)43-31-45(35-57(47-19-11-7-12-20-47)48-21-13-8-14-22-48)55-51(33-43)52-34-44(54-41(5)29-38(2)30-42(54)6)32-46(56-52)36-58(49-23-15-9-16-24-49)50-25-17-10-18-26-50;1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;;;/h27-34,47-50H,7-26,35-36H2,1-6H3;1-20H;1H;;/q;-1;;+3;-1/p-1" inchikey="BEUJVGCRFICSDD-UHFFFAOYSA-M" height="200px" width="300px" float="none"> | <chemform smiles="C(C1C(C)=CC(C)=CC=1C)1C=C2CP([Ir+3]([H-])([Cl-])34P(C5CCCCC5)(C5CCCCC5)CC5C=C(C6C(C)=CC(C)=CC=6C)C=C(C(C=1)=N23)N=54)(C1CCCCC1)C1CCCCC1.[B-](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1" inchi="1S/C54H74N2P2.C24H20B.ClH.Ir.H/c1-37-27-39(3)53(40(4)28-37)43-31-45(35-57(47-19-11-7-12-20-47)48-21-13-8-14-22-48)55-51(33-43)52-34-44(54-41(5)29-38(2)30-42(54)6)32-46(56-52)36-58(49-23-15-9-16-24-49)50-25-17-10-18-26-50;1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;;;/h27-34,47-50H,7-26,35-36H2,1-6H3;1-20H;1H;;/q;-1;;+3;-1/p-1" inchikey="BEUJVGCRFICSDD-UHFFFAOYSA-M" height="200px" width="300px" float="none"> | ||
-INDIGO-05172314302D | -INDIGO-05172314302D | ||
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</chemform> | </chemform> | ||
==== | ====Investigation ==== | ||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | |||
====Sacrificial electron donor==== | |||
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}} | |||
__FORCETOC__ | |||
Revision as of 10:26, 7 July 2023
Investigations
- Control experiments (Molecular process, Photocatalytic CO2 conversion experiments)
- Photocatalytic reduction of CO2, best TON (Molecular process, Photocatalytic CO2 conversion experiments)
